纳米多孔硅基薄膜的常压等离子体化学气相沉积过程研究

采用常压等离子体化学气相沉积(APECVD)的方法制备了带有新颖结构和特殊蓝紫光(400 nm左右)发光特性的硅基薄膜.通过在自行研制的等离子体反应装置中通入按100:1:1的体积比进行配比的SiH<,4>:H<,2>: Ar混合气体进行APECVD,在加负偏压条件下获得了由Si基组成的絮状多孔纳米结构薄膜.通过等离子体发射光谱测定了沉积过程中的电子温度在2.2eV左右,扫描电子显微镜(SEM)观测薄膜表面形貌后肯定了偏压对薄膜纳米结构的形成起着重要的作用.     

IR study on hydrogen bonding in epoxy resin–silica nanocomposites

The chemical and physical interactions between ingredients in composites play an important role in the improvement of service properties. The nucleophilic addition between polymer and isophoron diisocyanate molecules was monitored by FT-IR technique. The intensity loss of isocyanate absorption band in conjunction with the intensity growth of carboxyl absorption band indicates the progress of reaction. FT-IR spectroscopy was also adopted to examine the intermolecular hydrogen bonding of epoxy resin with silica as well as intramolecular one within polymer matrix. The vibration frequency of carboxyl group （-C=O） and hydroxyl group （-OH） shifts from 1736 to 1728 cm^-1and 3420 to 3414 cm^-1, respectively, indicating the occurrence of hydrogen bonding between -C=O and -OH. The vibration frequency of Si-OH moves from 3435 to 3414 cm^-1, suggesting the involvement of silica. Whereas the vibration frequency of pending -OH in polymer chain moves from 3435 to 3420 cm^-1 or 3414 cm^-1, proposing that this kind of interaction can also happen within polymer matrix.     

硅材料中硼杂质扩散综述

对国内近20年来扩散技术的进展进行了介绍,引用不同科研人员的研究成果说明以下结论:硼扩散仍是目前扩散中最常用的扩散方法;乳胶源扩散比普通的硼扩散容易实现深扩散;乳胶硼铝扩散必须在抛光前进行,可采用两次扩散的方法来代替。     

硅基高非线性递增光纤的绝热脉冲压缩研究

本文提出一种利用硅基高非线性递增光纤(silicon-based high Nonlinearity Increasing Fiber)实现脉冲绝热压缩的新方案.数值计算结果表明:通过选取合适的光纤参址,可使脉冲在硅基高非线性递增光纤中的压缩过程基本符合绝热压缩的要求.     

In situ measured growth rates of bainite plates in an Fe-C-Mn-Si superbainitic steel

The growth rates of bainite plates in an Fe-C-Mn-Si superbainitie steel were investigated by in situ observation. The lengthening rates of ferrite bainite during both cooling and isothermal holding processes were observed and the growth rates of bainite plates nucleating at grain boundaries, within grains and on preformed bainite were measured. It is indicated that the lengthening rates of bainite plates during the cooling and isothermal processes were different, and that the growth rates of bainite plates nucleating at different types of sites also demon- strated diversity. The bainite plates initiating at [vain boundaries during cooling grew the fastest, while the plates nucleating on preformed bainite did the slowest. However, the growth rate of the bainite plates nucleating at grain boundaries during isothermal transformation de- creased the most, whereas the bainite plates initiating within grains grew the fastest. In addition, the growth rate of ferrite bainite in the study supported the diffusion transformation mechanism of bainite from the viewooint of ~rowth rate.     

衬底温度对掺杂硅基薄膜结构的影响

采用双离子束溅射沉积法制备的掺杂硅基Si-SiO2和Al-Si-SiO2薄膜,实验中通过改变基片温度获得不同条件下的样品.测试发现,当基片温度低于450℃时,两种薄膜的XRD谱图中并未有明显的晶态峰存在,说明薄膜中并未形成晶态结构,样品的选区电子衍射花样的TEM测试结果也证明如此;当基片温度高于450℃时,XRD谱图中才呈现出几个微弱的晶态峰,说明薄膜中可能有Si或A1的晶粒出现.样品的XPS测试结果表明,Si-SiO2薄膜在温度较低时表现为欠氧富硅的结构SiOx(x ＜2),薄膜中的Si主要是以氧化物的形式存在,当基片温度高于450℃时,根据Si的XPS特征峰的硅双峰结构能够确定薄膜中的硅形成了较显著的硅的原子团簇.而对于Al-Si-SiO2薄膜,Al主要是以单质铝的形式存在,Si是以氧化物的形式存在,实验中可以通过改变靶材中铝片的面积大小,改变薄膜中的铝和硅的含量.     

论磨石、毛刷组合对硅晶体表面处理的影响

抛光工序作为晶体硅太阳能行业重要的一个工序,将硅锭经过钢线摩擦切割成硅块后,硅块表面变得粗糙不平,必须经过表面抛光才能进行硅片的切割。硅块表面的抛光直接影响硅片切割的质量。硅块在抛光过程中的磨石1有粗砂轮、细砂轮、金刚砂砂轮、毛刷2四种抛光材质。该文对四种材质磨石分别比较。首先对比粗砂轮、金刚石砂轮在处理硅块表面的＂鼓肚＂和大锯痕切割现象的差异,确定哪种材质效果更好;再使用此种材质砂轮分别配合细砂轮和毛刷精抛,通过抛光后粗糙度对比确定哪种材质精抛效果好。     

Keggin型Si-Mo-V杂多酸的合成与表征

采用改良的分步加酸、乙醚-丙酮萃取的方法合成了5种Keggin型硅钼钒杂多酸,分别用红外光谱(IR)检测到700~1 100cm-1范围内的4个特征吸收峰,X射线衍射(XRD)表征了硅钼钒杂多酸的二级结构,通过热重分析(TG)确定了杂多酸中结晶水的数目.     

镧对硅纳米管生长的影响机制

采用热蒸发法,在初始反应物硅(Si)及一氧化硅(SiO)混合粉末中加入镧(La)粉,能够成功地制备出硅纳米管.La粉作为一种特殊的气化调节剂,可以通过调节气化SiO的浓度来控制一维硅纳米材料的形貌,而且在最终的产物中并没有发现任何杂质.基于三相界面优先生长模型及氧化辅助生长理论来解释这种可控生长.采用透射电子显微镜(TEM)来分析产物形貌,并通过电感耦合等离子体原子发射光谱(ICP-AES)及X射线衍射(XRD)分析产物及剩余物成分.     

硅铝质掺合料对含石灰石组分水泥基材料硫酸盐侵蚀的影响

通过腐蚀试验后试件的外观形貌和强度变化、腐蚀物相分析,研究较低环境温度下硅铝质掺合料对含石灰石组分水泥基材料硫酸盐侵蚀的影响。结果表明：随着硅铝质掺合料掺量的增加,含石灰石粉硅酸盐水泥试件外观完整性明显提高,强度损失率逐渐降低;当硅铝质组分掺量为15%、30%时,矿粉对含石灰石组分水泥基材料抗硫酸盐侵蚀的改善作用明显优于相同掺量的粉煤灰;硅铝质组分能够延缓较低环境温度下含石灰石粉硅酸盐水泥的硫酸盐侵蚀,抑制腐蚀物相碳硫硅钙石的生成。