Fracture behavior and microstructure analysis of Al2O3–MgO–CaO castables for steel-ladle purging plugs

Three different castables based on the Al₂O₃–MgO–CaO system were prepared as steel-ladle purging plug refractories: corundum- based low-cement castable (C-LCC), corundum-spinel-based low-cement castable (C-S-LCC), and corundum-spinel no-cement castable (C-S-NCC) (hydratable alumina (ρ-Al₂O₃) bonded). The fracture behavior at room temperature was tested by the method of “wedge-splitting” on samples pre-fired at different temperatures; the specific fracture energy G′_f and notched tensile strength σ_NT were obtained from these tests. In addition, the Young’s modulus E was measured by the method of resonance frequency of damping analysis (RFDA). The thermal stress resistance parameter R′′′′ calculated using the values of G′_f, σ_NT, and E was used to evaluate the thermal shock resistance of the materials. According to the microstructure analysis results, the sintering effect and the bonding type of the matrix material were different among these three castables, which explains their different fracture behaviors.     

Thermodynamic simulation of the effect of slag chemistry on the corrosion behavior of alumina–chromia refractory

The corrosion behavior of alumina–chromia refractory against two kinds of industrial slags (coal slag and iron smelting slag) at 1550°C was investigated via thermodynamic simulations. In the proposed simulation model, the initial slag first attacks the matrix and surface aggregates and subsequently attacks the inner aggregates. The simulation results indicate that the slag chemistry strongly affects the phase formation and corrosion behavior of the refractory brick. Greater amounts of alumina were dissolved and spinel solid phases formed when the brick interacted with iron smelting slag. These phenomena, as well as the calculated lower viscosity, may lead to much deeper penetration than that exhibited by coal slag and to more severe corrosion compared to that induced by coal slag. The thermodynamic calculations well match the experimental observations, demonstrating the efficiency of the proposed simulation model for evaluating the corrosion behavior of alumina–chromia refractory.     

半序概率度量空间中增算子的不动点定理

不动点理论是非线性泛函分析的重要组成部分,对非线性微分积分方程的研究有重要意义.半序方法是研究非线性算子方程问题的主要方法之一,在概率度量空间中通过泛函引入半序,并利用此半序研究概率度量空间中增算子的不动点的存在性问题,得到一些不动点存在性定理.     

沉积环境与多元统计综合分析法

本文首先根据地震资料提取了十二种地震参数,然后通过对LH油田TZ地区沙三上段下部地层进行沉积环境分析,确定了可能存在的沉积相类型,并用有序样品聚类的方法对过井和井旁地震测线按沉积相个数进行分割,由此而建立了该区各类沉积相的判别函数。通过这些判别函数,用逐步判别分析的方法,对该区其它地震测线的参数进行判别分类,最后搞清了研究区目的层的沉积相展布。通过分析和计算证明,这一方法对有地震资料的盆地或地区进行沉积相的划分,是行之有效的。     

溅射气压对Al2O3薄膜的结构与电性能的影响

以纯铝为靶材,在不同溅射气压下采用直流磁控反应溅射方法制备了Al2O3薄膜。用扫描电镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)、台阶仪、绝缘电阻仪和精密阻抗分析仪等分析了薄膜的表面形貌、化学成分、结构、薄膜厚度和电学性能。结果表明,随着溅射压力增大,薄膜的颗粒尺寸和厚度减小,组织细密;薄膜的化学成分主要为Al、O元素,铝氧原子比接近2:3,在250℃的低温下,溅射态的Al2O3薄膜均为非晶结构,溅射压力对Al2O3薄膜的结构和化学成分影响不明显;溅射压力为1.0Pa时的薄膜,其电阻和电阻率较大,介电性能相对较好。     

每一个具有条件(S)的BCK—代数是一个可换负偏序幺半群的剩余元集

本文证明了每一个具有条件(S)的BCK—代数诱导一个交换负偏序剩余幺半群,反之每一个交换负偏序剩余幺半群诱导一个具有条件(S)的BCK—代数。由此进一步说明每一个具有条件(S)的BCK—代数是交换负偏序幺半群的剩余元集。     

氧化铝颗粒—耐热钢基复合材料的高温磨损特性

采用化学气相沉积技术对氧化铝颗粒表面进行涂层处理,通过负压铸渗工艺制备了氧化铝颗粒－耐热钢基复合材料,并对其在９００℃下的高温磨料磨损特性进行了研究,结果表明：耐热钢在高温下的磨损主要是由磨料的滚压形成的挤出唇,翻边脱落所引起,磨损量较大,而复合材料高温磨损时颗粒突出于基体,承受载荷多,阻碍了磨粒对基体的损伤,因而抗磨性较好,其高温耐磨性是基体材料的３．３倍多。     

双钙钛矿型Ba2YSbO6的水热合成和结构表征

报道了温和条件下双钙钛矿型复合氧化物Ba2YSbO6的水热合成,并通过XRD、IR、ICP、XPS对产物物相、组成、结构、锑离子价态等进行了表征.Ba2YSbO6产物为立方钙钛矿结构,属于Fm3m空间群,晶胞参数为a=0.840955(7)nm,V=0.594727(8)nm3,Y和Sb呈岩盐型有序排列,锑为 5价.     

铝基水溶胶体的制备和特性研究

讨论了制备氧化铝基连续陶瓷纤维用胶体的特点和现状,对实验室制备过程进行了研究,获得了有良好粘性特征的水溶性胶体,对胶体的浓度-粘度、温度-粘度参数进行了测定,结果表明该水溶性无机高分子溶胶属于切力变稀的假塑性流体,并初步制备出直径为（10～20）μm,单丝抗拉强度达到2300 MPa的纤维。     

中空介孔二氧化硅在生物医学领域中的应用研究进展

中空介孔二氧化硅具有中空腔结构、低密度、大比表面积、良好的生物相容性和稳定性以及表面易修饰等理化特性,在生物医学领域中受到广泛关注.该文主要概括了近年来功能化中空介孔二氧化硅在药物控释、靶向和生物成像中的应用研究进展,同时对目前中空介孔二氧化硅在临床应用中面临的问题进行了分析.