Dielectric relaxation and conduction mechanism in Aurivillius ceramic Bi5Ti3FeO15

For this study, we synthesized Aurivillius Bi5Ti3FeO15 ceramic using the generic solid-state reaction route and then performed room-temperature X-ray diffraction to confirm that the compound had a single phase with no impurities. The surface morphology of the prepared sample was observed to contain microstructural grains approximately 0.2–2 μm in size. The dielectric properties of the sample were determ-ined as a function of frequency in a range of approximately 100 Hz to 1 MHz at various temperatures (303 K ≤ T ≤ 773 K). Nyquist plots of the impedance data were found to exhibit a semi-circular arc in the high-temperature region, which is explained by the equivalent electrical circuit (R1C1)(R2QC2), where R1 and R2 represent the resistances associated with the grains and grain boundaries, respectively, C1 and C2 are the re-spective capacitances, and Q is the constant phase element (CPE), which accounts for non-Debye type of behavior. Our results indicate that both the resistance and capacitance of the grain boundaries are more prominent than those of the grains. The alternating current (ac) conductiv-ity data were analyzed based on the Jonscher universal power law, which indicated that the conduction process is dominated by the hopping mechanism. The calculated activation energies of the relaxation and conduction processes were very similar (0.32 to 0.53 eV), from which we conclude that the same type of charge carriers are involved in both processes.     

Effect of Co substitution on the structural,dielectric and optical properties of KBiFe2O5

Cobalt (Co)-modified brownmillerite KBiFe2O5 (KBFO; [KBiFe2(1?x)Co2xO5 (x = 0, 0.05)]) polycrystalline is synthesized following the solid-state reaction route. Rietveld refinement of X-ray diffraction data confirmed the phase purity of KBFO and KBiFe1.9Co0.1O5 (KBFCO). The optical bandgap energy (Eg) of KBFO decreased from 1.59 to 1.51 eV because of Co substitution. The decrease in bandgap can be attributed to the tilting of the Fe–O tetrahedral structure of KBFCO. The observed room-temperature Raman peaks of KBFCO shifted by 3 cm?1 toward a lower wavenumber than that of KBFO. The shift in Raman active modes can be attributed to the change in the bond angles and bond lengths of the Fe–O tetrahedral structure and modification in response to oxygen deficiency in KBFO because of Co doping. Compared with that of KBFO, the frequency-dependent dielectric constant and dielectric loss of KBFCO decrease at room temperature, which is a con-sequence of the reduction in oxygen migration and modification in response to vibrational modes present in the sample.     

Corrosion behavior of cold-rolled and post heat-treated 316L stainless steel in 0.9wt%NaCl solution

The effect of cold rolling and post-rolling heat treatment on the microstructural and electrochemical properties of the 316L stainless steel was investigated.Two-pass and four-pass cold-rolled stainless steel specimens were heat-treated by annealing at 900℃followed by quenching in water.During the cold rolling,the microstructure of the as-received specimen transformed from austenite to strain-inducedα′-martensite due to significant plastic deformation that also resulted in significant grain elongation(i.e.,~33%and 223%increases in the grain elongation after two and four rolling passes,respectively).The hardness of the heat-treated as-received specimen decreased from HV 190 to 146 due to the recovery and recrystallization of the austenite grain structure.The cyclic polarization scans of the as-rolled and heat-treated specimens were obtained in 0.9wt%NaCl solution.The pitting potential of the four-pass rolled specimen was significantly increased from 322.3 to 930.5 mV after post-rolling heat treatment.The beneficial effect of the heat treatment process was evident from~10-times-lower corrosion current density and two-orders-of-magnitude-lower passive current density of the heat-treated specimens compared with those of the as-rolled specimens.Similarly,appreciably lower corrosion rate(3.302×10^?4mm/a)and higher pitting resistance(1115.5 mV)were exhibited by the postrolled heat-treated specimens compared with the as-rolled 316L stainless steel specimens.     

一种新的维吾尔文字幕关键帧提取方法

为了快速有效地提取视频中含有维吾尔文字幕的关键帧提出一种新方法.该方法首先运用多尺度Harris角点检测,结合维吾尔文字笔画特点,完成字幕关键帧的初步提取;然后利用最小二乘法拟合直线,根据两条拟合直线的角度偏离情况对初步提取的结果作去冗余处理,得到最终字幕关键帧.实验结果表明:该方法快速简单,提取结果的准确率达到93%,具有很好的适应性.     

