Synoptic-scale variation of δ18O in summer monsoon rainfall at Lijiang, China

Based on the daily δ~(18)O data in June―September 2003 at Lijiang and the daily mean NCEP/ NCAR reanalysis data, synoptic-scale variation of δ~(18)O in summer monsoon rainfall was investigated. The 'precipitation amount effect' is obvious for the daily δ~(18)O variation, whereas the 'temperature effect' is insignificant. Alternate occurrences of active phase and break phase of the southwest monsoon probably influence the synoptic-scale δ~(18)O variation prominently. Moreover, the isotopic composition in precipitation during the late monsoon months is presumably influenced significantly by recycling of monsoon precipitation. Both the above factors disturb the 'amount effect' of isotopic variation in the monsoon region. This study also indicates that the synoptic-scale rainfall δ~(18)O variation at Lijiang in summer is domi-nated by the Indian monsoon depression (low pressure) system at large scale. These results are important for further studying the 'amount effect' and reconstructing paleoclimate in the monsoon region.     

Preliminary study of microscale zircon oxygen isotopes for Dabie-Sulu metamorphic rocks： Ion probe in situ analyses

151 in situ analyses of oxygen isotopes were carried out by ion micro-probe for zircons from 8 localities of HP-UHP metamorphic rocks including eclogites in the Dabie-Sulu terrane. The results show significant heterogeneity in δ^18O values, with variation in different rocks from -8.5‰ to 9.7‰ and within one sample from 2‰ to 12‰. No measurable difference in δ^18O was observed between protolith magmatic (detrital) zircons and metamorphic recrystallized zircons within analytical uncertainties from the ion micro-probe measurements. This indicates that the metamorphic zircons have inherited the oxygen isotopic compositions of protolith zircons despite the HP to UHP metamorphism. According to their protolith ages from zircon U-Pb in situ dating by the same ion micro-probe, two groups of oxygen isotope composition are recognized, with one having δ^18O values of 6‰-7‰ for old protolith of 1.9-2.5 Ga ages and the other 0‰-2‰ for young protolith of 0.7-0.8 Ga ages. The latter anomalously low δ^18O values of zircons indicate that the magma has had the obvious involvement of meteoric water when forming the young protolith of high-grade metamorphic rocks. This may be correlated with the snowball Earth event occurring in South China and the world elsewhere during the Neoproterozoic.     

Helium isotope compositions of Machangqing copper deposit in western Yunnan, China

Helium isotopic composition of inclusion fluid in pyrites from Machangqing copper deposit, China, has been measured. The measurements, with³He/⁴He ratios ranging from 0.46–2.08 Ra, indicate that the helium in ore-forming fluid is a mixture of crust and mantle, and are consistent with the fact that the parental magma responsible for the formation of ore-forming fluid of the deposit is of crust-mantle provenance.     

Variability of snail growing season at the Chinese Loess Plateau during the last 75 ka

Knowledge of seasonal climate change is one of the key issues facing Quaternary paleoclimatic studies and estimating seasonal climate change is difficult,especially changes such as seasonal length on glacial-interglacial timescales.The stable isotope composition from seasonal land snail shells provides the potential to reveal seasonal climatic features.Two modern land snail species,cold-aridiphilous Pupilla aeoli and thermo-humidiphilous Punctum orphana,were collected from different climatic zones in 18 localities across the Chinese Loess Plateau,spanning 11 degrees of longitude and covering a range of 1000 km2.The duration of the snail growing season(temperature ≥10℃) was shorter(202 ± 6 d) in the eastern Loess Plateau compared with in the western Loess Plateau(162 ±7 d).The δ13C of P.aeoli shells was ?9.1‰ to ?4.7‰ and ?5.0‰ to 0.3‰ for δ18O.For P.orphana,the δ13C ranged from ?9.1‰ to ?1.9‰ and ?8.9‰ to ?2.9‰ for δ18O.Both the δ13C and δ18O differences between the two snail species were reduced from the east to the western Loess Plateau(2.8‰ to 0.2 ± 1.1‰ for δ13C and 4.7‰ to 2.9 ± 1.3‰ for δ18O).These isotopic differences roughly reflect the difference in the growing season lengths between the east and west Loess Plateau indicating that the duration of the snail growing season shortens by 15 d or 19 d if the difference decreases by 1‰ in δ13C or δ18O,respectively.Thus,the difference in δ13C and δ18O between both snail species can be used to reveal the length of the snail growing season in the past.Based on our investigation,the length of the snail growing seasons from the Xifeng region during the last 75 ka was reconstructed.During the mid-Holocene(8-3 ka),the mean isotopic difference from both snail species reached maximum values of 2.6 ± 0.7‰ and 2.1 ± 1.4‰ for δ13C and δ18O,respectively.This was followed by MIS 3 that ranged from 2.5 ± 0.4‰ for δ13C and 1.6 ± 0.8‰ for δ18O.The Last Glacial Maximum changed by only 0.2‰ and 0.4‰ for δ13C and δ18O,respectively.Therefore,we estimate that the duration of the snail growing seasons to be ～200 ± 10 d during the mid-Holocene,190 ± 6 d in MIS 3 and 160 ± 3 d during the last glacial period.     

