废弃混凝土代替天然石灰石煅烧水泥熟料实验

从4个不同地点取得4个以破碎石灰石为粗集料的废弃混凝土样品,破碎、分离,获得以石灰石为主的颗粒,取代天然石灰石作为钙质原料煅烧出4个波特兰水泥熟料样品,并与重庆拉法基水泥厂生产的熟料和市售水泥样品进行对比.研究结果表明:废弃混凝土熟料的4种主要矿物的XRD特征峰明显;游离CaO低于1%;可以用其制备出52.5级硅酸盐水泥.     

萘酚磺酸类偶氮化合物酰氯化研究

以萘酚磺酸类偶氮化合物酸性橙7为原料,氯化亚砜为酰氯化试剂,N,N-二甲基甲酰胺(DMF)为催化剂,合成重要的染料中间体磺酰氯化合物.选择不同极性试剂作为酰氯化反应的溶剂,考查了不同溶剂对酰氯化收率和选择性的影响.并探讨了DMF在反应体系中的作用以及酰氯化反应的机理;其中以苯、甲苯和氯化亚砜作溶剂,反应选择性好,收率均高于89%.此外,鉴于磺酰氯在质谱与核磁分析中的不稳定性,以稳定的磺酰胺分析代替直接的磺酰氯分析,间接地证明了磺酰氯的分子结构.     

用于公路桥梁可靠性评估的车辆荷载多峰分布概率模型

通过对京沪高速公路车辆运行状况的实测和统计分析,发现由于汽车工业的发展以及超载现象的存在,实测的车辆荷载呈现出多峰分布的特性,难以用传统的单峰概率分布模型来描述.利用极值型Ⅰ分布函数和正态分布函数的加权和,拟合得到了由轻型车辆、普通车辆和重型(含超载)车辆所组成的多峰型车辆荷载的概率分布函数.通过滤过复合Possion过程和滤过复合Weibull过程分别对一般运行状态和密集运行状态下的车辆荷载过程进行了模拟.最终以后续服役期内轻型车辆、普通车辆和重型(含超载)车辆荷载最大值分布的0.95分位值作为桥梁在剩余可靠度研究的评估荷载.该多峰型车辆荷载模型更符合实际,提高了桥梁剩余可靠度评估的准确性和合理性.     

相转移法合成哒嗪类糖苷

本文采用相转移法,使乙酰基-α-D-溴代糖1(A-C)与6-(4-甲氧基)苯基-3(2H)-哒嗪酮2以及6-(4-羟基苯基)-4,5-二氢-3(2H)-哒嗪酮5反应合成了3(A,C)及6(A,B)四个乙酰基糖苷化合物.其中3A经氨解脱去保护基又得到一个化合物4A′.其结构被IR、1HNMR和元素分析所证实.     

Atmospheric heterogeneous reaction of acetone: Adsorption and desorption kinetics and mechanisms on SiO2 particles

Acetone plays an important role in photooxidation processes in the atmosphere. Up to date, little is known regarding the heterogeneous fate of acetone. In this study, the adsorption and desorption processes of acetone on SiO2 particles, which are the major constituent of mineral dust in the atmos-phere, have been investigated for the first time under the simulated atmospheric conditions, using in situ transmission Fourier transform infrared spectroscopy. It is found that acetone molecules are adsorbed on the surfaces of SiO2 particles by van der Waals forces and hydrogen bonding forces in a nonreactive and reversible state. The rates of initial adsorption and initial desorption, initial uptake coefficients and adsorption concentrations at equilibrium have been determined at different relative humidity. The presence of water vapor cannot result in the formation of new substances, but can decrease the adsorption ability by consuming or overlapping the isolated OH groups on the surfaces of SiO2 particles. In the desorption process, a considerable amount of acetone molecules will remain on SiO2 particles in dry air, whereas acetone molecules are almost completely desorbed at a high relative humidity. In order to evaluate the role of heterogeneous reactions of acetone and other carbonyl compounds in the atmosphere, a new model fitting the atmospheric conditions is needed.     

Progress and prospect for high temperature single-phased magnetic ferroelectrics

Magnetic ferroelectrics are one of the most important functional materials. The present bottleneck limiting applications of them is lacking of high-temperature single-phased ferromagnetic-ferroelectric multiferroics with strong magnetoelectric coupling effect. Here, those progresses of the mechanism for coexistence of ferroelectric and magnetic order, experimental and theoretical studies on single-phased magnetic ferroelectrics, and the relationship between magnetic structure and crystal symmetry are summarized. With examples of BiFeO3, BiMnO3 and Bi2FeCrO6, the difficulties encountered in this field are analyzed. At last, some prospects to develop high-temperature single-phased ferromagnetic-ferroelectric multiferroics are also presented.     

个体保单在两种分布模型下的平均索赔额

本文在索赔次数服从混合Poisson分布与复合Poisson—Geometric分布的基础上,当个体保单索赔额服从指数分布时,给出了累计索赔额服从的分布及个体保单的平均索赔额表达式．     

铁氧化合物对多孔陶瓷滤料表面改性的研究

通过液相沉积、多次涂层法研究了陶瓷滤料的改性.用均匀试验设计方法优化了改性工艺,并对改性滤料的铁覆盖量、抗酸碱和抗机械耐磨性能、比表面积、表面形貌和铁氧粉末的物相组成进行了表征分析.结果表明,2号样品改性工艺为最佳,其比表面积、铁覆盖量、抗酸碱和抗机械耐磨铁脱落率最大或最少,分别为4.987 m2/g、12.181 2 mg/g、0.016 22%、0.015 09%、0.230 7%,铁涂层的主晶相为α-Fe2O3,为多孔结构.改性滤料的这些特性为增强其除污能力奠定了基础.图5,表1,参8.     

复合型英语人才的培养模式研究

伴随着国际化、市场化进程的加速,我国高等教育改革和发展面临着前所未有的机遇,同时也面临着空前的考验。在这种形势下,针对我国英语教育存在的实际问题,必须加大英语专业复合型人才的培养力度,使学生的综合素质进一步提高,使之适应社会发展的需要。     

邯郸某商务楼CFG桩复合地基的设计与施工

以邯郸文化广场商住楼CFG桩工程为例,介绍了CFG桩复合地基的设计计算和施工方法.通过静荷载试验和对建筑物沉降的观测,复合地基承载力和沉降变形均满足要求.