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1.
Using first-principles density function for molecules method (DMol) and discrete variational method (DVM) based on the density functional theory, we studied the doping effect of Re in Ni3Al. The structure relaxation and the alloying energy show that Re has a strong Al site preference and leads to the local deformation, which is in agreement with the experimental results and other theoretical results. In addition, the charge density difference and the bond order show that Re can strongly enhance the interatomic interaction between the nearest neighbor atoms. From the density of states and the Pauli spectrum, we find that resonance states and localized states are induced by doping Re, and the doped Re atom forms the hybridized bond with the nearest neighbor atoms. 相似文献
2.
本文报道四甲基膦酸二甲庚酸萃淋树脂(CL-P_(350)从硝酸溶液中吸附鳞的性能和机理研究。实验结果表明,吸附平衡服从Langmuir经验等温式。测得吸附物分子中P(350)与Re(Ⅶ)的摩尔比为2:1。Re(Ⅶ)是以形式被树脂吸附,其吸附机理属于综合反应:并测定了吸附过程的热力学函数。 相似文献
3.
研究了用电镀法制取铁-铼高温自润滑合金的可能性。结果表明,电流密度,高铼酸根离子浓度等因素对镀层含铼量和阴极电流效率有较大影响,确定了较适宜的镀液组成和电镀条件。摩擦实验结果表明,铁-铼镀层有高温自润滑的作用,有希望代替整体冶炼的铁-铼合金。 相似文献
4.
在多种配副下测定了Fe-Re合金和Fe(ReO4)3的摩擦因数随温度变化的关系.结果表明:Fe-Re合金及Fe(ReO4)3的润滑行为和配副有关;在相近的试验条件下,它们的摩擦因数随温度变化有相似的趋势。Fe-Re合金在100℃以下及450~600℃间有2个较低的摩擦因数区,分别与自生的铁铼氧化物及高温下因摩擦而生成的Fe(ReO4)3,的润滑作用有关。 相似文献
5.
本文研究了 W-305C 螫合树脂从含铼的 H_2SO_4-(NH_4)_2 SO_4溶液中提取铼的性能.试验结果表明,在 pH=9条件下,该树脂对铼的动态吸附率为99.48%.用8%NH_3·H_2O 与2%(NH_4)_2SO_4混合溶液淋洗铼,其洗脱率为98.92%.经吸附—洗脱操作,溶液铼浓度增大19倍,铼的总收率达98.41%.用红外光谱法探讨了树脂吸附铼的机理. 相似文献
6.
本文研究了用氯化三烷基苄基铵(7407)萃取分离铼钼的工艺条件。结果表明,7407是铼钼分离的有效萃取剂,铼钼分离系数为2362。经3次逆流萃取,铼和钼的萃取率分别为:99.60%和3.37%。用40%硫氰酸铵溶液对富有机进行3次逆流反萃取,铼的反萃率为99%。萃取剂可再生循环使用。 相似文献
7.
用14MeV中子轰击天然锇靶,取道^192Os(n,α)反应生成^189W。利用改进的锇蒸馏装置蒸馏O8O4,完成锇与反应产物的分离;通过四苯砷铼沉淀除去铼。使用HPGe探测器测量了分离的钨样品的γ射线谱,该γ射线谱显示钨样品中杂质元素的去污是令人满意的。 相似文献
8.
在镍、钼、铼共存的混合物中,采用强碱性阴离子交换树脂,用氢氧化钠和硝酸溶液分离铼,铼回收率可达95%以上。 相似文献
9.
H. Berke C. Frech A. Lhamazares O. Blacque H.W. Schmalle C. Adlhart P. Chen 《复旦学报(自然科学版)》2005,44(5):625-626
Ring Opening Metathesis Polymerization (ROMP) is based on the olefin metathesis reaction, which requires transition metal catalysts. Mainly molybdenum, tungsten and ruthenium based catalysts have up to now been used. The “in-between” metal rhenium was only rarely applied in olefin metathesis reactions, and not at all in ROMP processes. We have found that cationic phosphine substituted dinitrosyl rhenium complexes 1a and 1b effectively catalyze ROMP of norbonene, dicyclopentadiene and of cyclooctene. See Fig. 1. 相似文献
10.
Zhao Xinxin Chit-Kay Chu 《复旦学报(自然科学版)》2005,44(5):660-661
The chemistry of dendrimers is a fast developing field and has brought about a tsunami of research activity since Vogtle reported the first preparation in 1978. These hyperbranched macromolecules have grown out of chemists' imagination and have challenged synthetic chemists with their architectural complexity and intriguity. The potentials of these macromolecules are extensive and are synthesized using both organic and inorganic cores from which different scaffoldings are built, and upon which functionalities are attached for specific applications. The synthesis and characterizations of cisplatin and rhenium(Ⅰ) containing PAMAM derivatives will be discussed. 相似文献