Ni Co Cr合金共沉积工艺

通过线性扫描、循环伏安和交流阻抗谱分析,研究了柠檬酸镀液中Ni-Co-Cr合金共沉积的电化学行为,并利用扫描电镜和X射线衍射对镀层的表面形貌和结构进行了表征.结果表明,Cr3+与Ni2+,Co2+离子有相互促进放电、加速共沉积的作用,Co为异常沉积.当添加剂为10 g/L,糖精为1 g/L,p H值为2.5,镀液温度为30℃时,阴极极化较大,有利于得到Cr含量高的Ni-Co-Cr合金镀层.所得镀层表面光亮平整,为非晶态结构.     

5083铝合金表面化学镀Ni-P镀层的力学性能

采用化学镀方法在5083铝合金基体上制备了Ni-P非晶薄膜,采用纳米压痕技术在不同应变速率下研究Ni-P非晶薄膜的硬度、弹性模量和变形行为.结果表明,Ni-P非晶薄膜硬度不是一个恒定值,与纳米压痕的压入深度有关,而弹性模量基本保持不变;载荷-深度曲线出现跳跃及台阶现象与应变速率有关,应变速率愈慢,曲线出现台阶现象越明显;跳跃台阶源于单个剪切带的开动,而在高的应变速率条件下,由于多个剪切带的开动,曲线上便不出现跳跃台阶.     

软磁材料应用研究进展

软磁材料因其饱和磁感应强度高、磁导率高、矫顽力低、损耗低和环境稳定性好等优点,被广泛应用于通信、电源、计算机和各种电子产品等领域。随着信息技术和电子产品数字化的发展,电子仪器设备向着精密化、高效化和节能化方向发展,这就对软磁材料和元件提出了新的要求和挑战。如何取得具有较高饱和磁感应强度和低损耗的软磁材料已成为研究的重点。本文对传统软磁材料与新型软磁材料的研究现状作了总结,并对软磁材料的发展趋势作了展望,为后续软磁材料的发展提供指导方向。     

金属纳米粒子对非晶硅太阳能电池性能影响的理论模拟

使用时域有限差分(FDTD)方法,在标准太阳光下模拟非晶硅太阳能电池表面上有序排列的Ag或Au纳米颗粒对电池的光吸收增强效应.结果表明:通过改变金属颗粒的直径和粒子周期性间距等不同条件,光吸收的增强效应有规律地变化.结合AMPS-1D模拟软件对非晶硅电池的电学性能进行计算,在标准太阳光下,使用直径为200 nm、周期性间距为600 nm的Ag纳米粒子可以使非晶硅电池效率的提高幅度达到23.4％.     

Rapid reductive degradation of azo dyes by a unique structure of amorphous alloys

An Fe-based amorphous alloy was found to significantly enhance the reductive degradation of an azo dye in aqueous solution. The surface-area normalized rate constant was up to 2.0 L m-2 min-1 at room temperature,an order of magnitude larger than any previously reported value. The activation energy of the degradation process was calculated according to the Arrhenius equation,and a much lower value than those previously reported was obtained. Valence band measurement indicated that a depressed valence band maximum and a widened empty band were established in the amorphous ribbon. The unique structure of the amorphous alloy is important-it may reduce the activation energy of the degradation process and enhance the activity of the electrons,thus accelerating the degradation process.     

轧制塑性变形对Zr65Al7.5Cu12.5Ni10Ag5非晶合金力学性能的影响

采用维氏显微硬度仪、扫描电子显微镜对铸态、轧制态Zr₆₅Al_7.5Cu_12.5Ni₁₀Ag₅非晶合金的硬度及剪切带形貌进行了研究,并对轧制变形量与合金的力学性能之间的关系进行了分析。结果发现,在室温轧制条件下,该合金最大变形量达到了95%;铸态试样的半圆形剪切带规律、平滑,随着轧制变形量的增加剪切带形貌变得越来越混乱,合金的硬度总体呈下降趋势。     

Fe-Si-B-Nb-Cu-Zr非晶（纳米晶）合金的磁性机理研究

采用单辊甩带法制取了Fe-Si-B-Nb-Cu-Zr非晶合金薄带。利用X射线衍射仪（XRD）、差示扫描量热法（DSC）和振动样品磁强计（VSM）等手段对非晶态和晶化后的薄带的微观结构和磁性能进行了表征和测试,研究了Fe-Si-B-Nb-Cu-Zr合金中磁性能随着Zr含量以及退火温度变化的磁性机理。结果表明,在铸态Fe-...     

A new criterion for predicting glass forming ability of bulk metallic glasses and some critical discussions

A modified criterion,β',defined as T_g/T_x-T_g/(T_l·η))(T_g,T_x,T_l andηdenote the glass transition temperature,the onset of crystallization temperature,the liquidus temperature and constant coefficient,respectively),has been proposed for assessing the glass-forming ability(GFA) of bulk metallic glasses(BMGs).A survey of the readily available experimental data associated with the thermal analysis of various BMG alloys demonstrates that the newβ' criterion exhibits much better correlation with the GFA tha...     

Influence of B,Al and Nb addition on the glass forming ability and stability of mechanically alloyed Zr-Ni amorphous alloys

We investigated the influence of minor additions of B,Al and Nb that have representative atomic sizes on the glass forming ability (GFA) and stability of Zr-Ni amorphous alloys during mechanical alloying. The results show that the minor addition of B,Al or Nb does not shorten the initial time of the full amorphization reaction or improve the glass forming ability of the Zr-Ni alloys at a low rotation speed. However,B addition can effectively improve the mechanical stability of the amorphous phase against me...     

Fe76Si7.6B9.5P5C1.9合金带的纵向巨磁阻抗效应

利用单辊快淬法制备宽0.35 mm,厚0.033 mm的Fe76Si7.6B9.5P5C1.9非晶薄带,具有明显的纵向巨磁阻抗效应,最大磁阻比达到754%.氮气保护条件下进行热处理的样品,最大阻抗比和灵敏度都有明显提高,440℃退火1 h的样品最大阻抗比达到1 196%,灵敏度为715%/(A·m-1).