High-resolution climate recorded in the δ13 C of Porites lutea from Nansha Islands of China

A Porites lutea core from Yongshu Reef of Nansha Islands covering 50_year growth history is analyzed for carbon isotopic composition with monthly and seasonal resolution, and the results show that the coral δ 13 C generally has clear yearly cycles. The calibration indicates that the coral δ 13 C can record the sunshine duration, total cloud cast and rainfall of the Yongshu Reef, and it also shows significant association to El Nio events. From 1950 to 1999, the δ 13 C shows a clear long-term declining trend, which indicates a decrease in the sunshine duration and an increase in cloud cast and rainfall over Yongshu Reef over the past fifty years.     

Characteristics of δ 18O in precipitation over Eastern Monsoon China and the water vapor sources

Monsoon circulation is an important carrier of water vapor transport, and it impacts the precipitation of the monsoonal regions through the constraints and controls of large-scale water vapor transport and distributions as well as the water vapor balance. An overall research on stable Hydrogen and Oxygen isotopes in precipitation over Eastern Monsoon China could benefit a compre-hensive understanding of the monsoonal precipitation mechanism. Seventeen field stations of the Chinese Network of Isotopes in Precipitation (CHNIP) have been selected to collect monthly composite precipitation samples during the years 2005―2006. Components of δD and δ¹⁸O have been analyzed to achieve the spatiotemporal distributions. The established Local Meteoric Water Line δD=7.46 δ¹⁸O+0.90 based on the 274 obtained monthly samples could be treated as isotope input functions across the region, due to basically reflecting the specific regional meteorological conditions over Eastern Monsoon China. The δ-value de-pleted from coastal to inner area. In Southern China and Northeastern China there were typical periodic patterns of δ¹⁸8O. Differ-ent dominant affecting metrological factors have been raised with different regions. From south to north, the temperature effect of δ¹⁸18O enhanced, while the amount effect changed from existing at an all-year-scale in Southern China to being only remarkable during the main rainy seasons in North China and Northeastern China. Main geographical controls varied from altitude in South-ern China and North China to latitude in Northeastern China. Furthermore, δ¹⁸O had an implication of advance and retreat of the monsoon as well as rainfall belt transfer δ¹⁸O was also a tracer for the movement path of typhoon and tropical storms.     

Coral reef ecosystems in the South China Sea as a source of atmospheric CO<Subscript>2</Subscript> in summer

Field measurements of air-sea CO2 exchange in three coral reef areas of the South China Sea (i.e. the Yongshu Reef atoll of the Nansha Islands, southern South China Sea (SCS); Yongxing Island of Xisha Islands, north-central SCS; and Luhuitou Fringing Reef in Sanya of Hainan Island, northern SCS) during the summers of 2008 and 2009 revealed that both air and surface seawater partial pressures of CO2 (pCO2) showed regular diurnal cycles. Minimum values occurred in the evening and maximum values in the morning. Air pCO2 in each of the three study areas showed small diurnal variations, while large diurnal variations were ob-served in seawater pCO2. The diurnal variation amplitude of seawater pCO2 was ~70 μmol mol–1 at the Yongshu Reef lagoon, 420–619 μmol mol–1 on the Yongxing Island reef flat, and 264–579 μmol mol–1 on the reef flat of the Luhuitou Fringing Reef, and 324–492 μmol mol–1 in an adjacent area just outside of this fringing reef. With respect to spatial relations, there were large differences in air-sea CO2 flux across the South China Sea (e.g. ~0.4 mmol CO2 m–2 d–1 at Yongshu Reef, ~4.7 mmol CO2 m–2 d–1 at Yongxing Island, and ~9.8 mmol CO2 m–2 d–1 at Luhuitou Fringing Reef). However, these positive values suggest that coral reef ecosystems of the SCS may be a net source of CO2 to the atmosphere. Additional analyses indicated that diurnal variations of surface seawater pCO2 in the shallow water reef flat are controlled mainly by biological metabolic processes, while those of deeper water lagoons and outer reef areas are regulated by both biological metabolism and hydrodynamic factors. Unlike the open ocean, inorganic metabolism plays a significant role in influencing seawater pCO2 variations in coral reef ecosystems.     

