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1.
为更深入的了解钙芒硝盐岩的溶解特性,促进水溶开采钙芒硝矿和盐穴储气库建造中钙芒硝夹层溶蚀的研究,对钙芒硝盐样以不同倾角在35℃恒温水中进行溶解速率和速度的实验。结果表明:钙芒硝在35℃恒温水中溶解速率和速度具有角度效应;倾角从90°~-90°变化时,溶解速率和速度越来越大,水溶采矿技术开采钙芒硝时应采用有利于上溶和侧溶,自下而上的开采技术;运用MATLAB对数据进行拟合,得出不同溶解角度下钙芒硝溶解速率和速度随时间变化规律的表达式,对水溶开采钙芒硝的相关研究和盐穴储气库夹层的溶蚀具有一定的指导和参考价值。  相似文献   

2.
在分析钙芒硝矿的化学组成和其溶解原理的基础上,通过实验研究了钙芒硝矿在不同碱性溶液中和不同溶解条件下溶解特性。结果表明,钙芒硝在碱性溶液中的溶解速度比较快,由于部分Na2SO4是由化学反应产生,因此属于化学溶解的范畴;钙芒硝在碱性溶液中的溶解速度与碱性强弱有关,碱性强溶解速度快,反之较慢;在溶解过程中会产生微溶物CaSO4,决定了钙芒硝在溶液流动的情况下速度较静态溶液的溶解速度快;实验结论的得出为较难溶于水的钙芒硝矿的地下水溶开采提供了一种有益的方法。  相似文献   

3.
含镁碳酸盐矿物在水中的溶解对浮选过程会产生影响.利用PHREEQC软件对菱镁矿和白云石在纯水中的溶解度进行了模拟计算.结果表明:温度对菱镁矿和白云石溶解度的影响规律不同;当溶液pH值为11时,菱镁矿和白云石的溶解度最低,分别为12.48,10.05 mg/L;除了定位离子,大部分金属阳离子和无机阴离子会增加含镁碳酸盐的溶解度;当菱镁矿、白云石在同一溶液中溶解平衡时,溶解度分别为14.03,3.16 mg/L.十二胺浮选体系中,降低矿物的溶解度有利于该浮选过程.  相似文献   

4.
研究CaF2 、ZnO和MgO以及配料组成、煅烧温度对硫硅酸钙 ( 2C2 S·CaSO4)单矿物和在贝利特 -硫铝酸盐水泥熟料中形成与分解的影响。结果表明 ,在 12 0 0℃以上 ,少量CaF2 或ZnO能促进 2C2 S·CaSO4的分解 ,而MgO则抑制其形成和分解 ;在多矿物组成体系中 ,碱度系数Cm升高 ,2C2 S·CaSO4的形成量减少 ,当Cm接近等于或大于 1.1时 ,熟料中基本上无 2C2 S·CaSO4形成 ;配料组成中CaSO4的量增加 ,则 2C2 S·CaSO4的形成量增加  相似文献   

5.
用硫酸和氢氧化钠作为调节剂,并采用间接碘量法分析测量了不同温度、不同pH下α和γ型蛋氨酸(DLMet)固体在水中的溶解平衡数据,在分析其离子化溶解机理的基础上建立溶解平衡模型,描述预测其溶解特性.实验结果研究表明:离子化平衡模型可准确地描述蛋氨酸在水中溶解情况和离子化程度,即随pH的增大,两种晶型的DLMet在水中的溶解度先减小后增大,极值点为等电点;温度升高使得两种晶型的DL-Met在水中溶解增加,且溶解度差值缩小.  相似文献   

6.
钙芒硝岩盐溶解特性的实验研究   总被引:3,自引:0,他引:3  
通过在NaOH,Na2CO3,NaHCO3, HCl溶液和H2O中的溶解实验,对钙芒硝的溶解特性进行了研究,得出了钙芒硝在氢氧化钠溶液中溶解速度较快的结论。由于其中一部分芒硝是由化学反应而生成的,因此其溶解属于化学溶解。  相似文献   

7.
高温高压条件下甲烷和二氧化碳溶解度试验   总被引:2,自引:1,他引:1  
根据不同温度和压力条件下测得的甲烷和二氧化碳两种气体在碳酸氢钠型水中的溶解度数据,对两种气体的溶解度与温度、压力及地层水矿化度之间的关系进行研究。结果表明:在地层水中的溶解机制不同,导致两种气体的溶解度值随温度、压力条件的变化具有不同的演变特征;综合前人低温(小于90℃)测试的溶解度数据,可将甲烷溶解度与温度之间的演变关系划分为缓慢递减(0~80℃)、快速递增(80~150℃)和缓慢递增(大于150℃)3个阶段;二氧化碳溶解度随温度的升高而逐渐降低,随压力升高而逐渐增大,其溶解与析离能力受压力影响更为明显;实际地层中,两种气体间溶解度的差异演变影响了天然气的空间分布。  相似文献   

