边界单元法三维应力分析计算程序

以三维弹性力学问题的基本解 (Kelvin解 )为基础开发了边界单元法三维弹性应力分析计算程序 ,并对其进行了验证。结果表明 ,该程序可用来求解三维弹性应力问题 ,尤其适用于三维应力集中问题。程序中采用动态分配内存 ,自动选点积分 ,并利用分块解法求解方程组 ,有效地节省了计算机资源 ,扩大了求解问题的规模。     

电弧喷涂铝及铝-锌涂层在动态腐蚀介质中的耐蚀性研究

对钢铁基体表面电弧喷涂铝及铝锌涂层进行了动态腐蚀实验 ,以失质量法计算了腐蚀速度 ,并探讨了腐蚀机理。采用SEM对铝及铝锌涂层腐蚀前后的外表形貌进行了观察 ,并对铝及铝锌涂层表面进行了能谱分析 ,采用电化学系统测试了涂层的自腐蚀电位。实验结果表明 ,在 3 %NaCl水溶液中铝涂层的耐蚀性优于铝锌涂层 ;其原因是铝涂层表面上氧化膜的自愈能力及自腐蚀电位高于铝锌涂层。研究还表明 ,铝及铝锌这些阳极涂层不仅能有效地保护它所覆盖的钢铁表面 ,还能保护暴露于腐蚀介质中的钢铁基体表面。在铝、铝锌涂层上刷涂有机涂料 ,有机涂料能渗透到金属涂层的孔隙中 ,将孔隙封闭。同时 ,有机涂层和金属涂层能构成复合涂层 ,其防腐效果更佳     

Asymptotic Approximations of Jacobi Polynomials and Their Zeros with Error Bounds

IntroductionUniform asymptotic expansions and error boundsof the (α,β>- 1 ) two- term approximations of theJacobi polynomials P(α,β)n ( cosθ) were obtained[1] .Their result wassin θ2α cosθ2βP(α,β)n ( cosθ) =Γ( n +α + 1 )n!θsinθ1/ 2 Jα( Nθ)Nα +θB0 (θ) Jα+1( Nθ)Nα+1+σ2 ,|σ2 |≤ E2 θ2 +αN -2 ,　 0≤θ≤ π2 ,where E2 is a construct.Baratella and Gatteschiused the first two terms of this expansion[2 ] toconstructa more accurate one- term approximation:x(θ)x′(θ)…     

HV/CVD Grown Relaxed SiGe Buffer Layers for SiGe HMOSFETs

High-vacuum/chemical-vapor deposition (HV/CVD) system was used to grow relaxed SiGe buffer layers on Si substrates. Several methods were then used to analyze the quality of the SiGe films. X-ray diffraction and Raman spectroscopy showed that the upper layer was almost fully relaxed. Second ion mass spectroscopy showed that the Ge compositions were step-graded. Transmission electron microscopy showed that the misfit dislocations were restrained to the graded SiGe layers. Tests of the electrical properties of tensile-strained Si on relaxed SiGe buffer layers showed that their transconductances were higher than that of Si devices. These results verify the high quality of the relaxed SiGe buffer layer. The calculated critical layer thicknesses of the graded Si1-xGex layer on Si substrate and a Si layer on the relaxed SiGe buffer layer agree well with experimental results.     

Structural and Chemical Diversity of TI-Based Cuprate Superconductors

The first TI一based euprate supereonduetor,TI一Ba-Cu一(),was diseovered by 2.2.Sheng and A.M.Hermann仁1〕. TI beeomes supereondueting at 2.38 K.NumerousTI eompounds and alloys are supereondueting.TIMo6Ses has the highest transition temperature of1 2.2 K among all non一euprate Tl eontaining alloyand eompound supereonduetors.Before thediseovery of the euprate supereonduetors,some TIeontaining oxide supereonduetors were found,among whieh TI。.3W()3 has the highest transitiontemPerature,2.14 K. Sinee the diseovery of TI euPratesuPereonduetors,two distinet families have beenidentified.Soon after the diseovery of TI一Ba一Cu-(),supereonduetivity was eonfirmed in TI一Ba一Ca-Cu一()samples.The ehemieal eompositions anderystal struetures of those eompounds were workedout as T12BaZCu()6,T12BaZCaCuZ()。,andT12BaZCaZCu3OI。[2〕.This 15 the first family of TIeuPrate supereonduetors,whieh features two TIatoms in eaeh ehemieal formula.     