The genesis and environmental significance of red and black sedimentary interlayers in coral reef of well Nanyong 2

The results of paleogeomagnetics and geochemistry of the coral reef in well Nanyong 2 of Nansha Islands showed that the bottom of the black sedimentary interlayer corresponds to the conversion boundary line between Brunhes Postive Polarity and Matuyama Reversed Polarity (B/M) and the cold/warm (19/20) climatic conversion bounds on δ¹⁸O curve, 0.78 Ma ago; and the red sedimentary interlayer corresponds to the ReunionⅠpolarity excursion (reversion) of the geomagnetic field, 2.01—2.04 Ma ago. Comparing with the normal light-coloured coral reef rock, the magnetic susceptibility (c), residual magnetization intensity (Mr) and the content of MnO and Fe₂O₃ of the black sedimentary layer appeared obviously positive abnormity. The magnetic susceptibility (c), residual magnetization intensity (Mr) and the content of Fe₂O₃ of the red sedimentary layer also appeared positive abnormity. Combining with the analyzing results of paleontology, we hold that this pair of special and typical sedimentary interlayers was relative to the sudden change of paleoclimate, i.e. the global climatic change and its incidental polarity reversal of the geomagnetic field directly affected the living environment of the paleontological species as well as the dispersion and enrichment of some chemical elements, especially the elements sensitive to redox such as Fe and Mn. For example, the elements Fe and Mn concentrated in the glacial period would be largely oxidized and diluted when the climate warmed up suddenly, and the originally oxidized high valence Fe would be condensed again when the climate cooled suddenly. This is possibly one of the important reasons of appearing and disappearing of the red and black sedimentary events of coral reef in well Nanyong 2.     

A reconnaissance of Cu isotopic compositions of hydrothermal vein-type copper deposit Jinman,Yunnan, China

The Jinman deposit is a low-temperature hydrothermal vein-type copper deposit, which occurs along faults and fractures within Middle Jurassic sandstone and mudstone units of the Lanping-Simao Mesozoic-Cenozoic basin of Yunnan Province. In this note, we report for the first time the Cu isotopic compositions of Cu-sulfides from the Jinman deposit. The data show large variations and low δ⁶⁵Cu values of -3.70‰ to +0.30‰, which are in sharp contrast to the δ⁶⁵Cu values of high-temperature magmatic-hydrothermal copper deposits (-0.62‰ to +0.40‰) and the modern ocean-floor massive sulfide deposits (-0.48‰ to +1.15‰). It is suggested that the Cu isotope fractionation at Jinman is affected mainly by the following factors, i.e. a low temperature of ore formation (150—286℃); a sedimentary source for ore materials; various stages of ore deposition; and involvement of organic matter in the ore-forming processes.     

Twenty-five years of change in scleractinian coral communities of Daya Bay （northern South China Sea） and its response to the 2008 AD extreme cold climate event