8.
以邻甲基酚和BaCl2为原料合成了邻甲基酚钡.重量法证明,本实验样品的结构式可写为,该化合物新合成的样品和烘干后的样品在水中的溶解度有很大的差别,30℃时溶解度分别是6.60和0.07,50℃时分别是7.59和0.07,表明样品的溶解度随温度变化不大.  相似文献   

9.
储层矿物的生长和溶解受控于成岩流体,在恒定温度条件下,对不同盐度和离子类型溶液体系中的方解石溶解特性进行实验研究。结果表明,在低盐度(20%)条件下,方解石溶解度随盐度增加而增大,但盐度过高会导致方解石溶解度降低,方解石溶解度最大值的盐度区间对应了高孔隙发育带;在相同浓度条件下,MgCl_2体系中方解石的溶解度最大,NaCl体系中次之,KCl中最小,说明Mg~(2+)的盐效应大于Na~+和K~+的盐效应,能促进方解石的溶解;Ca~(2+)会因为共同离子效应而抑制方解石的溶解,反而有助于方解石沉淀(生长),其结果有助于地层保持良好的封闭性;Na_2SO_4的盐效应不明显,随浓度增大,方解石的溶解度快速降低;硫酸根对方解石溶解的抑制作用强于氯离子,表明Na_2SO_4水型可能不利于储层溶蚀次生孔隙的发育。  相似文献   

10.
引言体系 LiI—Li_2SO_4—H_2O 的溶解度迄今尚未有人作过,为了找出 LiI 与 Li_2SO_4在水中溶解度的相互影响与化学行为,作者选作了该体系在0℃时溶解度的研究。体系 LiCl—I_4i_2SO_4—H_2O 在30°和25°的溶解度图均被研究过,结果证明 I_4i_2SO_4在水中的溶解度随溶液中 LiCl 含量的增加而迅速的减低。体系的溶解度曲线由两支构成,分别相应于 Li_2SO_4·H_2O 与 LiCl·H_2O,但与 LiCl·H_2O 对应的一支极短,只留下与 Li_2SO_4·H_2O对应的一支。在25℃时共晶点含 Li_2SO_40.02%;含 LiCl45.52%。体系 NaI—Na_2SO_4  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

13.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

14.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

15.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

16.
AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…  相似文献   

17.
There are numerous geometric objects stored in the spatial databases. An importance function in a spatial database is that users can browse the geometric objects as a map efficiently. Thus the spatial database should display the geometric objects users concern about swiftly onto the display window. This process includes two operations:retrieve data from database and then draw them onto screen. Accordingly, to improve the efficiency, we should try to reduce time of both retrieving object and displaying them. The former can be achieved with the aid of spatial index such as R-tree, the latter require to simplify the objects. Simplification means that objects are shown with sufficient but not with unnecessary detail which depend on the scale of browse. So the major problem is how to retrieve data at different detail level efficiently. This paper introduces the implementation of a multi-scale index in the spatial database SISP (Spatial Information Shared Platform) which is generalized from R-tree. The difference between the generalization and the R-tree lies on two facets: One is that every node and geometric object in the generalization is assigned with a importance value which denote the importance of them, and every vertex in the objects are assigned with a importance value,too. The importance value can be use to decide which data should be retrieve from disk in a query. The other difference is that geometric objects in the generalization are divided into one or more sub-blocks, and vertexes are total ordered by their importance value. With the help of the generalized R-tree, one can easily retrieve data at different detail levels.Some experiments are performed on real-life data to evaluate the performance of solutions that separately use normal spatial index and multi-scale spatial index. The results show that the solution using multi-scale index in SISP is satisfying.  相似文献   

18.
In the 19th century the society was controlled by men, and women were just appendants of them, they had not any rights and freedom. But Jane was an exception, she showed some characteristics of early feminist. Jane showed her characteristics of feminism in three aspects: rebellion, equality, and independence. These characteristics were helpful to her success, and feminism is the only way out for women of that time.  相似文献   

19.
正The periodicity of the elements and the non-reactivity of the inner-shell electrons are two related principles of chemistry,rooted in the atomic shell structure.Within compounds,Group I elements,for example,invariably assume the+1 oxidation state,and their chemical properties differ completely from those of the p-block elements.These general rules govern our understanding of chemical structures and reactions.Using first principles calcula-  相似文献   

20.
We have developed an adiabatic connection to formulate the ground-state exchange-correlation energy in terms of pairing matrix linear fluctuations.This formulation of the exchange-correlation energy opens a new channel for density functional approximations based on the many-body perturbation theory.We illustrate the potential of such approaches with an approximation based on the particle-particle Random Phase Approximation(pp-RPA).This re-  相似文献   

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