Oxygen isotope variation in the water cycle of the Yamzho lake Basin in southern Tibetan Plateau

Given the potential use of stable isotope in the paleoclimate reconstruction from lacustrine records as well as in the local hydrology cycle, it is crucial to understand the processes of stable isotope evolution in catchment in the Tibetan Plateau region. Here we present a detailed study on the water oxygen isotope based on 2 years observation including precipitation, river water and lake water in the Yamzho Lake, south of the Tibetan Plateau. Temporal variation of local precipitation 5180 shows an apparent ＂monsoon cycle＂. In monsoon season, 5180 in waters is lower. In non-monsoon season, δ^18O in precipitation and lake water is higher and higher river δ^18O exists in spring, probably reflecting the effect of land surface evaporation, together with the higher δ^18O values in spring precipitation. It is also found that the surface lake water δ^18O varies seasonally and annually. The lower lake water δ^18O in the late summer is apparently related to the summer monsoon precipitation. The mean δ^18O value of lake water in 2007 is 1.2‰ higher than that in 2004, probably due to the less monsoon precipitation in summer of 2007, as can be confirmed from the precipitation data at the Langkazi meteorological data. It is also found that an obvious shift of vertical lake water δ^18O reflects the fast mixture of lake water. δ^18O values of lake water are over 10‰ higher than those of precipitation and river water in this region due to the evaporation fractionation. The modeled results show that the evaporation process of the lake water is sensitive to relative humidity, and the present lake water δ^18O reflects a relative humidity of 51% in the Yamzho Lake. It shows that the lake will take 30.5 years to reach present lake water δ^18O given a large shift in the input water δ^18O. The modeled results also reveal that surface lake water temperature and inflow δ^18O have slight effect on the isotopic balance process of lake water in the Yamzho Lake.     

Water isotope variations in the snow pack and summer precipitation at July 1 Glacier, Qilian Mountains in northwest China

This paper presents the stable isotope data of the snow pack and summer precipitation collected at the July 1 Glacier, Qilian Mountains in northwest China and analyses their relationships with meteorologi- cal factors. On an event scale, there is no temperature effect on the δ 18O values in the summer pre- cipitation, whereas the amount effect is shown to be clear. By tracing the moisture transport history and comparing the precipitation with its isotopic composition, it is shown that this amount effect not only reflects the change in moisture trajectory, which is related to the monsoon activities, but is also associated with the cooling degree of vapor in the cloud, the evaporation of falling raindrops and the isotopic exchange between the falling drops and the atmospheric vapor. As very little precipitation occurs in winter, the snow pack profile mainly represents the precipitation in the other three seasons. There are low precipitation δ 18O ratios in summer and high ratios in spring and autumn. The Meteoric Water Line (MLW) for the summer precipitation is δ D = 7.6 δ 18O 13.3, which is similar to that at Delingha, located in the south rim of the Qilian Mountains. The MWL for the snow pack is δ D = 10.4 δ 18O 41.4, showing a large slope and intercept. The deuterium excess (d) of the snow pack is positively correlated with δ 18O, indicating that both d and δ 18O decrease from spring to summer and increase from early autumn to early spring. This then results in the high slope and intercept of the MWL. Sea- sonal fluctuations of d in the snow pack indicate the change of moisture source and trajectory. During spring and autumn, the moisture originates from continental recycling or rapid evaporation over rela- tively warm water bodies like Black, Caspian and Aral Seas when the dry westerly air masses pass over them, hence very high d values in precipitation are formed. During summer, the monsoon is responsi- ble for the low d values. This indicates that the monsoon can reach the western part of the Qilian Mountains.     