Coral reefs worldwide are becoming increasingly and detrimentally impacted upon by a variety of factors including significant climate changes, such as global warming and increased El Nino-Southern Oscillation activity. Generally, the persistence of coral reefs, especially at low-latitudes, is governed, in part, by sea surface temperatures not exceeding the critical limit （-30℃） at which mass mortality can occur. Thus, it is thought that corals living at high-latitudes （i.e., currently cooler sea surface temperatures） will likely respond more favourably to hypothesized future temperature increases than corals living at low-latitudes （i.e., currently warmer sea surface temperatures）. Consequently, high-latitude coral communities may have the potential to act as regions of refugia for many coral species in the face of potential future global warming. The Daya Bay （22°31′--22°50′N）, northern South China Sea, contains several high-latitude non-reefal coral communities and represents one of the most northerly distributions of scleractinian corals within the region. Significantly, Daya Bay has experienced dramatic warming in both air and sea surface temperatures throughout the past 50 years. In this paper, we analyze 25 years of change in the Daya Bay coral communities, based both on historic surveys and our latest 2006--2008 regional ecological surveys. Our results suggest that, contrary to predictions, there have been significant declines in coral cover within the Daya Bay during the past 25 years （i.e., 76.6% coral cover in 1983/1984 to only 15.3% coral cover by 2008）. Such changes also reflect a significant shift in the most abundant coral species, from Acropora pruinosa to Favites abdita. Most of the modern coral communities became established between 15 and 30 years ago, corresponding to a period of increased winter sea surface temperature. However, very few colonies have become established within the last 15 years, despite a more intense period of warming. By taking into account additional factors, we hypothesize that direct anthropogenic impacts, rather than climatic events, have both restricted the development, and drove the decline, of Daya Bay coral communities in the last 15 years. The Daya Bay has also been subjected to occasional extreme cold events during the past 50 years, with the most recent occurring in early 2008 （13 January-13 February）. During the 2008 cold event, the lowest air temperature reaches only 6.6℃, and the mean sea surface temperature for February fall to 〈 14℃, including six continuous days at 12.3℃. Significantly, the sea surface temperatures fall below the hypothesized critical lower temperature threshold （-13℃） that commonly leads to mass mortality in scleractinian coral communities. Surprisingly, our coral community surveys, conducted both before （August 2007） and after （late February 2008） the extreme 2008 cold event, demonstrate that the Daya Bay coral ecosystems are barely impacted upon during the cold period. Those observations suggest that the Daya Bay scleractinian coral communities have developed adaptations to low sea surface temperatures. Overall, our data support the hypothesis that high-latitude coral communities, such as Daya Bay, have the potential to act as areas of refugia for scleractinian corals in the advent of potential future global warming.     

Assessment of coral bleaching using symbiotic zooxanthellae density and satellite remote sensing data in the Nansha Islands,South China Sea

Coral bleaching,characterized by a significant loss of symbiotic zooxanthellae,is the primary cause of mass coral mortality and reef degradation throughout the world.The characteristics,processes,and resistance of corals to bleaching varies significantly and is dependent on environmental conditions.We documented a mass coral bleaching event in June 2007 at the Meiji and Zhubi Reefs,Nansha Islands (NS),South China Sea using ecological surveys and measurement of coral zooxanthellae density and sea surface temperatures (SST).More than 35 species of corals (between 0-20 m in depth) were bleached.These bleached corals accounted for 15.6% of total corals in the investigated quadrats.The branching corals Pocillopora and Acropora were the most vulnerable species whereas the massive corals Porites and Favia were more tolerant of the high SSTs.Surprisingly,we found no evidence of bleaching in Agariciidae corals suggesting that this family is resistant to thermal stresses.The bleached corals had lost 72%-90% of their symbiotic zooxanthellae.Furthermore,corals that had no visual signs of bleaching had also lost 31%-53% of their zooxanthellae suggesting that most corals were experiencing the early stage of bleaching.The monthly mean SST during June 2007 was 30.8°C,the highest since 1998.Based on measurements of SST and the Hotspots and DHW data (NOAA),we conclude that it the extremely high SSTs triggered this coral bleaching event.Our results suggest that the previously accepted temperature thresholds used to predict coral bleaching based on satellite data are likely to underestimate the extent and intensity of coral bleaching,at least in the NS.     

Regional relationship between the Jiang-Huai Meiyu and the equatorial surface-subsurface temperature anomalies

The Jiang-Huai Meiyu rainy season can be distinguished into the Jiangnan Meiyu spell and the Huaihe Meiyu spell. The Jiangnan Meiyu spell appears on the last ten days in June and the Huaihe Meiyu spell lasts from early July to middle July. An inter-decadal transition was observed in 1998 respectively from the anomalies of Jiangnan Meiyu rainfall, the sea surface temperature (SST), and the subsurface tem- perature in the equatorial Pacific. Since the beginning of the 21^_st century, opposite trends and biennial oscillations of the Meiyu rainfall are observed in the Jiangnan and Huaihe basins. Before the strong La Niña of 1999―2000, the positive SST anomalies usually occurred in the eastern equatorial Pacific. Since the beginning of the 21^_st century, a precursory warming signal of SST anomaly comes from the subsurface temperature which is centrally exposed near the dateline in the central equatorial Pacific. The above-normal Meiyu rainfall in 2003, 2005 and 2007 over the Huaihe basin followed the prior winter- spring positive SST anomaly near the dateline. A relationship shows that the more Jiangnan (Huaihe) Meiyu follows the winter-spring warm water in the eastern (central) equatorial Pacific.     

