FeCo-based hybrid MOF derived active species for effective oxygen evolution

Metal-organic frameworks(MOFs) have been regarded as promising catalyst materials due to the richness of coordinately unsaturated metal sites on the surface,which can act as catalytic active centres.In this study,a hybrid MOF material composed of Fe-based MOF and Co-based MOF was prepared with the involvement of graphene oxide nanosheets as additive.It was demonstrated that the hybrid MOF materials showed much higher electro-catalytic activity towards oxygen evolution than the single-phase counterparts.To drive current density of 10 mA cm~(-2),the hybrid CoFe-based MOF only needed an over potential of 290 mV in 1 M KOH.The catalytic activity could sustain for a longer time with only slight current density decrease.During oxygen evolution operation,the MOF catalyst evolved into catalytic active species but kept well the microscale sheet-like structure.It is thus believed that this study will provide an avenue for the development of advanced electrocatalysts.     

公安院校《有机物检验技术》课程研发探究

目前公安院校刑事技术相关课程体系还存在诸多问题,课程科目重合、基础知识单薄、教学内容滞后,远远不能满足一线公安的实战要求.根据教学实践,针对公安院校刑事技术专业学生,进行了《有机物检验技术》课程的研发,精选教学内容,保持其系统性、实战性和前沿性.有效地增强警校学生的基础知识,培养其动手能力,提升其办案水平,保证了教学质量和学科的健康发展.     

超临界水氧化处理有机物废料的新技术

和传统方法相比，超临界水氧化处理有机物废料有着极大的优势。介绍了处理废料的原理和工业应用的可能性。     

Polarized Emission of Molecular Film With Lanthanide (Ⅲ) Complex

1 Results In the coordination system by using complexation with organic ligand, the ff emission of lanthanide(Ⅲ) (Ln(Ⅲ)) is induced the excitation energy transfer form the organic chromophore under the light-irradiation. However, there are not so much number of reports to discuss the energy relaxation mechanism in such complexes with Ln(Ⅲ). Recently, we succeeded firstly to estimate the rate constant of the energy transfer between the ligand and Ln(Ⅲ) in Pr(Ⅲ)-phenanthroline analogs[1]. Here, we will di...     

新型纳米纤维膜对地下水中重金属的过滤去除研究

采用扫描电镜表征了氯化聚氯乙烯静电纺丝纳米纤维膜的微观结构特征,并进行了去除地下水中铜、铅、镉等重金属阳离子的过滤试验,包括直接过滤、加土壤过滤、加硅藻土过滤和胶束强化过滤。结果表明,最佳的过滤工艺是胶束强化过滤,其最佳试验条件是10层膜过滤和5mmol/L的SDBS浓度,对铜、铅、镉的去除率分别超过73%,82%和91%。     

一种新型粘土稳定剂的合成与应用研究

本文简要报导了有机阳离子聚和物(氯化N,N—二甲基二烯丙基铵—二氧化硫)的合成方法,并对其作为粘土稳定剂的性能进行了评价。结果表明,该共聚物稳定粘土的能力高于目前国内外广泛使用的同类聚合物TDC。     

羧基淀粉的制备及其吸附性能的研究

本文研究羧基淀粉的制备条件与吸附重金属离子的容量关系,并研究它的使用条件和性能。     

β-桉烯和其衍生物的合成及其抗生育活性

本文叙述了倍半萜类化合物——β-桉烯、衍生物Neointermedeol以及1,2,3,4,7,8-六氢-5,8-二甲基-3-异丙烯基萘的合成。初步药理筛选结果表明,这三个化合物均具有一定的抗生育活性。化合物还未见报道,它的化学结构在本文得到证实。     

制备介孔复合环境材料的酸洗刻蚀工艺

探索了一种制备介孔复合环境材料的方法--破坏式造孔与有机复合相结合,使最终产品可大量吸附污染水体中的各种污染物并具有一定的杀菌功能.该方法通过酸洗刻蚀,达到了去除原材料中的杂质和刻蚀孔径的目的,所制备的中间产品24h吸湿率为原材料的2倍,染料吸附量为原材料的1.6倍.     

液态金属压铸机的实时压射控制系统

为了满足压铸工艺的要求，有必要进行压射机构的改造并对压射实施自动控制．为此，研究了液态金属压铸机压射结构的重新设计及其实时控制，设计了一套对压射进行实时控制的系统，着重研究了该系统的组成、基本原理及其特点．