Modern stalagmite oxygen isotopic composition and its implications of climatic change from a high-elevation cave in the eastern Qinghai-Tibet Plateau over the past 50 years

An oxygen isotope record of a stalagmite from Huanglong Cave in the eastern Qinghai-Tibet Plateau dated with 230Th and 210Pb methods provides variations of the Asian monsoon with an average resolu-tion of 1 year over the past 50 years. This study shows that the δ18O of dripwater in the cave represents the annual mean δ18O of local meteoric precipitation and the stalagmites were deposited in isotopic equilibrium. A comparison of the stalagmite δ18O record with instrumentally meteorological data indi-cates that shifts of the δ18O are largely controlled by the amount effect of meteoric precipitation con-veyed through the southwest monsoon(the Indian monsoon) and less affected by temperature. Therefore,the variations of δ18O record reflect the changes in monsoon precipitation on inter-annual time scales under the influence of the southwest monsoon. Like many other stalagmite δ18O records in the Asian monsoon regions,the δ18O record of the stalagmite from Huanglong Cave also reveals a gradually enriched trend during the past 50 years,i.e. relatively enriched in 18O. This trend may indicate the decline of the Asian monsoon intensity which is consistent with the decrease of monsoon indices. The weakening of the modern Asian monsoon well matched with the temperature changes in strato-sphere,which may illustrate that the weakening of the monsoon mainly results from the lowering of solar radiation.     

Indian monsoon influences altitude effect of δ~(18)O in precipitation/river water on the Tibetan Plateau

The δ^18O variation in precipitation acquired from 28 stations within the network of Tibetan Observation and Research Platform （TORP） is studied, with the focus on the altitude effect of δ^18O in river water during monsoon precipitation in an effort to understand the monsoon influence on isotopic composition in annual river water. It is found that δ^18O in precipitation on the Plateau is influenced by different moisture sources, with significant Indian monsoon influence on δ^18O composition in plateau precipitation and river water. The δ^18O of water bodies in the monsoon domain is generally more depleted than that in the westerly domain, suggesting gradual rainout of southwesterly borne marine moisture in the course of long-distance transportation and lifting over the Himalayas. The lapse rate of δ^18O in river water with altitude is the largest during monsoon precipitation, due to the increased temperature vertical gradient over the southern Plateau region controlled by monsoon circulation. The combination of δ^18O in river water in monsoon （wet） and non-monsoon （dry） seasons shows a larger lapse rate than that in non-monsoon （dry） season alone. As the altitude effect of δ^18O in precipitation and river water on the Tibetan Plateau results from the combined effect of monsoon moisture supply and westerly moisture supply, the δ^18O composition and its altitude effect on the Plateau during monsoon seasons should be considered in the reconstruction of paleoelevation of the Tibetan Plateau.     

Experimental study on the P wave velocity in rocks from lower crust and crust-mantle transitional zone beneath the Hannuoba

Cenozoic basalt-borne mafic granulite-facies plagioclase pyroxenite and eclogite-facies garnet pyroxenite xenoliths from the Hannuoba, as well as nearby Archean terrain granulites, are selected for the experimental study on the P wave velocity at high temperature and high pressure in order to reveal the present-day compositional features for the lower crust and crust-mantle transitional zone. Results show that mafic xenoliths have high Vp (7.0～8.0 km/s), in contrast, the Archean terrain granulites have low Vp (<7.0 km/s). High Vp mafic xenoliths can represent the present-day compositional features for the lower crust and crust-mantle transitional zone beneath the Hannuoba. This provides new evidence for the crust vertical growth and the formation of the crust-mantle transitional zone resulting from the magma underplating. Low Vp Archean granulite still remains the characteristics of the early lower crust.     