Coral cover as a proxy of disturbance： A case study of the biodiversity of the hermatypic corals in Yongxing Island, Xisha Islands in the South China Sea

The Yongxing Island is the biggest island of Xisha Islands in the middle part of the South China Sea. It occupies 1.8 square kilometers of land area and has permanent residence on it. There are only a few papers on the coral community of the Xisha Islands, reporting the species composition, structure and zonations of the hermatypic coral community in 1970s. The present study describes the hermatypic coral community based on the quadrat survey after almost 30 years in Yongxing Island in August 2002. It was the first time to present the percent cover data of live corals of Yongxing Island via a systematic scheme of quantitative quadrat sampling. The average total percent cover of the live coral is 68.4%. We found the total percent cover （TPC） could be an idea proxy of the overall disturbance regime impinging on the coral community. TPC can be used as an integrated measure of disturbance to coral reef. Using this surrogate, the best fit relation between TPC of the live corals and species richness, species diversity, or the species evenness is the unimodal second-order polymorphic parabola equation. This result is expected by the intermediate disturbance hypothesis （IDH）. From the fitted parabola equations, we calculated the best TPCs corresponding to the maximal species richness, the highest species diversity, or the most evenness respectively. They are surprisingly stabilized between 55% and 58%. Coral cover is the basic parameter widely available for most observation, research or monitoring programs. The good qualitative characteristics of percent cover provide powerful tool for the experimental, theoretical and modeling studies of coral reef in response to the disturbance.     

A weak El Nio event in 2002 detected by the astronomical observation

El Ni駉 is a kind of the disastrous events occurring in the central and eastern parts of tropical Pacific. It pre-sents itself as anomaly of sea surface temperature (SST) in these parts of the tropical Pacific. It is called an El Ni駉 (La Ni馻) event whenever the tropical Pacific SST anom-aly is warmer (cooler) than 0.5℃(- 0.5℃) and lasts for over 6 months[1]. Southern oscillation (SO) is a seesaw- like variation of sea level pressure (SLP) in eastern and western parts of the souther…     

Coral cover as a proxy of disturbance:A case study of the biodiversity of the hermatypic corals in Yongxing Island, Xisha Islands in the South China Sea

The Yongxing Island is the biggest island of Xisha Islands in the middle part of the South China Sea. It occupies 1.8 square kilometers of land area and has permanent residence on it. There are only a few papers on the coral community of the Xisha Islands, reporting the species composition, structure and zonations of the hermatypic coral community in 1970s. The present study describes the hermatypic coral community based on the quadrat survey after almost 30 years in Yongxing Island in August 2002. It was the first time to present the percent cover data of live corals of Yongxing Island via a systematic scheme of quantitative quadrat sampling. The average total percent cover of the live coral is 68.4%. We found the total percent cover (TPC) could be an idea proxy of the overall disturbance regime impinging on the coral community. TPC can be used as an integrated measure of disturbance to coral reef. Using this surrogate, the best fit relation between TPC of the live corals and species richness, species diversity, or the species evenness is the unimodal second-order polymorphic parabola equation. This result is expected by the intermediate disturbance hypothesis (IDH). From the fitted parabola equations, we calculated the best TPCs corresponding to the maximal species richness, the highest species diversity, or the most evenness respectively. They are surprisingly stabilized between 55% and 58%. Coralcover is the basic parameter widely available for most observation, research or monitoring programs. The good qualitative characteristics of percent cover provide powerful tool for the experimental, theoretical and modeling studies of coral reef in response to the disturbance.     

