磁性纳米复合粒子表面接枝聚苯乙烯磺酸钠的制备

合成了聚苯乙烯磺酸钠接枝Fe3O4/SiO2纳米复合材料.通过表面引发原子转移自由基聚合在Fe3O4/SiO2磁性纳米粒子表面包覆了阴离子聚电解质(聚苯乙烯磺酸钠).利用透射电子显微镜(TEM),傅立叶变换红外光谱仪(FT-IR),震荡磁力计(VSM),X射线能谱仪(EDS),全自动X射线衍射仪(XRD)等仪器对所制备的复合材料进行了表征,成功制备了尺寸均一的聚苯乙烯磺酸钠接枝Fe3O4/SiO2核壳结构的纳米复合材料.     

Inconel718高温合金多层夹芯板结构的LBW/SPF技术

Inconel718高温合金多层夹心板结构具有高强度、高刚度、轻量化结构的特点,已用于低成本、轻质火箭发动机的制造.采用LBW/SPF技术制造了Inconel718合金多层夹芯结构件,并对其超塑成形前后的微观组织进行了分析.试验结果表明:超细晶Inconel718合金板材具有优良的超塑性能,在T=950℃,初始应变速率为1.6×10-4/s的条件下,延伸率达到483.6％.LBW/SPF技术制造出的Inconel718高温合金多层夹芯构件具有外观形状良好、壁厚分布均匀等特点.面板与芯板激光焊接参数为:功率1050W,焊接速度1000mm/min,离焦量-0.80mm,保护气体流量0.6L/min;芯板与芯板激光焊接参数为:功率900W,焊接速度1000mm/min,离焦量-1.00mm,保护气体流量0.6L/min.多层夹芯板结构的超塑成形参数为:成形温度Tf=965℃;成形压力Pf=4.2MPa;成形时间tf=130min.微观组织分析表明超塑成形过程利于焊缝显微组织的改善并且能够提高其力学性能.因此,LBW/SPF技术适用于超细晶Inconel718高温合金多层夹芯结构的制造.     

Influence of Rare Earth Elements on Mechanical Properties and Corrosion Resistance of Cu-15Ni Alloy

In order to improve the mechanical property and Cl-+S2-corrosion resistance of B15 copper-nickel alloy,Cu-15Ni-xRE(x:0-0.1%by weight)alloy was prepared by adding rare earth(RE)in melted Cu-15Ni alloy using metal mould casting method.Optical microscopy(OM),electronic tensile testing machine,X-ray diffraction(XRD),scanning electron microscope(SEM),and electrochemical testing system were used to analyze mechanical property,corrosion resistance property,and surface microstructure of different treatment samples.The results of OM and tensile testing show that the RE addition can effectively deoxidize the alloy melt and the microstructure of the alloy changes from coarse dendrite to small equiaxed grain.By addition of 0.05%RE,the tensile strength and elongation of Cu-15Ni alloys are improved from 294 MPa to 340MPa,and 8%to 33.5%respectively.The results of electrochemical testing show that the corrosion resistance of Cu-15Ni alloy is greatly improved by adding proper amount of RE,whereas excess addition of RE worsens the corrosion resistance.The optimum RE content was about 0.05%by weight.In comparison with the alloy without RE,the corrosion potential and corrosion current density of Cu-15Ni alloy containing proper RE decreased by about-0.28 V and 70A/cm2,respectively.