碳扩散对非真空热轧不锈钢复合板结合性能的影响

采用非真空热轧方法制备304不锈钢/Q235碳钢复合板材,利用OM、SEM、EDS等研究了不同压下率和轧后冷却方式下复合界面夹杂物、界面组织及力学行为的演变,并分析了C扩散对复合板界面组织形成及结合强度的影响。结果表明,随着轧制压下率的增加,界面夹杂物由块状向线型、连续点状乃至弥散点状分布变化。当压下率较低(28%)时,复合板剪切断裂位于结合界面处,随着压下率增加至47%及以上,复合板断裂位置为脱碳铁素体区。另外,热轧复合板经水冷工艺处理后,由于冷却速率较快,要抑制碳钢侧C元素的扩散,避免复合界面处脱碳区域的形成,从而提高了复合界面的结合强度。     

快中子增殖反应堆燃料元件包壳材料的晶界工程技术应用展望

针对钠冷快中子增殖反应堆(简称快堆) 燃料元件包壳材料316 以及15-15Ti 奥氏体不锈钢, 讨论了通过晶界工程(grain boundary engineering, GBE) 技术进一步提高材料抗辐照肿胀以及抗蠕变性能的可行性. 通过GBE 技术能够大幅增加材料中与孪晶相关的低 重合位置点阵(coincidence site lattice, CSL) 晶界比例. 快堆燃料元件包壳在固溶退火处理后还要经过20% 左右的冷加工变形, 目的是在显微组织中引入大量位错, 吸收由辐照产生的点缺陷, 并增加吸收裂变产物的陷阱. 如果在这样的冷加工变形前大幅提高材料的低∑CSL 晶界比例, 使冷加工变形时的位错滑移在具有特殊取向关系的晶粒间的传播以及位错在特殊结构晶界处的堆积排列发生变化, 那么就有可能使冷加工后位错的分布状态有利于吸收更多的由辐照产生的点缺陷, 提高材料抗辐照肿胀的能力.     

Effect of tin addition on the microstructure and properties of ferritic stainless steel

This article reports the effects of Sn on the inclusions as well as the mechanical properties and hot workability of ferritic stainless steel. Precipitation phases and inclusions in Sn-bearing ferritic stainless steel were observed, and the relationship between the workability and the microstructure of the steel was established. Energy-dispersive X-ray spectroscopic analysis of the steel reveals that an almost pure Sn phase forms and MnS-Sn compound inclusions appear in the steel with a higher Sn content. Little Sn segregation was observed in grain boundaries and in the areas around sulfide inclusions; however, the presence of Sn does not adversely affect the workability of the steel containing 0.4wt% Sn. When the Sn content is 0.1wt%-0.4wt%, Sn improves the tensile strength and the plastic strain ratio and also improves the plasticity with increasing temperature. A mechanism of improving the workability of ferritic stainless steel induced by Sn addition was discussed:the presence of Sn lowers the defect concentration in the ultra-pure ferritic lattice and the good distribution of tin in the lattice overcomes the problem of hot brittleness that occurs in low-carbon steel as a result of Sn segregation.     

Effects of elemental Sn on the properties and inclusions of the free-cutting steel

A new environment-friendly free-cutting steel alloyed with elemental Sn (Y20Sn) was developed to meet the requirements of machinability and mechanical properties according to GB/T8731-1988. The machinability of the steel is enhanced by the segregation of elemental Sn at grain boundaries. The effect of Sn segregation on intergranular brittle fracture at normal cutting temperature from 250℃ to 400℃ is confirmed. The formation mechanism of main inclusions MnS is influenced by the presence of Sn and the attachment of Sn around MnS itself as a surfactant, and this mechanism also explains the improvement in machinability and mechanical properties of the steel. In the steel, the relevant inclusions are mainly spherical or axiolitic, and are uniformly distributed in small volume. Such inclusions improve the machinability of the steel and do not impair the mechanical properties as well. Experimental results demonstrate that the appropriate content of Sn in the steel is 0.03wt% to 0.08wt%, and the remaining composition is close to that of standard Y20 steel.     

Acoustic emission detection of 316L stainless steel welded joints during intergranular corrosion

This study analyzes acoustic emission (AE) signals during the intergranular corrosion (IGC) process of 316L stainless steel welded joints under different welding currents in boiling nitric acid. IGC generates several AE signals with high AE activity. The AE technique could hardly distinguish IGC in stainless steel welded joints with different welding heat inputs. However, AE signals can effectively distinguish IGC characteristics in different corrosion stages. The IGC resistance of a heat-affected zone is lower than that of a weld zone. The initiation and rapid corrosion stages can be distinguished using AE results and microstructural analysis. Moreover, energy count rate and amplitude are considered to be ideal parameters for characterizing different IGC processes. Two types of signals are detected in the rapid corrosion stage. It can be concluded that grain boundary corrosion and grain separation are the AE sources of type 1 and type 2, respectively.     