Fatty-acids and their <Emphasis Type="Italic">δ</Emphasis><Superscript>13</Superscript>C characteristics of seep carbonates from the northern continental slope of Gulf of Mexico

Here we reported the fatty-acids and their δ¹³C values in seep carbonates collected from Green Canyon lease block 185 (GC 185; Sample GC-F) at upper continental slope (water depth: ~540 m), and Alaminos Canyon lease block 645 (GC 645; Sample AC-E) at lower continental slope (water depth: ~2200 m) of the Gulf of Mexico. More than thirty kinds of fatty acids were detected in both samples. These fatty acids are maximized at C₁₆. There is a clear even-over-odd carbon number predominance in carbon number range. The fatty acids are mainly composed of n-fatty acids, iso-/anteiso-fatty acids and terminally branched odd-numbered fatty acids (iso/anteiso). The low δ¹³C values (−39.99‰ to −32.36‰) of n-C₁₂:0, n-C₁₃:0, i-C₁₄:0 and n-C₁₄:0 suggest that they may relate to the chemosynthetic communities at seep sites. The unsaturated fatty acids n-C_18:2 and C_18:1△⁹ have the same δ¹³C values, they may originate from the Beggiatoa/Thioploca. Unlike other fatty acids, the terminally branched fatty acids (iso/anteiso) show lower δ¹³C values (as low as −63.95‰) suggesting a possible relationship to sulfate reducing bacteria, which is common during anaerobic oxidation of methane at seep sites.     

Geothermal measurements in the pilot-boreholes of the china continental scientific drilling

The geothermal measurements in the pilot-boreholes of the China Continental Scientific Drilling (CCSD) indicate that the temperature gradients in the target area of the deep drilling range from 19 to 26℃/km, which is lower than that (25—30℃/km) for the global continental area and similar to that for the KTB (21—28℃/km). Thermal conductivity measurements for 44 core samples show that the ultra-high pressure (UHP) metamorphic rocks have 50% higher thermal conductivity (with a mean of 3.94±1.26 W/mK) than that for the average value of the upper crust. The measured heat flow values vary between 76 and 80 mW/m², higher than that for the global continental area (65±1.6 mW/m²) and the continental China (61±15.5 mW/m²) as well as the adjacent North Jiangsu Basin (68 mW/m²), but lower than that below 1000 m in the KTB (85 mW/m²). The elevated heat flow in the pilot-boreholes can be attributed to the lateral heat concentration due to higher rock thermal conductivity of the UHP belt than that of the adjacent rocks. Lower deep temperature in the target area of the deep drilling can be expected due to the lower measured temperature gradient, which means that the Sulu area is geothermally suitable for continental deep drilling.     

Simulation of the western North Pacific summer monsoon by regional ocean–atmosphere coupled model:impacts of oceanic components

A successful simulation of the western North Pacific summer monsoon needs a regional ocean–atmosphere coupled model(ROAM). How the performance of ROAM relies on the oceanic component model remains unknown. In this study, the authors investigated the effects of different oceanic components on the simulation of western North Pacific(WNP) summer monsoon in a ROAM. Three cases of simulations were performed, viz. the summer of 1998(El Nin o decaying phase), 2004(El Nin o developing phase), and 1993(the non-ENSO phase). Results show that the coupled simulations for different ENSO phases exhibit improvements in the simulation of location of Meiyu rainband and spatial distribution of monsoon low-level flow over WNP, whereas the systemic cold biases of sea surface air temperature are further increased. The coupled simulations with different oceanic components show similar performance, which is not ENSO phase dependent. For the case of the summer of 1998, a slightly stronger western Pacific subtropical high and colder sea surface air temperature are found in the simulation with colder sea surface temperature(SST) biases. The colder SST biases are partly contributed by the ocean dynamics processes because the sea surface net flux favors a warmer SST. This study suggests that the dependence of performance of ROAM over WNP on oceanic models is much weaker than that on atmospheric models.     

