成型压力对GZO陶瓷靶材无压烧结致密化的影响

采用模压成型-无压烧结法制备Ga掺杂量为3wt%的氧化锌陶瓷靶材(ZnO∶Ga2O3=97∶3wt%).分析研究了成型压力对靶材致密度、物相组成、微观结构及烧结收缩变化率的影响.采用X射线衍射仪分析物相组成,扫描电镜观测烧结体断口形貌,用热膨胀仪分析试样烧结收缩曲线,阿基米德排水法测量试样密度.结果表明:成型压力对GZO靶材烧结时生成ZnGa2O4的固相反应有促进作用,并且当成型压力由120MPa提高到200MPa时,固相反应生成更多的ZnGa2O4尖晶石相导致GZO陶瓷烧结致密所需的温度也有所提高.成型压力为200MPa时靶材致密度最高,相对密度达93.54%TD.     

氧化锌陶瓷低温导电特性研究(英文)

研究了Nb2O5掺杂的ZnO陶瓷在低温下导电特性,结果表明,低温状态下,随着Nb2O5掺杂量的增加,ZnO电阻率降低,不同温度下烧结的ZnO样品,烧结温度越高,电阻率愈小,同一烧结温度下,不同烧结时间的ZnO样品,随着烧结时间的增加,电阻率愈小.     

Y-TZP纳米陶瓷的制备、结构及力学性能

采用沉淀法制备的Y-TZP纳米粉体经冷压成型后烧结成Y-TZP纳米陶瓷.结果表明,Y-TZP纳米陶瓷的密度随着烧结温度的升高和烧结时间的延长而增大,但随成型压力和初始粉体颗粒的增大而减小.而陶瓷平均晶粒尺寸随成型压力的增大和烧结时间延长而长大.烧结过程中大量单斜相ZrO2生成改变了Y-TZP纳米陶瓷的烧结行为和微结构.采用无压烧结获得了相对密度为98%、平均晶粒尺寸为60 nm的Y-TZP纳米陶瓷.Y-TZP纳米陶瓷的显微硬度主要取决于陶瓷的相对密度、相结构和晶粒尺寸,即陶瓷的四方相质量分数越高,相对密度越大,晶粒尺寸越小,则显微硬度越高.     

高能球磨法制备Mg_4Nb_2O_9微波介质陶瓷及其表征

采用高能球磨法制备粉体.粉体球磨60 h后在900℃保温3 h预烧合成Mg4Nb2O9纯相,研究了由高能球磨所得粉体制备的Mg4Nb2O9陶瓷的相结构、显微组织和微波介电性能随烧结温度的变化关系.X射线衍射检测Mg4Nb2O9陶瓷在1 150～1 200℃烧结过程中有微量的MgNb2O6和Mg5Nb4O15杂相产生,烧结温度高于1 200℃时,样品为Mg4Nb20g纯相;样品收缩率和密度随烧结温度的增大而增加,在1 200℃趋于饱和,分别为13.6和4.22 g/cm3(相对密度96.42%);样品的气孔含量随烧结温度增大降低,晶粒尺寸随烧结温度增大而增大,介电常数和品质因数随烧结温度的增大而增加;1 200℃烧结的样品具有高的致密度、清晰的显微组织,平均晶粒尺寸为3.5 μm,微波介电性能εr=12.6,Q·f=133164 GHz,τ=-56.69×10-6/℃.实验结果表明.高能球磨有效促进球磨后粉体在900℃低温合成Mg4Nb2O9纯相;并降低Mg4Nb2O9陶瓷的烧结温度到1 200℃,改善了陶瓷的谐振频率温度系数,有望成为新一代中温烧结微波介质材料.     

液固混合烧结制备渗流型镍锌铁氧体/钛酸钡复相陶瓷

利用自燃烧法制备Ni0.5Zn0.5Fe2O4粉体,利用溶胶凝胶法配制BaTiO3溶胶,通过BaTiO3溶胶混合Ni0.5Zn0.5Fe2O4粉体烧结制备得到xNi0.5Zn0.5Fe2O4/(1-x)BaTiO3复合粉体,再将其压成片状或环状后,在不同温度下成功烧结制备了渗流型复相陶瓷.研究了xNi0.5Zn0.5Fe2O4/(1-x)BaTiO3中镍锌铁氧体的摩尔分数x对陶瓷介电性能和磁性能的影响,结果表明:当x≤0.5时,复合体系与传统渗流型复合材料相似,介电常数随着x的增加呈指数性增长;当x0.5时,复相陶瓷在低频下的介电常数基本上不随x变化而变化,稳定在10 kF/m左右;随着x从0.5增加到0.9,磁导率可从5 H/m升高至18 H/m.很明显,利用液固混合烧结方法,可以制备得到一种同时具有高介电常数和一定磁导率的复相陶瓷.     

