大平掌铜多金属矿斜长花岗斑岩中锆石标型研究

运用J.P.Pupin(1980)的锆石标型研究方法,通过对锆石晶形的鉴定和统计来探讨大平掌铜多金属矿花岗闪长斑岩成因信息.结果表明,锆石在亚碱性中温环境种形成,伴随矿化可能性较大.     

扬子克拉通35亿年碎屑锆石的发现及其地质意义

对来自宜昌三峡地区震旦纪莲沱组和南沱组标准剖面的砂岩与冰积岩中大量碎屑锆石的LA-ICP-MS U-Pb定年结果发现，其中含有年龄为3319—3508Ma的锆石，这些锆石年龄均十分谐和（谐和度99%—100％），且具有典型的岩浆型振荡环带阴极发光图像和典型岩浆成因的Th/U比值（0.46—0.76），表明这些锆石为中-古太古代岩浆作用的产物.这些锆石是在扬子克拉通迄今发现的最古老的锆石.对崆岭群变碎屑岩锆石的进一步定年研究，未发现>3.3Ga的锆石年龄，表明扬子克拉通可能存在比崆岭高级变质地体更古老的陆壳.     

河北平山深熔伟晶岩锆石成因及SHRIMP U-Pb年龄

深熔伟晶岩中的锆石具有典型的岩浆锆石的形态和结构,但却具有较低的Th/U比值,是非常特殊的,研究表明其为深熔作用所形成.进而说明并不是所有的具有自形柱状和密集振荡环带/韵律的锆石都是严格意义上的岩浆锆石.两样品锆石的SHRIMP U-Pb年龄表明伟晶岩的结晶年龄在1.87～1.89 Ga之间,大致代表了母岩深熔的时间,其核部残留的锆石年龄在2.5 Ga左右.伟晶岩形成于张性环境的浅部层次,表明陆-陆碰撞的时代可能早于1.9 Ga.     

锆石U-Pb定年与微量元素分析的地质应用

 锆石U-Pb定年与微量元素同时测定的原位微区分析是目前应用最广泛的地质测年方法之一,对锆石形貌学、内部结构及地球化学特征进行深入研究,是正确理解、解释锆石原位微区分析测年结果的关键。通过锆石的阴极发光图像（CL）、背散射电子图像（BSE）,结合锆石的Th/U比值及稀土配分模式曲线特征,可判别不同锆石的成因类型;通过锆石的微量元素分析,可判别锆石寄主岩石的成因类型及形成环境;利用Ti温度计可限定岩体的岩浆源区深度范围,结合锆石寄主岩石类型及寄主岩石中深源包裹体的研究,可进一步推断锆石母岩浆的起源。锆石U-Pb定年与微量元素分析相结合的地质测年方法,已成功地应用于最大沉积地层时代限定、碎屑岩物源分析以及古洋盆演化过程约束等方面,且具有强有力的发展前景。     

变质重结晶锆石微量元地球化学与U-Pb年代学:以辽宁红透山铜锌矿床赋矿片麻岩为例

利用CL和LA-ICP-MS技术,对红透山铜锌矿床赋矿黑云母斜长片麻岩中的锆石开展了内部结构特征分析、原位微量元素组成分析和锆石微区定年.CL图像特征显示锆石具有核幔边结构,分析认为核部为岩浆锆石,幔部为变质重结晶锆石;原位微量元素组成分析的结果显示核部和幔部锆石稀土元素组成存在异同点,相同之处表现在两者的稀土配分模式相似,表明微量元素组成方面变质重结晶锆石对岩浆锆石的继承性;差别之处体现在稀土总量和轻稀土上,幔部变质重结晶锆石的稀土总量和轻稀土量都明显低于核部岩浆锆石,显示变质重结晶过程中锆石中稀土元素的地球化学行为.在此基础之上,对锆石U-Pb年龄进行合理解释,认为核部岩浆锆石年龄2 552Ma代表研究区海底火山岩的喷发时限,变质重结晶锆石较小年龄2 520 Ma代表区域变质事件的时限.既而限定红透山铜锌矿的成矿时代在2 552 Ma,变质变形时代2 520 Ma.     

黑龙江金厂金矿花岗斑岩锆石地球化学、U-Pb年代学及地质意义

为确定与金厂金矿成矿有关的岩浆类型、活动时限和构造背景,采用LA-ICP-MS技术对研究区花岗斑岩开展了锆石U-Pb年龄及原位微区微量元素测定。结果表明:锆石环带发育,wTh/wU值>0.4,具有岩浆锆石特征;锆石年龄分布于220Ma和103～123Ma 2个区间,代表了2期岩浆事件;对2种锆石分别命名为捕获岩浆锆石和新生岩浆锆石;锆石的地球化学和年龄信息显示捕获岩浆锆石的原岩为早三叠世花岗岩;锆石微量元素信息暗示花岗斑岩是早三叠世花岗岩高度熔融结晶分异、侵位于浅部氧化环境而形成,这一过程导致新生岩浆锆石负Eu异常程度降低。新生锆石加权平均年龄为(113.5±3.8)Ma,与成矿年龄一致,据此认为早白垩世的岩浆事件是金厂金矿成矿事件的直接原因,成矿背景为太平洋板块俯冲后的岩石圈伸展。     

福建明溪锆石巨晶中的斜锆石、锆石矿物包裹体及其成因启示

福建明溪是我国和火山岩有关的锆石巨晶的典型产地.通过对该地的锆石巨晶晶体形态及其包裹体的研究发现,福建明溪锆石巨晶四方柱明显较双锥发育,表面有熔蚀结构,内部结构均匀;锆石巨晶中发现的斜锆石包裹体和其它产地斜锆石相比具有贫大离子半径元素U,Th,Y,Zr/Hf高的特点.巨晶中的锆石包裹体的拉曼光谱有两种不同类型,其中一类锆石包裹体的拉曼谱和变质及热处理锆石相似,说明锆石巨晶形成时曾经历过变质作用过程.锆石巨晶及其包裹体特征暗示锆石巨晶不是玄武岩结晶产物,和伴生的刚玉巨晶相比其来源可能更深,是壳一幔物质相互作用产物.     