Different fossil brachiopod skeletal microstructure of different information on carbon and oxygen isotope contents

Whether there is isotope fractionation caused by metabolism (vital effect) of bra-chiopods in geologic time with their shells' δ18O and δ13C has been studied intensively in the field of carbonate isotope geochemistry in the last decade. The approach to dealing with the problem is by comparing isotopic compositions between different fossil brachiopods with their secondary shells which usually consist of two kinds of layers: prismatic layer composed of prismatic low-Mg calcite crystals, and fibrous layer comprising fibrous ones. The isotopic compositions of the two secondary layers have been investigated by comparison of carbon and oxygen isotopic compositions between five genera of Atrypidae collected from Givetian, Middle Devonian in Longmenshan, Sichuan Province, China. Due to different microstructures of the two secondary layers, their abilities to prevent from being altered by diagenesis are also different, thus in their state of preservation. The fibrous layer is more susceptible to the diagenetic alternation than the prismatic one in the way of microfracture filling between fibrous crystals in the elongated direction. Consequently, the isotopic compositions of the fibrous layer are systematically lower than those of the prismatic layer in their δ18O and δ13C by (0.53 ± 0.08)‰ and (0. 12 ± 0.04)‰, respectively. This suggests that further studies of vital effects with brachiopod in geological times by comparison of isotopic compositions in the secondary shell take into consideration of the different states of preservation between the fibrous and the prismatic layer.     

Zircon chronology and REE geochemistry of granulite xenolith at Hannuoba

The lower crustal xenolith of mafic two-pyroxene granulite (the majority) and hypersthene granulite in the Cenozoic basalt at Hannuoba have the characteristics of igneous blastic structure and granulite facies metamorphic recrystallization. Study on the zircon chronology and REE geochemistry of granulite xenolith shows that the underplating of basic magma into the lower crust during late Mesozoic led to the formation of mafic accumulate, which further through metamorphism of granulite facies formed the high-density and high-velocity crustal bottom layer at the lower crust. This suggests that the underplating of mantle magma is the important way for the vertical overgrowth of continental crust since the Phanerozoic and provides new evidence for crust-mantle interaction.     

He-Ar isotopic system of fluid inclusions in pyrite from the molybdenum deposits in south margin of North China Block and its trace to metallogenetic and geodynamic background

The helium and argon isotopic compositions of the ore-forming fluids from the molybdenum deposits such as Jinduicheng, Donggou, Shijiawan, and Sandaozhuang, which are located in the East Qinling molybdenum belt in south margin of North China Block （SMCNB）, are reported in this paper. The origin and the evolution of the ore-forming fluids and their coupled-relationships with the intra-continental collision and orogenic process of Qinling Orogen in Mesozoic-Cenozoic have been discussed. The 3He/4He and 40Ar/36Ar values （3He/4He=1.38-3.64 Ra, and 40Ar/36Ar=295.68-346.39, respectively） of the fluid inclusions in pyrite from the molybdenum deposits in East Qinling suggest that, the ore-forming fluid system is mixed by two end members. One is the high temperature deep-derived fluid congenetic with the porphyries generated by crust-mantle mixing, and the other is the low-temperature meteoric water which is rich in crustal radiogenic He with the component of atmospheric Ar. From the Pb isotopic composition, and ore-bearing potential of the porphyry and the regional stratum, we can conclude that the ore-forming materials of the deposits in the East Qinling molybdenum belt are derived from the deep source by the mixing of lower crust and upper mantle. Therefore, the formation of the molybdenum deposits in SMNCB can be related to the crust-mantle interaction, which is accompanied by the intra-continental orogenic and extension process in the post-collision period of Qinling Orogen. The granitic porphyries which are related to Mo mineralization are not simple crust-remelting type granites or S type granites, but belong to syntexis-type or mantle-derived granites, hence their formation has a profound and regional geodynamic background.     