氧化钛纳米陶瓷的制备及其结构与力学性能

为探讨在无压烧结过程中TiO2纳米陶瓷的致密化与晶粒长大的关系以及纳米陶瓷的结构对其力学性能的影响,采用溶胶一凝胶技术制备的不同颗粒粒径的TiO2纳米粉体经冷压成型后无压烧结TiO2纳米陶瓷.研究结果表明:利用相变辅助无压烧结方法在800℃烧结获得了晶粒粒径小于60 nm、相对密度超过95%的TiO2纳米块体陶瓷:当800℃以下烧结时,TiO2纳米陶瓷的相对密度随烧结温度的升高而快速增大,而TiO2纳米陶瓷的平均晶粒粒径随烧结温度升高则缓慢长大;当大于800℃的温度烧结时,TiO2纳米陶瓷的致密化加快,但陶瓷的晶粒粒径则快速长大.TiO2纳米陶瓷的显微硬度主要取决于TiO2纳米陶瓷的相对密度和平均晶粒粒径,即纳米氧化钛陶瓷的相对密度越大,晶粒粒径越小,则显微硬度越大.     

Sm2O3、ZnO共掺杂Ba0.2Sr0.8TiO3陶瓷的制备及性能研究

采用固相反应法制备了ZnO、Sm2O3共掺杂Ba0.2Sn.8TiO3陶瓷样品,利用X射线衍射方法及介电谱测量方法对样品的结构和介电性能进行了测量分析,结果表明:(1)Zn2+与Sm3+进入Ba0.2Sr08TiO3晶格内,与之形成ABO3钙钛矿型固溶体;(2)介电常数弥散的P过程和弛豫的D过程随着Sm2O3含量的增大均被压低展宽,D的弛豫过程逐渐明显,在Sr2O3为0.06mol时为Debye型弛豫过程;(3) Sm2O3的掺入可降低B a0.2Sr0.8TiO3+ZnO陶瓷介电常数,增大损耗,Sm2O3为0.05mol时是样品的一个过渡组分.     

反应烧结法制备Mg_4Nb_2O_9陶瓷及其微波介电性能的表征

采用反应烧结法制备Mg4Nb2O9陶瓷,省去预烧阶段,优化了制备工艺,研究得到Mg4Nb2O9陶瓷样品的相组成、微观形貌以及微波介电性能随着烧结温度的变化关系.由XRD检测到陶瓷在1 200~1 450℃均得到纯相的Mg4Nb2O9陶瓷,在1 400℃烧结保温3h所得陶瓷密度为4.13g/cm3(相对密度94.25%),样品具有清晰的微观形貌,微波介电性能为:εr=12.1,Q×f=169 000GHz,τf=-55.55×10-6℃-1.     

稀土Sm_2O_3对WCoB-TiC复相陶瓷组织的影响

以WC、TiB2、Co粉末为基本原料,添加稀土Sm2O3为抑制剂,采用真空液相反应烧结技术制备WCoBTiC复相陶瓷材料,利用XRD、SEM和EDS对其微观形貌和相组成进行表征。结果表明,添加一定量稀土Sm2O3后,WCoB-TiC复相陶瓷晶粒细小且分布均匀,晶粒的长大得到抑制;随着稀土Sm2O3的过量加入,复相陶瓷中有棒状晶粒出现,晶粒有粗化的趋势。在1400℃下烧结时,当Sm2O3添加量为0.3%时,制成的WCoB-TiC复相陶瓷材料密度达到10.01g/cm3,硬度HRA达到91。     

烧结温度对CaBi2Nb2O9超高温压电陶瓷结构及性能影响

采用传统固相合成法制备了铋层状结构CaBi2Nb2O9压电陶瓷,研究了烧结温度对样品相结构、微观形貌、密度和介电、铁电性能的影响。采用X射线衍射衍射仪、电子扫描电镜、拉曼光谱、介电温谱以及电滞回线对制备陶瓷样品进行表征分析和性能测试。结果表明:所有陶瓷样品的相组成均为纯铋层状结构,晶粒呈棒状,各向异性明显,随着烧结温度的升高,晶粒逐渐长大,陶瓷密度先变大后变小。固相法制备的CaBi2Nb2O9压电陶瓷的最佳烧结温度为1 150℃,介电温谱显示CaBi2Nb2O9陶瓷的居里温度为 943 ℃。     