新型中孔多金属氧酸盐复合材料光催化降解染料罗丹明B的研究

以胺修饰的中孔氧化硅为载体，通过自组装技术制备了一取代keggin结构的K5［Ni（H2O）PW11O39］(以下简称PW11Ni)复合材料，并研究了该复合材料对可溶性染料罗丹明B(简称RB)光催化的活性。实验结果表明。该复合材料光催化RB的活性高于RB的直接光解和PW11Ni均相光催化。其中，复合材料PW11Ni—APS—SiO2可在180min内使RB的转化率达到91．6％。具有一定的开发价值。     

苯酚废水的光氧化降解研究

研究了UV/Fenton、日光/Fenton、UV/TiO_2和UV/Fe~(2+)等几种光氧化体系对模拟苯酚废水的氧化降解。结果表明,在上述几种光氧化体系中,UV/Fenton体系对苯酚的氧化降解能力最强,可很快地使苯酚矿化,日光/Fenton体系的降解能力次之;而UV/TiO_2与UV/Fe~(2+)体系对苯酚的降解效果较差。反应初始pH值与催化剂Fe~(2+)用量等因素对苯酚的降解均有很大影响,光Fenton反应体系中,pH值在3～4范围内,苯酚的矿化效果较佳,pH值超过此范围,矿化率则急剧下降;苯酚的矿化率随着Fe~(2+)用量的增加而逐渐增大,但当Fe~(2+)达到一定量时,再增加Fe~(2+)用量,苯酚的矿化率反而有所下降。     

一种薄壁矩形管弯曲胎具的设计

介绍了一种薄壁矩形管弯曲胎具。利用金属材料弯曲变形时的塑变硬化特性来弯曲矩形管,较好地解决了雨阳棚骨架现场弯曲加工的问题。     

Emergent Property in Macromolecular Motion

In this paper, the model of inverse cascade fractal super-blocks along one direction (in the positive or negative) in the 3-dimensional space is developed to describe the self-similar motion in macromolecular system. Microscopically the cohesive and dispersed states of the motion blocks are co- existent states with vastly different probability of occurrence. Experimental results and theoretical analysis show that the microscopic cohesive state energy and dispersed state energy of each motion block are respectively equal to the macroscopic glassy state energy kTg and molten state energy kTm of the system. This singularity unveils topologically the non-integrability, mathematically the anholonomy, and macroscopically the emergent property. This singularity also reveals that the glass, viscoelastic and melt states are three distinct emergent properties of macromolecular motion from a macroscopic viewpoint. The fractal concept of excluded volume is introduced to depict the random motion at various scales in     

Ordinary Toxicity of Chlorine Dioxide and By-products Chlorite and Chlorate in Water

Acute toxicity and accumulated toxicity of chlorine dioxide (ClO2) and by-products chlorite (ClO2-) and chlorate (ClO3-) in water acted on mice are studied by the method of Horn and accumulation coefficient. Subchronic toxicity of the mixture of ClO2 and ClO2-and ClO3- in water acted on rat is studied though feeding test for 90 days, including statistical analysis of variance on weight gaining, food utilization efficiency,index of blood and serum,liver (or kidney) to body weight ratio, and histopathological examination on liver and kidney. The results show that aqueous solution of ClO2, NaClO2 and NaClO3 ( with the concentration of 276.5 mg/L, 200 mg/L and 200 mg/L respectively) and the mixed aqueous solution of ClO2 with the concentration of 553 mg/L are actually non-poisonous , and non-cumulative aqueous solution as well.