欧陆科学哲学的两条路径（英文）

如果你戴上我称为"欧陆式眼镜"的东西,运用欧陆哲学的视角来审视诸如探究、发现、实验、理论和确证等传统的科学哲学问题,某些事物就会以颇为不同的方式呈现,你就会看到新的事物,一切事物会彼此相关并以不同的方式与背景相关。透过欧陆式眼镜的凝视,让你倾向于关注两种事物:第一,那些妨碍你看得更清晰的事物;第二,事物"如何"显现,而非事物是"什么"。该隐喻有某种严重的缺陷,但仍是有用的,因为它提示了审视科学的传统视角与欧陆视角之间的巨大差异。它也能被用于发展"科研平台"这个观念,即科学不仅仅是一组活动,不仅仅是在某种程度上允许我们将之封闭的一组工具、实践和借此形成的知识,而是由诸线条的流动之网构成的,这些线条顺利地与紧密地整合入我们的世界并且塑造了世界的轮廓。我在本文中讨论了欧陆科学哲学的两条可能路径。一条涉及的是"解构性的重演",即对我们继承下来的科学概念(包括传统的分析性概念与海德格尔的"科学不思"的概念)的探究;另一条涉及的是可被称为"回归田野研究"的东西,即仔细地审视科学实践。接受这两条路径,将让欧陆科学哲学唤醒一大片重要的探究领域。忽略这些探究的领域,科学哲学将自食其果。     

超临界CO2气溶胶溶剂萃取法制备尤特奇S100纳米颗粒

采用超临界CO2气溶胶溶剂萃取法(ASES)制备了尤特奇S100(Eudragit S100)纳米粒,考察了有机溶剂的选择、压力、温度、溶液浓度及流速等主要工艺参数对Eudragit S100纳米粒形貌及粒径大小的影响,并采用扫描电镜、傅立叶红外光谱分析对结果进行了表征。结果表明,在以丙酮作为溶剂、压力为16 MPa、温度为45℃、溶液浓度为1 mg/m L的工艺条件下,可制备出有机溶剂残留少、分布均匀、平均粒径为30~60 nm的Eudragit S100纳米颗粒。纳米粒子的平均粒径随温度、压力的升高而减小,随溶液浓度的减小而减小。     

HPLC-ELSD测定安神宝颗粒中3种成分

为完善安神宝颗粒的质量控制标准,采用高效液相色谱法同时测定安神宝颗粒中酸枣仁皂A、东莨菪内酯、槲皮素3种有效成分,采用Agilent Zorbox SB C18色谱柱(4.6mm×150mm,5μm)及蒸发光散射检测器,柱温35℃,流动相为甲醇-0.5%的冰醋酸水溶液,梯度洗脱,流速为1.0mL/min,进样量10μL。结果表明,在该色谱条件下,3种有效成分均完全分离,峰面积对数与进样量对数呈良好的线性关系(r=0.995 6~0.998 0);精密度、重复性、稳定性试验结果符合要求,各被测组分的平均回收率在94.74%~96.08%之间。液相色谱法操作简单,准确度、灵敏度高,可用于检测安神宝颗粒中的有效成分,对完善安神宝颗粒质量标准,提升药品的质量控制水平具有实际意义。     

Effect of MWCNT reinforcement on the precipitation-hardening behavior of AA2219

Aluminum alloy matrix composites have found a predominant place in research, and their applications are explored in almost all industries. The aerospace industry has been using precipitation-hardenable alloys in structural applications. However, insufficient literature is available on the influence of multiwalled carbon nanotubes (MWCNTs) on precipitation-hardenable alloy composite materials; thus, this work was designed to elucidate the effect on MWCNT reinforcement on AA2219 with and without precipitation hardening. Reinforcement with MWCNTs has been reported to accelerate precipitation and to achieve greater hardness within a much shorter time. The addition of 0.75wt% MWCNTs resulted in maximal hardness at 90 min, which is approximately 27% of improvement over the maximum hardness achieved by the corresponding monolithic alloy after 10 h of aging. The sample reinforced with 0.75wt% MWCNTs showed an improvement of 82% in hardness by solutionizing and aging compared to that achieved by sintering.     

新疆旅游关注度的时空差异及其影响因素

基于百度指数平台,获取了2011年、2013年及2015年我国大陆31个省、直辖市和自治区的新疆旅游搜索指数.运用季节集中指数、周内分布偏度指数、空间自相关方法对新疆旅游关注度的时空差异进行了分析并引入GWR模型探究其影响因素.结果表明:(1)新疆旅游关注度总体呈现增长态势,且各年关注度表现出明显的季节性特征,节假日、周存在"前兆效应";(2)全国各省、直辖市和自治区的新疆旅游关注度具有显著的空间自相关性,大多数地区呈现出持续的"低—低"集聚现象;(3)GWR模型优于OLS模型,从全域视角看,人口规模、经济发展水平、教育发展水平及互联网发展水平对新疆旅游关注度的影响均呈现不同程度的正向作用;从局域视角看,各影响因素作用整体上与OLS模型结果一致,但各影响因素的敏感度在空间上表现出西部地区高于东部地区的态势.