Spectroscopic study on the photophysical properties of chlorine substituted tetraphenylporphyrin-histidine and its zinc(Ⅱ)complexes

As the structural analogues of (bacterio)chlorophylls in photosynthetic organisms, porphyrins play an important role in building up artificial photosynthetic systems[13]. In natural photosynthetic pigment-protein complexes,certain amino acid residuals modulate the reactions ofcharge transfer and energy transfer via coordination andother types of interactions with chlorophyll molecules.For instance, in higher-plant photosynthetic reaction cen-ter PSⅡ, the oxidization-reduction system consistin…     

二元函数的微积分基本定理

从二元函数的面导数出发定义原函数和不定积分，研究了它们的性质．证明了：（１）若ｆ（ｘ，ｆｙ）有原函数，则有一族原函数且任意两个原函数相差ｋ（ｘ，ｙ）＝Ｃ（Ｘ）＋Ｄ（ｙ）＋Ｅ，其中Ｃ（ｘ），Ｄ（ｙ）为一元函数，Ｅ为常数；（２）若ｆ（ｘ，ｙ）在闭区间［Ａ，Ｂ］Ｒ２上连续，Ｚ＝（ｘ，ｙ）∈［Ａ，Ｂ］，则Φ（ｘ，ｙ）＝ｆ（ｓ，ｔ）ｄｓｄｔ在（ｘ，ｙ）可导且Φ’ｘｙ＝ｆ（ｘ，ｙ）；（３）若ｆ（ｘ，ｙ）在［Ａ，Ｂ］上连续，Ｆ（ｘ，ｙ）为其一个原函数，则ｆ（ｘ，ｙ）ｄｘｄｙ＝Ｆ（［Ａ，Ｂ］）．     

利用工业双戊烯合成香芹酮

目前,国内外合成香芹酮的主要原料苧烯均来自桔油,而我们利用精馏的工业双戊烯为原料,通过一步氧化法和三步合成法分别制备了香芹酮。对一步氧化法中,在一定条件下的最佳反应时间进行了探索;对三步合成法进行了改进,从而对松节油的综合利用开辟了新途径。     

Spectroscopic investigation on the telomeric DNA base sequence repeat

Telomeres are protein-DNA complexes at the terminals of linear chromosomes, which protect chromosomal integrity and maintain cellular replicative capacity. From single-cell organisms to advanced animals and plants, structures and functions of telomeres are both very conservative. In cells of human and vertebral animals, telomeric DNA base sequences all are (TTAGGG)n. In the present work, we have obtained absorption and fluorescence spectra measured from seven synthesized oligonucleotides to simulate the telomeric DNA system and calculated their relative fluorescence quantum yields on which not only telomeric DNA characteristics are predicted but also possibly the shortened telomeric sequences during cell division are implied. Oligonucleotide 5′-TTAGGGTTAGGG holds a low relative fluorescence quantum yield and remarkable excitation energy innerconversion, which tallies with the telomeric sequence of (TTAGGG)n. This result shows that telomeric DNA has a strong non-radiative or innerconvertible capability.     

Recent progress in terahertz science and technology

The relatively new technique of coherent electromagnetic radiation, in the region of 1012 Hz, has potential to detect the nature of low energy processes in physics, chemistry and biomedicine. In this review article, an overview of recent progress of terahertz (THz) science and technology is presented. The development of the THz generation and detection system, the THz radiation applications which include THz time-domain spectroscopy and T-ray imaging, and the future potential of THz wave research are discussed.     

莰烯及其衍生共轭烯甲酰化动力学常数的确定

本文确定了莰烯、ω-乙烯基莰烯、ω-丙烯基莰烯、ω-莰烯-戊烯基莰烯和ω-莰烯-丁二烯基莰烯的Vilsmeier-Haack甲酰化反应的动力学常数并比较了它们的反应速度。     

具有可变几何喷嘴的增压器轴流涡轮热力计算方法

本文提出具有可变几何喷嘴的增压器轴流涡轮热力计算方法。引入三个脉冲系数将脉冲涡轮按等压涡轮计算。给定通流部分尺寸,利用可变几何喷嘴来满足所驱动压气机和涡轮的配合。考虑各部实际损失,采用吴仲华燃气热力性质表迭代计算求出反动度、喷嘴出气角和喉口面积。可给定废气初温时迭代所需的初压或给定初压时迭代所需的初温,并算出涡轮当量通流面积。计算结果表明迭代计算是收敛的,算出的喷嘴喉口面积与实际相符。     

混合Kriging代理模型的高维参数估计优化算法

基于Kriging代理模型的优化算法对于解决函数计算昂贵的优化问题非常有效,但并不适用于高维参数的优化.针对该问题,提出了一个混合Kriging代理模型和多种优化技术的算法.该算法在Kriging模型选择新样例点时使用单维参数独立优化以克服维度灾难并提高收敛速度,同时基于已构建的Kriging代理模型信息提出一种新的动态坐标扰动策略,并将该策略用于高维参数优化以得到更好的目标函数值.为了保证不丢失全局最优解,在使用一般期望提高加点策略作为选点原则时,在期望函数的多个峰值同时选点.为了验证算法的有效性,将该算法应用于具有41维参数的人类白细胞代谢网络参数估计问题.实验结果表明,在有限的迭代次数下,该算法能产生较小的目标函数值,以及和实验拟合较好的参数估计结果.     

HJ1310锁相环调频立体声解码器电路原理及版图设计

本文在分析HJ1310电路原理的基础上,着重介绍该电路的版图设计.经投片实验,证明设计是成功的.经鉴定会测试通过,全部电参数都达到了国外目前同类产品的参数规范,并有较好的一致性.     

吕梁山隧道下穿青银高速公路施工技术

文章总结了在复杂地质条件下下穿高速公路的施工方法和技术措施，对今后类似工程施工具有借鉴意义。