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Electrospun porous films doped with the green-synthesized CdSe quantum dots were synthesized. Glycerol was chosen to prepare the quantum dots ( QDs), with the highest quantum yield of 78.28%. Polycaprolactone (PCL) was electrospun with CdSe QDs to avoid the QDs' toxicity and improve the QDs' cytocompatibility. The electrospun QDs-doped films preserve the original QDs' fluorescence. Pores can be detected from the SEM of the films, predicting the possibility of loading drugs in the cancer therapy. The cell proliferation assay shows excellent cytocompatibility of the eletrospun CdSe-QDs-doped films. The present eletrospun CdSe- QDs-doped porous films are cytocompatibale, highly-fluorescent and ootential to load drugs in cancer therapy. 相似文献
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通过岩心观察、薄片及古生物鉴定,结合岩相、电相及地球化学特征分析,对东营凹陷HB地区沙一段湖相薄层碳酸盐岩成因进行研究。结果表明:目的层纵向上可划分为早、中、晚3期沉积;中期沉积构成了碳酸盐岩的主体,细分为藻礁格架、礁间、礁前、礁后、陆源沙坝和浅湖泥坪等6个成因单元;早期到中期气候、水文条件的改变形成了有利于藻的生长环境,末期海侵作用发生,藻礁建造结束,而广盐性腹足类、介形类生物繁盛,形成了广泛的螺灰岩沉积。 相似文献
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Recent years, it has attracted more attentions to increase the porosity and pore size of nanofibrous scaffolds to provide the for the cells to grow into the small-diameter vascular grafts. In this study, a novel bi-layer tubular scaffold with an inner layer and an outer layer was fabricated. The inner layer was random collagen/poly ( L-lactide-co-caprolactone ) I P ( LLA- CL) ] nanofibrous mat fabricated by conventional electrospinning and the outer layer was aligned collagen/P (LLA-CL) nanoyarns prepared by a dynamic liquid dectrospinning method. Fourier transform infrared spectroscopy (FTIR) was used to characterize the chemical structure. Scanning electron microscopy ( SEM ) was employed to observe the morphology of the layers and the cross- sectioned bi-layer tubular scaffold. A liquid displacement method was employed to measure the porosities of the inner and outer layers. Stress-strain curves were obtained to evaluate the mechanical properties of the two different layers and the bi-layer membrane. The diameters of the nanofibers and the nanoyarns were (480 ± 197 ) nm and ( 19.66 ± 4.05 ) μm, respectively. The outer layer had a significantly higher porosity and a larger pore size than those of the inner layer. Furthermore, the bi-layer membrane showed a good mechanical property which was suitable as small-diameter vascular graft. The results indicated that the bi-layer tubular scaffold had a great potential application in small vascular tissue engineering. 相似文献
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Colloidal gels made of oppositely charged nanoparticles are a novel class of hydrogels and can exhibit pseudoplastic behavior which will enable them to mold easily into specific shapes. These moldable gels can be used as building blocks to self-assemble into integral scaffolds from bottom to up through electrostatic forces. However, they are too weak to maintain scaffold morphology just depending on interparticle interactions such as Van der Waals attraction and electrostatic forces especially for bone tissue engineering. In this study, oppositely charged gelatin nanoparticles were firstly prepared by two-step desolvation method, followed by the mixture with water to form colloid gels. To solve the problem of weak mechanical performance of colloid gels, gelatin macromolecules were introduced into the prepared gels to form blend gels. The blend gels can be easily processed into three-dimensional (3D) porous scaffolds via motor assisted microsyringe (MAM) system, a nozzle-based rapid prototyping technology, under mild conditions. After fabrication the scaffolds were erosslinked by glutaraldehyde ( GA, 25 % solution in water by weight), then the crosslinked gelatin macromolecules network could form to improve the mechanical properties of colloid gels. The average particle size and zeta potential of gdatin nanoparticles were measured by Nano- ZS instrument. The morphology and microstructures of scaffolds were characterized by macroscopic images. The mechanical properties of the scaffolds were studied by a universal material testing machine. 相似文献
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以六氟异丙醇(HFIP)为溶剂,乳酸己内酯共聚物(P(LLA-CL))掺杂聚苯胺(PANi)和樟脑磺酸(CPSA)作材料,采用静电纺技术制备导电型纳米纤维膜,并对其纤维的物理学特征进行表征.通过控制导电材料的添加量,探究纳米纤维直径和电导率的变化.研究表明:P(LLA-CL)纳米纤维分布均匀表面光滑,添加聚苯胺的纳米纤维直径变粗,电导率增大. 相似文献
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