Morphology,size and distribution of MnS inclusions in non-quenched and tempered steel during heat treatment

This article reports the morphology, size, and distribution evolution of MnS inclusions in non-quenched and tempered steel during heat treatment. The variation of single large-sized MnS inclusions at high temperature was observed in situ using a confocal scanning laser microscope (CSLM). The slender MnS inclusions first changed to pearl-like strings. These small-sized pearls subsequently coalesced and became closer together as the temperature increased. Large-sized MnS inclusions in non-quenched and tempered steel samples with different thermal histories were investigated with respect to the evolution of their morphology, size, and distribution. After 30 min of ovulation at 1573 K, the percentage of MnS inclusions larger than 3 μm decreased from 50.5% to 3.0%. After a 3 h soaking period, Ostwald ripening occurred. Most MnS inclusions moved from the grain boundaries to the interior. The present study demonstrates that heat treatment is an effective method of changing the morphology, size, and distribution of MnS inclusions, especially large-sized ones.     

Titanium effect on the microstructure and properties of laminated high boron steel plates

High-boron steel is an important material used for thermal neutron shielding. The appropriate amount of added boron must be determined because excessive boron may deteriorate the steel's workability. A uniform microstructure can be formed by adding titanium to boron steel. In this study, casting and hot rolling were used to fabricate laminated high-boron steel plates whose cores contained 2.25wt% boron and 0wt%-7.9wt% titanium. The effects of titanium content and hot-rolling and heat-treatment processes on the microstructure and properties of the laminated plates were studied. The results indicated that the optimum titanium content was 5.7wt% when the boron content was 2.25wt%, and that the best overall properties were obtained after heat treatment at 1100℃ for 4 h. The tensile strength, yield strength, and elongation at the specified temperature and holding time were as high as 526.88 MPa, 219.36 MPa, and 29%, respectively.     

Effects of H content on the tensile properties and fracture behavior of SA508-III steel

SA508-Ⅲ steel was charged with different hydrogen (H) contents using a high-pressure thermal charging method to study the effects of H content on the tensile properties and evaluate the H embrittlement behavior of the steel. The results indicate that the ultimate tensile strength remains nearly unchanged with the addition of H. In contrast, the yielding strength slightly increases, and the elongation significantly decreases with increasing H content, especially at concentrations exceeding 5.6×10-6. On the basis of fractographic analysis, it is clear that the addition of H changes the fracture mode from microvoid coalescence to a mixture of river patterns and dimples. Carbides are strong traps for H; thus, the H atoms easily migrate in the form of Cottrell atmosphere toward the carbides following moving dislocations during tensile deformation. In addition, stress-induced H atoms accumulate at the interface between carbides and the matrix after necking under three-dimensional stress, which weakens the interfacial bonding force. Consequently, when the local H concentration reaches a critical value, microcracks occur at the interface, resulting in fracture.     

一种新型结构材料S280

 S280 是一种超高强度不锈钢, 采用低碳马氏体相变强化和时效强化叠加, 靠析出强化获得所需的强度。使用状态下的基体组织为低碳板条马氏体, 主要强化相为Fe₂Mo 等, 抗拉强度σ_b为1920～1930 MPa, 断裂韧度K_IC为95～100 MPa √m, 具有比300M 和AerMet100 更好的耐腐蚀性能, 主要用于抗腐蚀性能要求高的超高强度构件。     

基于OpenSees的钢管混凝土柱-钢梁错层节点抗震性能有限元分析

为研究钢管混凝土柱-钢梁错层节点抗震性能,基于已有试验研究成果,利用OpenSees有限元软件,对钢管混凝土柱-钢梁错层节点进行数值模拟,将模拟结果与试验结果进行对比,两者较吻合。通过数值模拟,分析了轴压比、混凝土强度等级和钢材强度等参数对钢管混凝土柱-钢梁错层节点抗震性能的影响。结果表明:在轴压比为0.3～0.7范围内,随轴压比增大,结构承载力降低明显;随混凝土强度等级提高,试件极限承载力特征值增大较为明显,最大增幅达9.39%;通过对比发现,合理提高钢材强度可以有效增加结构承载力和延性,当模拟计算Q345钢材时,试件极限承载力增加了26.08%,破坏点位移值增加了8.41%。