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1.
双金属MEL结构杂原子分子筛催化性能的研究   总被引:1,自引:0,他引:1  
研究了H2O存在下双金属CrCo-、VCr-、VCo-、VNi-、CrNiMEL结构杂原子分子筛对环己醇、2-丁醇、2-丙醇、环己烯的选择氧化催化性能,并考察了反应温度及H2O2浓度对环己烯催化氧化反应的影响。结果表明,反应物不同,活性亦不同,其顺序为环为已烯〉环己醇〉2-丁醇〉2-丙醇;CrNi、CrCoMEL分子筛活性较高,而VCo-、VCr-、VNiMEL分子筛活性较低,反应温度和H2O2浓  相似文献   

2.
激光熔覆WC—Co系合金层   总被引:5,自引:0,他引:5  
用激光熔覆的方法在18CrMnTi钢的表面熔覆WC-Co系合金层,获得细小的组织,硬度达到1600HV,熔覆层平均厚度0.5mm。该熔覆层的耐磨性与同种钢材的渗碳层、等离子喷涂Cr2O3涂层、离子氮化层的耐磨性相比较,均有大幅度提高。  相似文献   

3.
AlCr2O3体系燃烧合成反应的热力学分析与实验   总被引:3,自引:0,他引:3  
首先对Al-Cr2O3体系的燃烧合成反应进行了热力学分析,讨论了起始反应温度,Al2O3和Cr2O3稀释剂以及MoO3添加剂对Al-Cr2O3体系的绝热反应温度的影响。最后对Al-Cr2O3体系进行了热爆和点燃模式的燃烧合成实验,并对实验结果进行了分析。  相似文献   

4.
1673K下,采用-MoCr+Cr2O3ZrO2(MgO){Cu+Cr}aloy+(Cr2O3)slagMo+固体电解质电池测定了BaOBaF2Cr2O3渣系中Cr2O3的活度.研究结果表明,Cr2O3的活度随其浓度升高而升高,随XBaO/XBaF2升高而降低.根据实验及X射线衍射结果推测了该渣系的等温相图,并作出了该渣系中Cr2O3的等活度图.  相似文献   

5.
1673K下,采用-Mo│Cr+Cr2O3‖ZrO2(MgO)‖{Cu+Cr}alloy+(Cr2O3)slag│M固体电解质电池测定了BaO-BaF2-Cr2O3渣系中Cr2O3的活度,研究结果表明,Cr2O3的活度随其浓度升高而升高。随XBaO/XBaF2升高而降低。根据实验及X射线衍射结果推测了该渣系的等温相图,并作出了该渣系中Cr2O4的等活度图。  相似文献   

6.
渗碳不锈钢的开发Oarpenter工艺技术公司为轴承和齿轮应用,开发了一种新的渗碳不锈钢,具有良好的抗腐蚀、耐热和抗疲劳性能。Pyrowear675不锈钢的组成为:Fe-13Cr-5.4Co-2.6Ni-0.8Mo-1.6V-0.4Si-0.07C-...  相似文献   

7.
本文对热作模具钢3Cr2W8V和4Cr5MoSiV1钢的耐磨性、高温拉伸、冲击性能及热疲劳抗力进行了对比研究.结果表明,4Cr5MoSiV1钢的高温强韧性优于3Cr2W8V钢,且具有更高的耐磨性及热疲劳抗力,更适宜做摩擦压力机热锻模.  相似文献   

8.
深冷处理引起高速钢的性能改善与微结构变化   总被引:10,自引:0,他引:10  
介绍了对W6Mo5FCr4VK2、W18Cr4V高速钢刀具进行-196℃深冷处理的实效;研究表明,对于经过淬火与三回火的高速钢、引起其强韧性提高的主要原因是深冷处理导致了材料的晶粒细化与碳化物微小颗粒的弥散析出,残余奥氏体向马氏体转化不是其韧性提高的主要原因。  相似文献   