Oxygen and carbon isotope records of calcareous nannofossils for the past 1 Ma in the southern South China Sea

Oxygen and carbon isotopic analyses have been carried out on calcareous nannofossils from ODP Site 1143 in the southern South China Sea. The results demonstrate that the δ18O values of calcareous nannofossils for the past 1 Ma vary systematically with those of planktonic and benthic foraminifera from the same site. But the average δ18O value of nannofossils is 1.869‰ higher than that of planktonic foraminifera, and is 3.855‰ lower than that of benthic foarminifera. There are systematic differences between the δ13C values of nannofossils, planktonic foarminifera and benthic foraminifera. The average δ13C of nannofossils is 0.756‰ higher than that of benthic foraminifera, and is 0.460‰ lower than that of planktonic foraminifera. The δ13C values of nannofossils exhibit a significant positive shift beginning near isotope stage 14 and lasting until stage 8. This study also finds that there is a close ralationship between the δ13C of nannofossils and the percentage of Florisphaera profunda. This implies that the δ13C of nannofossils can be used as an indicator of sea water surface paleoproductivity.     

Southwest monsoon changes indicated by oxygen isotope of ostracode shells from sediments in Qinghai Lake since the late Glacial

The δ 18O records of ostracode shells in sediments of core QH-2000 from Qinghai Lake can be used as a better proxy to reflect monsoon changes. Low monsoon precipitation between 17.5 and 11 cal. ka BP is indicated by positive δ 18O values averaging 2.37‰. A fast shift in δ 18O from positive at 11 cal. ka BP to negative at 10 cal. ka BP indicates sharp increase of monsoon precipitation. An interval of generally high monsoon precipitation is observed between 10 and 6 cal. ka BP with δ 18O values averaging -2.15‰. Decrease of monsoon precipitation between 6 and 2.5 cal. ka BP is indicated by positive δ 18O values. δ 18O keeps positive values averaging 3.0‰ between 2.5 and 0 cal. ka BP suggesting low high monsoon precipitation. The climatic changes indicated by δ 18O records of ostracode shells in sedi- ments of core QH-2000 from Qinghai Lake and our broader regional comparison show that the climate in Qinghai Lake since the late Glacial is probably controlled by southwest monsoon other than southeast monsoon.     

Simulations of seasonal variations of stable water isotopes in land surface process model CLM

In this study, we simulated and analyzed the monthly variations of stable water isotopes in different reservoirs at Manaus, Brazil, using the Community Land Model （CLM） that incorporates stable isotopic effects as a diagnostic tool for understanding stable water isotopic processes, filling the observational data gaps and predicting hydrometeorological processes. The simulation results show that the δ^18O values in precipitation, vapor and surface runoff have distinct seasonality with the marked negative correlations with corresponding water amount. Compared with the survey results by the International Atomic Energy Agency （IAEA） in co-operation with the World Meteorological Organization （WMO）, the simulations by CLM reveal the similar temporal distributions of the δ^18O in precipitation. Moreover, the simulated amount effect between monthly δ^18O and monthly precipitation amount, and MWL （meteoric water line） are all close to the measured values. However, the simulated seasonal difference in the δ^18O in precipitation is distinctly smaller than observed one, and the simulated temporal distribution of the δ^18O in precipitation displays the ideal bimodal seasonality rather than the observed single one. These mismatches are possibly related to the simulation capacity and the veracity in forcing data.     

The altitude effect of δ 18O in precipitation and river water in the Southern Himalayas

The lapse rate of water isotopes is used in the study of the hydrologic cycle as well as in the estimation of uplift of the Tibetan Plateau.The greater elevation contrast in the Southern Himalayas allows for a detailed discussion about this lapse rate.We analyze variations of 18δO in precipitation and river water between 1320 m and 6700 m elevations in the Southern Himalayas,and calculate the specific lapse rate of water 18δO.The results show that the multi-year average lapse rate in precipitation over this region is 0.15‰/100 m.The one-year average lapse rate is 0.17‰/100 m from three sites along the Southern Himalayas.The two results agree,but are much lower than the global average of 0.28‰/100 m.This work also shows that there is a difference in precipitation 18δO lapse rate between the monsoon and non-monsoon seasons.The calculated precipitation lapse rate is much lower than that in surface water.     