Record-breaking SST over mid-North Atlantic and extreme high temperature over the Jianghuai–Jiangnan region of China in 2013

In July 2013, the Jianghuai–Jiangnan region of China experienced a persistent extreme high temperature,and the surface air temperature(SAT) over many areas of the region set a new record, which had a profound impact on people's lives. This study explored the possible mechanism for this extreme climate phenomenon. The results show that the sea surface temperature(SST) over the midNorth Atlantic in July 2013 was the warmest observed over the past 160 years. The strong anomaly of the SST connects to the East Asian upper level westerly and western Pacific subtropical high(WPSH) via the teleconnection wave train and further contributes to the SAT variability over the Jianghuai–Jiangnan region; this connection could be one possible mechanism for the formation of the recordbreaking extreme hot event(EHE) over the Jianghuai–Jiangnan region in July 2013. In addition, for the EHE over the Jianghuai–Jiangnan region, the role of the WPSH was generally emphasised. This study found that the variability of the upper level westerly over the Jianghuai–Jiangnan region is also an important climate factor impacting the SAT of the region. In particular, the record-breaking weakness of the upper level westerly corresponded to the record-breaking SAT over the Jianghuai–Jiangnan region in July 2013. These results indicate that the role of the upper level westerly should be emphasised in addition to the WPSH, according to both the variability in the summer air temperature and the EHE over the Jianghuai–Jiangnan region.     

Carbon isotopic composition,turnover and origins of soil CO<Subscript>2</Subscript> in a monsoon evergreen broadleaf forest in the Dinghushan Biosphere Reservoir,South China

Carbon isotopic compositions of soil CO2 in rainy season (July) from two natural soil profiles (DHLS & DHS) in the monsoon evergreen broadleaf forest in the Dinghushan Biosphere Reservoir (DBR), South China, are presented. Turnover and origins of soil CO₂ are preliminarily discussed in this paper. Results show that the content of soil CO2 varies between 6120 and 18718 ppmv, and increases with increasing depth until 75 cm, and then it declines. In DHLS, soil CO₂ δ¹³C ranges from −24.71‰ to −24.03‰, showing a significant inverse correlation (R²＝0.91) with the soil CO₂ content in the same layer. According to a model related to soil CO₂ δ¹³C, the soil CO₂ is mainly derived from the root respiration (>80%) in DHLS. While in DHS, where soil CO₂ ? 13C ranges from −25.19‰ to −22.82‰, soil CO₂ is primarily originated from the decomposition of organic matter (51%–94%), excluding the surface layer (20 cm, 90%). Radiocarbon data suggest that the carbon in soil CO₂ is modern carbon in both DHLS and DHS. Differences in ¹⁴C ages between the “oldest” and “youngest” soil CO₂ in DHLS and DHS are 8 months and 14 months, respectively, indicating that soil CO₂ in DHLS has a faster turnover rate than that in DHS. The ¹⁴C values of soil CO₂, which range between 100.0‰ and 107.2‰ and between 102.5‰ and 112.1‰ in DHLS and DHS, respectively, are obviously higher than those of current atmospheric CO₂ and SOC in the same layer, suggesting that soil CO₂ is likely an important reservoir for Bomb-¹⁴C in the atmosphere.     

Estimation of the rational wa-ter area for controlling wind erosion in the dried-up basin of the Ebinur Lake and its effect detection

The Ebinur Lake region was described as a “Green Labyrinth” in “Xinjiang Map Records: Records of Rivers” published in 1910, however, the ecology and environment in the region have been seriously degenerated due to the impacts of human activities during the recent 40 years. A dried-up lake basin with an area of 107.4 km² forms in its northwestern part, is covered by unconsolidated silt deposit without vegetation, and has become one of the main dust sources of dust weathers in north Xinjiang, and the dust with an annual amount of 4.8×10⁶ t is blown out of the region by strong winds from the Alataw mountain-gap where there are 164 days occurring strong winds in a year. The rational water area and inflow of the Ebinur Lake for improving the ecology in the lake region and effectively controlling wind erosion in the dried-up lake basin are estimated using the water balance equation after analyzing the current ecological problems and the relationship be-tween the granular composition of deposit in the dried-up lake basin and the dust weathers, and the ecological effects in recent years are monitored. It is considered that the water area of the Ebinur Lake for improving the ecology in the lake region and effec-tively controlling wind erosion in the dried-up lake basin should be 800 km² at least, and the annual volume of surface runoff and groundwater recharging the lake should be over 7.92×10⁸ m³.     