9.
9Cr—1Mo—V—Nb耐热钢焊接接头组织分析   总被引:11,自引:0,他引:11  
文章分析了9Cr-1Mo-V-Nb与几种常用耐热钢焊接接头的显微组织,表明试验的各种焊接接头的机械性能良好.各焊接接头回火后焊缝区的显微组织均为回火马氏体,这与9Cr-1Mo-V-Nb钢正火回火态的显微组织相类似,但晶粒相对粗大.9Cr-1Mo-V-Nb同类钢焊接接头过热区显微组织为回火马氏体,局部地区有少量δ铁素体.9Cr-1Mo-V-Nb钢与合金元素较低的异类钢焊接接头过热区的晶粒长大程度较同类钢为甚,碳化物聚集长大较显著.  相似文献   

10.
对9Cr18Mo和GCr15两种钢的腐蚀,磨蚀和腐蚀疲劳行为进行了实验研究,结果表明,在质量分数为2%-5%硫酸,1%盐酸,40%硝酸,3.5%NaCl水溶液和蒸馏水中,9Cr18Mo的抗腐蚀性能优于GCr15;在含0.02%与5%沙量的沙浆中,9Cr18Mo的年磨蚀率低于GCr15的数值;  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

13.
AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…  相似文献   

14.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

15.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

16.
本文叙述了对海南岛及其毗邻大陆边缘白垩纪到第四纪地层岩石进行古地磁研究的全部工作过程。通过分析岩石中剩余磁矢量的磁偏角及磁倾角的变化,提出海南岛白垩纪以来经历的构造演化模式如下:早期伴随顺时针旋转而向南迁移,后期伴随逆时针转动并向北运移。联系该地区及邻区的地质、地球物理资料,对海南岛上述的构造地体运动提出以下认识:北部湾内早期有一拉张作用,主要是该作用使湾内地壳显著伸长减薄,形成北部湾盆地。从而导致了海南岛的早期构造运动,而海南岛后期的构造运动则主要是受南海海底扩张的影响。海南地体运动规律的阐明对于了解北部湾油气盆地的形成演化有重要的理论和实际意义。  相似文献   

17.
There are numerous geometric objects stored in the spatial databases. An importance function in a spatial database is that users can browse the geometric objects as a map efficiently. Thus the spatial database should display the geometric objects users concern about swiftly onto the display window. This process includes two operations:retrieve data from database and then draw them onto screen. Accordingly, to improve the efficiency, we should try to reduce time of both retrieving object and displaying them. The former can be achieved with the aid of spatial index such as R-tree, the latter require to simplify the objects. Simplification means that objects are shown with sufficient but not with unnecessary detail which depend on the scale of browse. So the major problem is how to retrieve data at different detail level efficiently. This paper introduces the implementation of a multi-scale index in the spatial database SISP (Spatial Information Shared Platform) which is generalized from R-tree. The difference between the generalization and the R-tree lies on two facets: One is that every node and geometric object in the generalization is assigned with a importance value which denote the importance of them, and every vertex in the objects are assigned with a importance value,too. The importance value can be use to decide which data should be retrieve from disk in a query. The other difference is that geometric objects in the generalization are divided into one or more sub-blocks, and vertexes are total ordered by their importance value. With the help of the generalized R-tree, one can easily retrieve data at different detail levels.Some experiments are performed on real-life data to evaluate the performance of solutions that separately use normal spatial index and multi-scale spatial index. The results show that the solution using multi-scale index in SISP is satisfying.  相似文献   

18.
19.
The elongation method,originally proposed by Imamura was further developed for many years in our group.As a method towards O(N)with high efficiency and high accuracy for any dimensional systems.This treatment designed for one-dimensional(ID)polymers is now available for three-dimensional(3D)systems,but geometry optimization is now possible only for 1D-systems.As an approach toward post-Hartree-Fock,it was also extended to  相似文献   

20.
Various applications relevant to the exciton dynamics,such as the organic solar cell,the large-area organic light-emitting diodes and the thermoelectricity,are operating under temperature gradient.The potential abnormal behavior of the exicton dynamics driven by the temperature difference may affect the efficiency and performance of the corresponding devices.In the above situations,the exciton dynamics under temperature difference is mixed with  相似文献   

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