Isotopic composition of atmospheric water vapor before and after the monsoon’s end in the Nagqu River Basin

Atmospheric water vapor samples were collected in the Nagqu River Basin in the middle of Tibetan Plateau between August and October in 2004. Results show that there exist some fluctuations of the δ^18O of atmospheric water vapor, especially before and after the monsoon＇s end.Moreover, the variety trend of the δ^18O of atmospheric water vapor inverse correlates with that of dew point. Precipitation events make an important effect upon the variation of δ^18O of atmospheric water vapor. During the whole sampling period, the δ^18O values of atmospheric water vapor are low while precipitation events occurred. The moisture origins w also contribute to the variation of δ^18O of atmospheric water vapor. The oceanic moisture transported by the southwest monsoon results in lower δ^18O of atmospheric water vapor in the Nagqu River Basin. Compared with the influence of the oceanic moisture, the δ^18O values, however, appear high resuiting from the effect of the continental air mass in this region.     

Origin of middle Miocene leucogranites and rhyolites on the Tibetan Plateau: Constraints on the timing of crustal thickening and uplift of its northern boundary

Leucogranites play a significant role in understanding crustal thickening, melting within continental collisional belts, and plateau uplift. Field investigations show that Miocene igneous rocks from the Hoh Xil Lake area mainly consist of two-mica leucogranites and rhyolites. We studied the Bukadaban two-mica leucogranites and the Kekao Lake, Malanshan and Hudongliang rhyolites by zircon U-Pb, muscovite and sanidine 40Ar/39Ar geochronology, and whole-rock geochemical and Sr-Nd isotopic analysis. Results yielded crystallization and cooling ages for the Bukadaban leucogranites of 9.7±0.2 and 6.88±0.19 Ma, respectively. Extrusive ages of the Kekao Lake and Malanshan rhyolites are 14.5±0.8 and 9.37±0.30 Ma, respectively. All rocks are enriched in SiO2 (70.99%-73.59%), Al2O3 (14.39%-15.25%) and K2O (3.78%-5.50%) but depleted in Fe2O3 (0.58%-1.56%), MgO (0.11%- 0.44%) and CaO (0.59%-1.19%). The rocks are strongly peraluminous (A/CNK=1.11?1.21) S-type granites characterized by negative Eu anomalies (δ Eu=0.18-0.39). In also considering their Sr-Nd isotopic compositions (87Sr/86Sri=0.7124 to 0.7143; δ Nd (9 Ma) =-5.5 to -7.1), we propose that these igneous rocks were generated through dehydration melting of muscovite in the thickened middle or lower crust of northern Tibet. Melting was probably triggered by localized E-W stretching decompression in the horse tails of Kunlun sinistral strike-slip faults. Reactivation of the Kunlun strike-slip faults, accompanied by emplacement of leucogranite and eruption of rhyolite in the Hoh Xil Lake area, indicates that large-scale crustal shortening and thickening in northern Tibet mainly occurred before 15 Ma. In addition, these findings suggest that the northern Tibetan Plateau attained its present elevation (~5000 m) at least 15 Ma ago.     

Determination and geological implication of O-Si isotope of the sediment core in the CC area, the Pacific Ocean

Conclusions  

Study of altitudinal lapse rates of δ18O in precipitation/river water with seasons on the southeast Tibetan Plateau

Seasonal δ^18O variation in water on the southeast Tibetan Plateau has been studied, showing the consistent variation pattern of δ^18O with altitude indicative of relevant atmospheric circulation processes. Study shows a similar variation pattern of fixed-site river water δ^18O with that of the precipitation δ^18O in southeast Tibet. δ^18O in regional rivers in southeast Tibet demonstrates a gradual depletion with increasing altitude, though the rates vary seasonally. The most depleted river ^18O occurs during the monsoon period, with the lowest δ^18O/altitude lapse rate. The river ^18O during the westerly period is also depleted, together with low δ^18O/altitude lapse rate. The pre-monsoon rivers witness the most enriched ^18O with least significant correlation coefficient with the linear regression, whilst the postmonsoon rivers witness the largest δ^18O/altitude lapse rate. Different coherence of seasonal δ^18O variation with the altitude effect is attributed to different moisture supplies. Though sampling numbers vary with seasons, the δ^18O-H linear correlation coefficients all reach the 0.05 confidence level, thus witnessing the variation features of δ^18O in seasonal river water due to the influence of atmospheric general circulation and land surface processes revealed from the altitudinal lapse rates.