Noble gas isotopic compositions of deep carbonate rocks from the Tarim Basin

Abundances and isotopic compositions of noble gases (He, Ne, Ar, Kr) with various existence states in carbonate rocks from the Tacan1 Well have been investigated by means of the stepwise heating technique. The elemental abundance patterns of noble gases in the samples show the enrichment of heavy noble gases and depletion of ²⁰Ne relative to the atmosphere, which are designated as type-Ⅰand are similar to that observed in water, natural gases and sedimentary rocks. The ³He/⁴He ratios of deep carbonate samples at lower and medium temperature (300—700℃) and a majority of samples at higher temperature (1100—1500℃) steps are very similar to those of natural gases in the same strata in this area, this feature of radiogenic crustal helium shows that the Tazhong Uplift is relatively stable. However, significant helium and argon isotopic anomalies are found at the 1100℃ step in the Middle-Upper Ordovician carbonate rock, suggesting the incorporation of mantle-derived volatiles, this may be due to minor igneous minerals contained in sedimentary carbonate rocks. The ⁴⁰Ar/ ³⁶Ar ratios in the Cambrian carbonate rock are slightly higher than those in Ordovician carbonate rocks, which may reflect the influence of the chronologic accumulation effect of crust radiogenic ⁴⁰Ar. Argon isotopes of various existence states in source rocks are much more different, both ³⁸Ar/ ³⁶Ar and ⁴⁰Ar/ ³⁶Ar ratios at the higher temperature steps are higher than those at the lower temperature steps.     

Effects of autumn-winter Arctic sea ice on winter Siberian High

The intensity of the winter Siberian High has significantly negative correlations with Arctic sea ice concentration anomalies from the previous autumn to winter seasons in the Eastern Arctic Ocean and Siberian marginal seas. Our results indicate that autumn-winter Arctic sea ice concentration and concurrent sea surface temperature anomalies are responsible for the winter Siberian High and surface air temperature anomalies over the mid-high latitudes of Eurasia and East Asia. Numerical experiments also support this conclusion, and consistently show that the low sea ice concentration causes negative surface air temperature anomalies over the mid-high latitudes of Eurasia. A mechanism is proposed to explain the association between autumn-winter sea ice concentration and winter Siberian High. Our results also show that September sea ice concentration provides a potential precursor for winter Siberian High that cannot be predicted using only tropical sea surface temperatures. In the last two decades (1990–2009), a strengthening trend of winter Siberian High along with a decline trend in surface air temperature in the mid-high latitudes of the Asian Continent have favored the recent frequent cold winters over East Asia. The reason for these short-term trends in winter Siberian High and surface air temperature are discussed.     

Synthesis mechanism of LiNiVO4 by wet chemical method and mixed valence of nickel and vanadium

The single phase LiNiVO₄ has been successfully synthesized by adopting a new mild liquid route with oxalic acid as both complexant and precipitant, and this method is named the CPG method. The products were obtained by sintering the dry gel precursor which was prepared by the CPG method at 200—850℃ for 2—10 h in air. The products were tested by XRD, XPS, ESR and TGA-DTA, and the results indicate that the single phase LiNiVO₄ could be obtained at 450℃ for 2—3 h in air and LiNiVO₄ was still steady at 850℃ for 10 h. The valence analyses show that in LiNiVO₄ the valence of lithium is +1, both nickel and vanadium have the mixed valence, namely +2, +3 for nickel and +4, +5 for vanadium respectively. The LiNiVO₄ can be expressed as LiNi³⁺_xNi²⁺_1-xV⁴⁺_xV⁵⁺_1-xO₄ (0≤x<1). The pyrolysis mechanism of the dry gel is also discussed.