Improving the photocatalytic activity of graphitic carbon nitride by thermal treatment in a high-pressure hydrogen atmosphere

Extending visible light absorption range and suppressing the recombination of photogenerated charge carriers are always important topics in developing efficient solar-driven photocatalysts. In this study, the thermal treatment process at 400 °C in a high-pressure hydrogen atmosphere was applied to modify graphitic carbon nitride. Compared to the normal atmospheric hydrogen treatment process, this process has the merit of producing nitrogen deficient graphitic carbon nitride in high-yield. The optimal photocatalytic activity of modified graphitic carbon nitride was demonstrated by controlling the treatment duration in the hydrogen atmosphere.The changes in the crystal structure, microstructure and optical properties of carbon nitrides were investigated by several characterizations. The relationship between the photocatalytic activity and structures of graphitic carbon nitride was preliminarily established. The results obtained in this study could provide some new ways of improving the activity of graphitic carbon nitride based photocatalyst.     

高新技术企业创新资金配置风险预警的FOA-SVM模型及实证

为了提高创新资金的运营效率和为企业创新活动提供有效支撑,按照高新技术企业创新资金配置的生态化要求,从资金的来源、使用、偿还、收益分配四个维度进行风险分析并构建风险预警指标,给出创新资金配置的生态目标,将支持向量机二分类问题扩展到多分类并与果蝇优化算法结合构建风险预警的FOA-SVM (fruit fly optimization algorithm and support vector machines)模型,确定警度和警限,选取117家医药制造企业2016年数据进行模型验证并与GA-SVM (genetic algorithm and support vector machines)模型进行比较分析,研究表明,FOA-SVM模型分类准确率高而且对于高风险的误判率低,可以实现对高新技术企业创新资金配置风险的分类预警,为优化创新资金配置、防范与控制创新资金配置风险提供依据.     

Blockage of the NLRP3 inflammasome by MCC950 improves anti-tumor immune responses in head and neck squamous cell carcinoma

The NLRP3 inflammasome is a critical innate immune pathway responsible for producing active interleukin (IL)-1β, which is associated with tumor development and immunity. However, the mechanisms regulating the inflammatory microenvironment, tumorigenesis and tumor immunity are unclear. Herein, we show that the NLRP3 inflammasome was over-expressed in human HNSCC tissues and that the IL-1β concentration was increased in the peripheral blood of HNSCC patients. Additionally, elevated NLRP3 inflammasome levels were detected in tumor tissues of Tgfbr1/Pten 2cKO HNSCC mice, and elevated IL-1β levels were detected in the peripheral blood serum, spleen, draining lymph nodes and tumor tissues. Blocking NLRP3 inflammasome activation using MCC950 remarkably reduced IL-1β production in an HNSCC mouse model and reduced the numbers of myeloid-derived suppressor cells (MDSCs), regulatory T cells (Tregs) and tumor-associated macrophages (TAMs). Moreover, inhibiting NLRP3 inflammasome activation increased the numbers of CD4⁺ and CD8⁺ T cells in HNSCC mice. Notably, the numbers of exhausted PD-1⁺ and Tim3⁺ T cells were significantly reduced. A human HNSCC tissue microarray showed that NLRP3 inflammasome expression was correlated with the expression of CD8 and CD4, the Treg marker Foxp3, the MDSC markers CD11b and CD33, and the TAM markers CD68 and CD163, PD-1 and Tim3. Overall, our results demonstrate that the NLRP3 inflammasome/IL-1β pathway promotes tumorigenesis in HNSCC and inactivation of this pathway delays tumor growth, accompanied by decreased immunosuppressive cell accumulation and an increased number of effector T cells. Thus, inhibition of the tumor microenvironment through the NLRP3 inflammasome/IL-1β pathway may provide a novel approach for HNSCC therapy.     

Estimation of Partially Linear Panel Data Models with Cross-Sectional Dependence

Journal of Systems Science and Complexity - This paper studies the estimation of the partially linear panel data models, allowing for cross-sectional dependence through a common factors structure....     

Preparation of rare-earth-modified medical stone powders and their application as conductive fillers

Traditional metal conductive fillers are expensive and prone to oxidation. Thus, the development of new conductive powders as fillers is urgently needed. A novel gaseous penetration technology was adopted to prepare La-doped medical stone powders(La-MSPs), which are inexpensive mesoporous materials, as a new kind of conductive filler material. The prepared La-MSPs attained a resistivity of 450 ?·m and were used as a filler to prepare conductive coatings with epoxy resin as the resin matrix. The influence of the La-MSPs dosage on the resistance and hardness of the coatings was also determined. The resistance and the hardness both decreased with increasing filler dosage. Finally, the optimum recipe of the conductive coatings with the most suitable fillers dosage(55 wt%) was obtained. The hardness and resistance of the coatings with 55 wt% La-MSPs were HV 4 and 5.5 × 10~7 ?, respectively.     

Optimal Switching Integrity Attacks on Sensors in Industrial Control Systems

In this article, an optimal switching integrity attack problem is investigated to study the response of feedback control systems under attack. The authors model the malicious attacks on sensors as additive norm bounded signals. The authors consider an attacker who is only capable of launching attacks to limited number of sensors once a time and changing the combinations of attacked sensors all over the time. The objective of this paper is to find the optimal switching sequence of these combinations and the optimal attack input. The authors solve this problem by transforming it into a traditional optimal control problem with new control variables vary continuously in the range [0, 1]. The optimal solutions of the new control variables are of bang-bang-type. Therefore, an algebraic switching condition and an optimal attack input can be obtained. Finally, numerical results are provided to illustrate the effectiveness of the methods.     

基于语言偏好信息的满意公平稳定双边匹配方法

针对语言偏好信息下的双边匹配问题,提出一种考虑匹配满意性、公平性和稳定性的双边匹配方法.首先,通过构造匹配满意度计算规则,将双边主体的语言偏好信息转化为匹配满意度;然后,给出满意匹配、公平匹配和稳定匹配的定义,在此基础上,考虑稳定匹配约束条件,建立双边匹配多目标优化模型,采用理想点法将多目标优化模型转化为单目标规划模型进行求解;最后,通过一个算例验证了提出方法的可行性和有效性.     

Speeding Up the GVW Algorithm via a Substituting Method

Journal of Systems Science and Complexity - The GVW algorithm is an efficient signature-based algorithm for computing Gröbner bases. In this paper, the authors consider the implementation of...     

Existence and Uniqueness Results for Quaternion-Valued Nonlinear Impulsive Differential Systems

This paper studies the existence and uniqueness conditions for the quaternion-valued nonlinear impulsive system. Firstly, a space of quaternion-valued piecewise functions is constructed and completeness of the space is also proved. Then by taking advantage of the Bielecki norm and fixed point theorem, existence and uniqueness criteria of quaternion-valued nonlinear impulsive system are obtained. At last, an example is given to illustrate our theoretical results.