金属载体上原位合成ZSM-5分子筛

以正硅酸乙酯(TEOS)和NaAlO2作为硅源和铝源，四乙基氢氧化铵(TEAOH)作为模板剂，用水热合成法在经表面处理的金属载体上原位合成了ZSM-5分子筛涂层，并采用BET、XRD、SEM等表征技术，研究了金属材料的处理方法、合成时间及次数等因素对ZSM-5分子筛涂层的结晶度、比表面积、覆盖率和涂层热牢固度的影响。结果表明，用原位合成法可以在金属载体上制得结晶度高、热牢固度好的ZSM-5涂层。     

<Emphasis Type="Italic">In situ</Emphasis> synthesis of TiC reinforced Cu<Subscript>47</Subscript>Ti<Subscript>34</Subscript>Zr<Subscript>11</Subscript>Ni<Subscript>8</Subscript> bulk metallic glass composites

In situ synthesized TiC particles and β-Ti dendrites reinforced Cu47Ti34Zr11Ni8 bulk metallic glass (BMG) composite ingots were prepared by the suction casting method.The ingots with diameters from 1 up to 4mm were successfully obtained. It was shown that introducing TiC micro-sized particles into the amorphous matrix did not disturb the glass forming ability (GFA) of the matrix,while the yield strength and ductility could be well improved.The phase constitution, microstructure and elements distribution in the composites were studied by OM, XRD, SEM and EDS.It was shown that the in situ synthesized TiC particles acting as heterogeneous nucleation sites promoted the precipitation of β-Ti dendrites, resulting in the formation of the TiC particles and β-Ti dendrites co-reinforced BMG composites. The compressive tests were employed to probe the yield strength and ductility of BMG composites.     

低聚壳聚糖金属卟啉络合物的制备及抗肿瘤细胞活性研究

制备了低聚壳聚糖金属（铜、钴）卟啉络合物,通过紫外-可见光谱和红外光谱对其进行了表征,采用SRB细胞染色法研究了低聚壳聚糖金属（铜、钴）卟啉络合物对人体肝癌细胞Bel-7721的毒活性.结果表明,系列化合物均对肝癌细胞Bel-7402有较强的抑制生长活性,IC50值均小于100μg/mL,在10~30μg/mL范围内,是一类具有应用前景的抗肿瘤药物前体.     

金属防热瓦温度及发射率的测量

为了解决金属防热瓦在连续加热过程中热边表面温度和发射率的测量问题,基于多光谱辐射测温的参考温度数学模型,提出了一种数据处理方法。该方法假设材料的光谱发射率在选定的光谱处与温度有近似相同的线性关系,通过处理两个不同温度点处的多光谱测量数据,从而得到防热瓦的真温及光谱发射率。采用多光谱辐射高温计测量了某种防热瓦在900-1300℃的温度范围内的辐射,并进行数据处理。实验结果表明:只要温度估计初值与真实情况的误差在±200℃以内,即可得到较好的计算温度值和计算发射率值,测量不确定度在2%以内。     

锆合金腐蚀与防护研究进展

锆合金以其优异的核性能和生物相容性被广泛应用于民用发电反应堆、核动力航空母舰、核潜艇、空间飞行器的结构材料以及医用材料，在苛刻环境下服役的锆合金同样面临腐蚀失效的风险。由于材料本身服役环境的特殊性，使得锆合金腐蚀研究的模拟测试难度加大，诸多疑问难以得到有效解答。锆合金的腐蚀形式包括均匀腐蚀、疖状腐蚀、应力腐蚀以及微生物腐蚀，其腐蚀也受材料成分、热处理工艺、表面粗糙度、氧化膜成分、溶液的pH值、辐照、热流水化学环境以及温度等因素的影响，防护措施包括涂层和缓蚀剂等方式。为进一步改善锆合金的耐蚀性能，未来可从以下几方面展开研究：1)锆合金基体中固溶元素的浓度；2)第二相元素类型、晶粒尺寸及分布；3)氧化膜的生长机制；4)细菌附着方式和生物被膜生长行为等。     

离子注入过程中金属间化合物的生长模型

给出了在离子注入过程中金属间化合物生长的一个数学模型。在准静态近似下,利用分区处理和引入快、慢变量的方法,给出了该模型的近似解。得到了生长速率与微缺密度、注量率、热发射率之间的定量关系。     

水电站用爆破膜代替调压井的过渡过程和工程措施

水电站用爆破膜代替调压井新技术已成功地应用于多个水电站并取得显著的经济效益，简述了爆破膜工作原理，水力过渡过程数据模拟，并介绍了干水电站应用实例。     

N-cadherin detected in the membrane fraction of lens fiber cells

Summary N-cadherin was identified as a glycoprotein present in the fiber cell membranes of frog, chick, bovine, rabbit and human lenses. The molecular size of N-cadherin varies with the species. Homogenization of the chick lens in the presence of Ca²⁺ resulted in a decrease in the concentration of N-cadherin. This suggests that the lens contains a Ca²⁺-activated protease which can act on N-cadherin.     

Formation and biocorrosion behavior of Zr-Al-Co-Nb bulk metallic glasses

Ni-and Cu-free Zr-Al-Co-Nb glassy alloys with different Nb and Co contents were synthesized by melt spinning and copper mold casting.The effects of Nb addition to partially replace Co in the Zr55Al20Co25 glassy alloy on the glass-forming ability,thermal properties,in-vitro biocorrosion behavior and surface wettability of the metallic glasses were investigated.Although addition of Nb up to 5 at.% slightly decreased the supercooled liquid region and the glass-forming ability(GFA),the alloys could be casted in a bulk glassy rod form with diameters up to 3mm.The Zr-Al-Co-Nb glassy alloys were spontaneously passivated with low passive current densities in phosphate buffered saline and Hanks’ solution.Substitution of "toxic" Co by Nb is effective in improved the corrosion resistance of the Zr-Al-Co glassy alloy.Water contact angle measurements showed that Nb addition increased the hydrophilicity of the glassy alloys,which may enhance cell adhesion of the alloys in biomedical applications.     

磁场引导水溶还原法制备磁性金属纤维

提出了用磁场引导水溶还原法制备磁性金属纤维的新思想，分析了用这种方法制备磁性金属纤维的机理和动力学过程，给出了实验结果．实验表明，磁场引导水溶还原法适合于制备磁性金属纤维，且纤维的直径在μｍ和亚μｍ数量级．