超声辐照降解水中三氯乙烯主要影响因素

采用超声辐照新技术降解水中三氯乙烯(TCE),实验研究了影响TCE降解速率的主要因素.结果表明:TCE降解率随初始浓度增加而减小,呈现准一级反应动力学特性;增加超声波输出功率可以明显提高TCE降解率,在60 min内TCE的去除率可达90%以上;空化气体对TCE降解率的影响顺序为Ar>O2 ～空气;自由基清除剂的加入对TCE的降解效果稍有影响,表明TCE的超声降解主要是在空化泡内以及空化泡的气-液界面内的高温热解,同时在超声降解TCE过程中也可能伴随着自由基氧化作用.     

Characterstics of seasonal variations of leaf n-alkanes and n-alkenes in modern higher plants in Qingjiang, Hubei Province, China

On the basis of GC and GC-MS analyses, the seasonal variation of leaf lipids is observed in five plant species in Qingjiang in Hubei Province. The CPI values （carbon preference index） of n-alkanes decrease gradually from May to November, though the carbon number distributions and the predominant carbon number in an individual species keep unchanged. The declined CPI values might be caused by the leaf fading, which is further supported by a comparison of the defoliated leaves with the fresh leaves. This observation infers the CPI values of n-alkanes in Quaternary sediments can be used as a tool to index the humification, and thus the climatic and the environmental conditions. The plants analyzed here show a remarkable difference in n-alkanes abundance, suggesting their differential contribution to the n-alkanes identified in sediments. The abundance and the compound species of the n-alkenes detected in the plant leaves change greatly with the seasons due to the influence of temperature, with the least compounds being identified in August.     

Three-dimensional fluorescence spectral characteristics of dissolved organic carbon in cave drip waters and their responses to environment changes: Four cave systems as an example in Guizhou Province,China

Understanding the responses of fluorescence spectral characteristics of cave drip waters to modern environment and climate changes is key to the reconstructions of environmental and climatic changes using fluorescence spectral characteristics of speleothems. The fluorescence spectral characteristics of dissolved organic carbon （DOC） in four active cave systems were analyzed with a three-dimensional （3D） fluorescence spectral analysis method. We found that the fluorescence types of DOC were mainly of fulvic-like and protein-like fluorescences, both in soil waters and cave drip waters. The intensity of fulvic-like fluorescence was positively correlated with the concentrations of DOC, suggesting that the DOC of cave drip waters was derived from the overlying soil layer of a cave system. Compared with the other cave systems, the variation range of the excitation and emission wavelengths for fulvic-like fluorescence of cave drip waters in Liangfeng cave system that had forest vegetation was smaller and the excitation wavelength was longer, while its fluorescence intensity varied significantly. By contrast, the excitation and emission wavelengths and fluorescence intensity for that in Jiangjun cave system that had a scrub and tussock vegetation showed the most significant variation, while its excitation wavelength was shorter. This implies that the variation of vegetation overlying a cave appears to be a factor affecting the fluorescence spectral characteristics of cave drip waters.     

Semi-crosslinked polyacrylamides as high-resolution and dynamic self-coating sieving matrices for protein capillary electrophoresis

This paper describes non-gel capillary sieving electrophoresis employing semi-crosslinked polyacrylamide as a high performance and low viscous replaceable separation matrix for separation of non-denatured protein separation. Arising from the fine sieving and dynamic coating ability of this polymer, a mixture of basic proteins lysozyme, cytochrome C, ribonuclease A, and trypsin was resolved with excellent reproducibility. Mixing different semi-crosslinked polyacrylamides together further improves the separation. The separtion mechanism was analyzed. With network structure developed to an intermediate state between crosslinked gel and linear polymer solutions, these semi-crosslinked polyacrylamide polymers demonstrate a promise as a new class of size sieving separation medium, not only in capillary electrophoresis, but also in microfluidic chip separation schemes.     

Super-plasticity of Zr<Subscript>64.80</Subscript>Cu<Subscript>14.85</Subscript>Ni<Subscript>10.35</Subscript>Al<Subscript>10</Subscript> bulk metallic glass at room temperature

Generally, bulk metallic glasses （BMGs） exhibit a very limited plastic deformation under a compression load at room temperature, often less than 2% before fracturing. In this letter, through an appropriate choice of BMGs＇ composition, an amorphous rod of Zr64.80Cu14.85Ni10.35Al10 with a diameter of 2 mm was prepared by using copper mold suction casting. X-ray diffraction and differential scanning calorimetry were utilized to determine its structure and thermal stability, and the uniaxial compression test was adopted to study its plastic deformation behavior at room temperature simultaneously. The results showed that the glass transition temperature and onset temperature of the exothermic reaction of the amorphous rod were 646 and 750 K, respectively, and its micro-hardness was 594.7 Hv. During compression, when the engineering strain and engineering stress arrived at 9.05% and 1732 MPa, respectively, i.e., the true strain and true stress reached 9.42% and 1560 MPa, respectively, the amorphous rod started to yield. After yielding, with the increase of load, the strain increased and the glass rod ulti- mately were compressed into flake-like form. Although the maximum engineering strain was larger than 70%, i.e., the maximum true strain exceeded by 120%, the amorphous specimen was not fractured, indicating that it has super-plasticity at room temperature. Through the appropriate choice of composition and optimization of the technological process, flexible BMG with super-plasticity at room temperature could be produced.     

基于MODIS乌昌地区春季地表温度反演

根据新疆春季地表温度的特性,将前人研究反演地表温度的反演上下限(0℃~50℃)调整为(-30℃~50℃)。然后根据学者研究提出的Plank函数的线性简化方法,对MODIS的第31和32热红外波段分别简化为:B31(T)=0.1088T31-23.349,B31(T)=0.0097T32-220.364,从而反演出更接近于乌昌(乌鲁木齐、昌吉)地区春季地表温度的实测数值。     

可持续发展视阈下的甘肃农业水资源利用

近年来,甘肃农业在水资源利用方面取得了一定的成绩,总结了许多经验,对推动甘肃农业发展和促进农民增收起到了积极作用。但是,当前甘肃农业水资源利用依然存在着诸多问题和矛盾。从甘肃农业水资源利用的现状入手,针对不同区域特点从理顺机制、完善制度、研发技术、转变发展模式4个方面提出了加强甘肃省农业水资源利用的对策和建议。     

基于认知无线网络的跨层设计研究

首先讨论认知无线网络跨层设计的挑战,然后提出一种基于推理机的跨层设计方案。最后,总结全文并对未来工作提出展望。     

数学分析课程教学改革的几点尝试

结合数学分析课程教学实际,探讨数学分析课程教学内容的处理和教学方法的更新以及师资队伍的建设。     

Analysis of realizable rational decimated nonuniform filter banks with direct structure

In the design of nonuniform filter banks （NUFBs） with direct structure, the location of each analysis filter, corresponding to the sampling factor satisfying maximal decimation condition, should be set properly to avoid large aliasing. In this paper, a necessary and sufficient condition for the setting of the location of each analysis filter is derived. The NUFBs, we focus on, have rational decimation factors. Based on the derived condition, the frequency support of each analysis filter for the realizable NUFBs can be determined directly in such a way that the analysis filters can extract the corresponding bands of the input signal. This provides a guideline for the design of NUFBs with direct structure in choosing proper locations of analysis filters.