SiO2/PMMA无机-有机复合材料的制备与性能

以苯乙烯磺酸钠（NaSS）为离子单体,将其介入甲基丙烯酸甲酯（MMA）与正硅酸乙酯（TEOS）的原位分散聚合体系,以获得较少分散剂用量下的多功能二氧化硅/聚甲基丙烯酸甲酯(SiO2/PMMA)复合体系的单分散微球,采用XRD、SEM、TEM、FTIR、TGA和DSC对所获SiO2/PMMA复合微球进行了表征,并对其防水性能及单体合成机理进行了研究。研究结果表明：在分散聚合体系中加入正硅酸乙酯（TEOS）获得的纳米SiO2颗粒,可提高聚合物PMMA的疏水性能,且对该复合材料的透光率影响不大,仍具有很高的透明度。     

Preparation and Properties of Poly（Ethylene Terephthalate）/Boehmite Nanocomposite

Colloidal boehmite particles have been included into a polyethylene terephthalate matrix by in situ polymerization. Boehmite nanoparticles were produced by the controlled hydrolysis of aluminium isopropylate. The nanoparticles were characterized using Transmitted Electronic Microscopy （TEM） and X-ray Diffraction （XRD）, which revealed the particles of magnitude about 10 nm. The particles have been used without any surface modification. Characterization of the nanocomposite has been carried out using TEM and differential scanning calorimetry （DSC）. TEM images indicate that the particles have been homogeneously dispersed in the polymer. DSC results show that the presence of boehmite affects the process of crystallization of polyethylene terephthalate.