氨基六辛氧基不对称酞菁锌的光动力学性质研究

采用4-氨基邻笨二甲腈与4，5-二辛氧基邻苯二甲腈合成了单氨基六辛氧基不对称酞菁锌配合物，采用元素分析、激光解吸电离飞行时间质谱（TOF-MS）、IR对配合物进行了表征，并采用电子吸收光谱法研究了配合物在DMF，THF溶液中的动力学性质。     

The ring-substituted phthalo-cyanines and its metal com-plexes: Crystal structure of 1,4, 8,11,15,18,22,25-octa-butoxyphthalocyani-natocopper(Ⅱ)

Crystal structure of 1, 4, 8, 11, 15, 18, 22, 25-octa-butoxyphthalocyaninato- copper (Ⅱ) (1) was determined by X-ray diffraction methods. The crystal system is mono-clinic, space group is P2₁/c, Z = 4, a = 1.3741(1) nm, b = 2.6737(1) nm, c = 1.6690(1) nm, β= 101.278(1)°. The steric congestion between the neighbouring butoxyl groups causes the distortion of the ring core of phthalocyanine (Pc) into a saddle shape conformation. In the crystal structure, molecules stack along a axis forming one-dimensional packing structure and there are two molecular overlap types which appear in turn with different distances between molecules, overlap area and angle.     

多核金属酞菁催化下的环己烯环氧化反应

尝试使用９种多核金属酞菁催化环己烯的环氧化反应，结果表明它们对环已烯在氧气为氧源的环氧化反应有催化作用。     

固相法合成铜酞菁的研究

以苯酐、尿素、氯化铜、钼酸铵为原料,用固相法合成了铜酞菁.通过加入添加剂NS,使其产品质量达到溶剂法生产的水平,并且大大降低了可溶性铜的含量.该法具有工艺简单,生产稳定、质量好、成本低等优点     

酞菁铁—表面活性剂薄膜修饰电极及其催化性能

将酞菁铁（ＦｅＰｃ）掺入阳离子表面活性剂双十二烷基二甲基溴化铵（ＤＤＡＢ）的氧仿溶液，并涂布于热解石墨电极表面，待氯仿挥发后即制得ＦｅＰｃ－ＤＤＡＢ薄膜电极，循环伏安实验表明，在ＫＢｒ溶液中该薄膜电极有２对还原氧化峰，第１对峰的Ｅｐｃｌ＝－０．６４Ｖ，Ｅｐａｌ＝－０．２９Ｖ（ｖｓ．ＳＣＥ）第２对峰的Ｅｐｃ２＝－１．０４Ｖ，Ｅｐａ２＝－０．９４Ｖ着重探讨了第２对峰的电化学行为，估计了该体系的电化学参     

酞菁铜硅胶固定相上分离嘧啶核苷

利用合成的磺化酞菁铜硅胶固定相,在反相ＨＰＬＣ条件下对３种结构极为相似的嘧啶核苷进行分离。同时研究了酸、有机修饰剂用量、流动相流速等对分离效果的影响。     

Synthesis, spectral properties of aluminum polymeric phthalocyanine carboxyl with low aggregation in aqueous solution

A water soluble poly-[tetrakis-（2,3-dicarboxylate phenoxy） methyl methan] aluminum phthalocyanine （AIPPc.（COOH）x） has been synthesized from the cyclization of tetranuclear phthalonitrile and succes- sive hydrolysis of cyano in alkaline solution, The absorption spectra showed low aggregation of this compound in pH 9.18 buffer than that of existing water soluble phthalocyanine compounds. With the addition of Triton X 100, an enhancement of fluorescence emission with quantum yield from 0.4 to 0.83 was observed; contrarily, it was thoroughly quenched by the addition of CATB in suit, A longer life time of singlet state was also detected in presence of Triton X 100. The result indicates that AIPPc.（COOH）x is desired to investigate in fluorescent probe or in fluorescence imaging diagnose.     

负载CoPc的微-介孔Cu-BTC的制备及其催化性能

在合成的具有介孔结构的[Cu3(BTC)2(H2O)3]n(Cu-BTC)试样b上,浸渍负载四取代硝基酞菁钴(Co Pc),制备不同负载量的催化活性比较高的复合型催化剂试样c-f。采用X线粉末衍射仪(XRD)、N2吸附-脱附、扫描电子显微镜(SEM)等对复合型催化剂的结构和形貌进行了表征。研究对比了试样Co Pc、试样a、试样b以及复合型催化剂催化氧化苯甲醇的催化活性。结果表明:负载Co Pc的复合型催化剂催化能力明显比其他催化剂催化氧化苯甲醇的能力高,当Co Pc负载量为10.2%时(即试样e),于60℃反应2 h苯甲醛收率最高,产率达42.9%。     

新型不对称酞菁的制备与表征

以4-(对叔丁基苯氧基)邻苯二腈、1,3-二亚胺基异吲哚啉和二水乙酸合铜为原料合成了2(3)-(对叔丁基苯氧基)酞菁铜,并通过元素分析、红外、紫外-可见光谱和质谱的表征证实产物即为目标化合物.     

新型两亲性不对称酞菁锌的合成及光谱性质

采用统计缩合法合成了2种新型两亲性3∶1不对称酞菁锌,1-(对羟甲基苯氧基)-六烷氧基酞菁锌(RO)6(HOCH2phO)PcZn(II)(R=n-C4H9;n-C5H11),并用UV-Vis光谱、元素分析、IR光谱和TOF-MS对其结构和组成进行了表征.考查了其在有机溶剂中的溶解性,测定并研究了它们在DMF,DMSO及DMSO与H2O的混合溶剂中的电子吸收光谱和荧光光谱特征.