An Index mechanism for multi-scale view in spatial databases

There are numerous geometric objects stored in the spatial databases. An importance function in a spatial database is that users can browse the geometric objects as a map efficiently. Thus the spatial database should display the geometric objects users concern about swiftly onto the display window. This process includes two operations:retrieve data from database and then draw them onto screen. Accordingly, to improve the efficiency, we should try to reduce time of both retrieving object and displaying them. The former can be achieved with the aid of spatial index such as R-tree, the latter require to simplify the objects. Simplification means that objects are shown with sufficient but not with unnecessary detail which depend on the scale of browse. So the major problem is how to retrieve data at different detail level efficiently. This paper introduces the implementation of a multi-scale index in the spatial database SISP (Spatial Information Shared Platform) which is generalized from R-tree. The difference between the generalization and the R-tree lies on two facets: One is that every node and geometric object in the generalization is assigned with a importance value which denote the importance of them, and every vertex in the objects are assigned with a importance value,too. The importance value can be use to decide which data should be retrieve from disk in a query. The other difference is that geometric objects in the generalization are divided into one or more sub-blocks, and vertexes are total ordered by their importance value. With the help of the generalized R-tree, one can easily retrieve data at different detail levels.Some experiments are performed on real-life data to evaluate the performance of solutions that separately use normal spatial index and multi-scale spatial index. The results show that the solution using multi-scale index in SISP is satisfying.     

Characterization of Ordovician carbonate reservoirs, southeastern Saskatchewan, Canada

The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3～4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰～ -7.8‰, PDB) and matrix dolomites (-6.6‰～ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084～0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078～0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.     

A computer generator for randomly layered structures

AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…     

Perspherical Approaches for Electrons in Atoms and Charged Excitons in Quantum Wells

Instead of following Fock’s expansion,we solve the Schrodinger equation for some quantum mechanical manybody systems such as electrons in atoms and charged excitons in quantum wells in a similar way in hyperspherical coordinates by expanding the wave functions into orthonormal complete basis sets of the hyperspherical hannonics(HHs)of hyperangles and generalized Laguerre polynomials(GLPs)of the hyperradius.This leads the equation to     

Advances in broadband wireless communications under high-mobility scenarios

Future mobile communication systems aim at providing very high data transmission rates, even in high-mobility scenarios such as high-speed wheel-track trains, maglev trains, highway vehicles, airplanes, guided missiles or spacecraft. A particularly important commercial application is the strong and increasing worldwide demand for high- speed broadband wireless communications （up to 574.8 km/ h test speeds or 380 km/h commercial speeds） in railways, providing data, voice and video services for applications such as onboard entertainment services to passengers, train control, train dispatch, train sensor status handling and sur- veillance. In such high-mobility scenarios, there are a number of communication challenges, including fast hand- over, location updating, high-speed channel modeling, estimation and equalization, anti-Doppler spreading tech- niques, fast power control, and dedicated network architec- ture. Because signal transmission in very high-speed scenarios will inevitably experience serious deterioration, it is imperative to develop key broadband mobile communi- cation techniques for such high-speed vehicles.     

Wuhan University Journal of Natural Sciences TOTAL CONTENTS

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海南岛地体及其毗邻陆缘晚中生代—新生代古地磁研究和构造演化

本文叙述了对海南岛及其毗邻大陆边缘白垩纪到第四纪地层岩石进行古地磁研究的全部工作过程。通过分析岩石中剩余磁矢量的磁偏角及磁倾角的变化,提出海南岛白垩纪以来经历的构造演化模式如下:早期伴随顺时针旋转而向南迁移,后期伴随逆时针转动并向北运移。联系该地区及邻区的地质、地球物理资料,对海南岛上述的构造地体运动提出以下认识:北部湾内早期有一拉张作用,主要是该作用使湾内地壳显著伸长减薄,形成北部湾盆地。从而导致了海南岛的早期构造运动,而海南岛后期的构造运动则主要是受南海海底扩张的影响。海南地体运动规律的阐明对于了解北部湾油气盆地的形成演化有重要的理论和实际意义。     

Scale-based spatial data model for GIS

Being the primary media of geographical information and the elementary objects manipulated, almost all of maps adopt the layer-based model to represent geographic information in the existent GIS. However, it is difficult to extend the map represented in layer-based model. Furthermore, in Web-Based GIS, It is slow to transmit the spatial data for map viewing. In this paper, for solving the questions above, we have proposed a new method for representing the spatial data. That is scale-based model. In this model we represent maps in three levels: scale-view, block, and spatial object, and organize the maps in a set of map layers, named Scale-View, which associates some given scales.Lastly, a prototype Web-Based GIS using the proposed spatial data representation is described briefly.     

Exciton Seebeck in Molecular Systems

Various applications relevant to the exciton dynamics,such as the organic solar cell,the large-area organic light-emitting diodes and the thermoelectricity,are operating under temperature gradient.The potential abnormal behavior of the exicton dynamics driven by the temperature difference may affect the efficiency and performance of the corresponding devices.In the above situations,the exciton dynamics under temperature difference is mixed with     

Achieving Unusual States of Matter Under High Pressure

The elongation method,originally proposed by Imamura was further developed for many years in our group.As a method towards O(N)with high efficiency and high accuracy for any dimensional systems.This treatment designed for one-dimensional(ID)polymers is now available for three-dimensional(3D)systems,but geometry optimization is now possible only for 1D-systems.As an approach toward post-Hartree-Fock,it was also extended to