桂东北豆乍山岩体和香草坪岩体锆石微量元素特征及其地质意义

华南花岗岩型铀矿床的形成与产铀花岗岩关系密切。对产铀的豆乍山岩体和无矿的香草坪岩体开展锆石LA-ICP-MS U-Pb测年及微量元素分析,通过锆石的微量元素特征来识别产铀花岗岩。结果表明,豆乍山岩体和香草坪岩体分别形成于(226±5) Ma和(223±5) Ma。相较于香草坪岩体,豆乍山岩体的锆石具有较低的Ti饱和温度和较高的U、Th含量以及较低的锆石与全岩的U、REE、Y等微量元素含量比值等。花岗岩中锆石微量元素含量变化受到岩体中矿物组合的影响,因此锆石与全岩的U、REE、Y等微量元素含量比值可以作为区分产铀花岗岩和无矿花岗岩的标志。本研究成果有助于快速高效地圈定铀成矿远景区。     

川西高原几个花岗岩体的岩浆起源浅探——利用锆石标型特征方法

文章通过对锆石晶形的仔细鉴定来探讨花岗岩的起源。对川西高原8个花岗岩体中锆石标型特征的研究,得出的初步结论是:这些花岗岩的起源可能属于壳源成因,或壳源十幔源成因。     

甘肃白银厂矿田的锆石标型特征及其岩石学意义

运用Ｊ．Ｐ．Ｐｕｐｉｎ的锆石成因矿物学研究方法,详细研究了甘肃白银厂矿田各类岩石的锆石产出状态、晶体的标型特征及主要岩石学参数。该区锆石标型的演化程度高,平均碱度指数为６３０以上,锆石形成于富碱的介质环境中。各类岩石形成温度虽有差异,但都在６８０～８１７℃范围内。锆石标型的信息表明,岩浆来源于壳幔边界处,且以幔源为主。     

An in vitro evaluation of novel NHA/zircon plasma coating on 316L stainless steel dental implant

The surface characteristics of an implant that influence the speed and strength of osseointegration include crystal structure and bioactivity. The aim of this study was to evaluate the bioactivity of a novel natural hydroxyapatite/zircon(NHA/zircon) nanobiocomposite coating on 316L stainless steel(SS) dental implants soaking in simulated body fluid. A novel NHA/zircon nanobiocomposite was fabricated with 0(control),5, 10, and 15 wt% of zircon in NHA using ball mill for 1 h. The composite mixture was coated on SS implants using a plasma spray method.Scanning electron microscopy(SEM) was used to evaluate surface morphology, and X-ray diffraction(XRD) was used to analyze phase composition and crystallinity(Xc). Further, calcium ion release was measured to evaluate the coated nanobiocomposite samples. The prepared NHA/zircon coating had a nanoscale morphological structure with a mean crystallite size of 30–40 nm in diameter and a bone-like composition,which is similar to that of the biological apatite of a bone. For the prepared NHA powder, high bioactivity was observed owing to the formation of apatite crystals on its surface. Both minimum crystallinity(Xc=41.1%) and maximum bioactivity occurred in the sample containing 10 wt% of zircon because of minimum Xcand maximum biodegradation of the coating sample.     

Geological and chronological evidence of Indo-Chinese strike-slip movement in the Altyn Tagh fault zone

A set of granitic and amphibole mylonite are exposed in the Altyn Tagh fault zone. The preliminary study shows that these rocks are the product of the syntectonic anatexis in the process of the left-lat- eral strike-slip shear, and are the result of the ductile transpression. There are two types of zircon sorted from the mylonite formed with synshear anatexis. Among them, one is the anatectic long columnar zircon and another is the residual metamorphic sub-rounded columnar zircon. Two groups of age for single zircon measured by ion microprobe (SHRIMP) are obtained: one is 461-547 Ma for the sub-rounded columnar residual metamorphic zircon, and the other is 239-244 Ma for the long-columnar anatectic zircon. This type of zircon is directionally spread in rock, and the long axis direction of its crystal is identical to that of stretching lineation, representing the direction of tectonic stress in the process of the strike-slip. 40Ar-39Ar age of the directional growth hornblende in the same mylonite sample measured is 223-226 Ma. The above geological and chronological data prove that the syntectonic anatexis occurred during Indo-Chinese Epoch, showing that the strong strike-slip movement occurred in the Altyn Tagh fault zone at least as early as Indo-Chinese Epoch.     

Z型涂料成分和溃散性

采用X衍射、电子探针、矿相分析等手段;对离心浇注合金钢管所用的进口Z型涂料的配方、烧结后的涂料结构和性能,尤其对溃散性能进行了研究。结果表明:该涂料是由锆英石(ZrSiO_4)、膨润土及少量氧化铁和高分子有机物所组成。涂料高温烧结后,有机物已分解挥发,锆英石、膨润土仍为晶态。膨润土颗粒细化,在其表面出现一薄层液化膜使烧结涂料强度下降,溃散性能优良。据此,选用我国自产的石英粉、膨润土、硅溶胶、CMC及其它必要的成分制成涂料,用于生产性试验中,获得了满意的结果。     

Zircon U/Pb ages for gniess from Qianshan, Anhui

Zircon U/Pb ages were measured for Qianshan gneiss at the ultrahigh pressure metamorphic (UHPM) complex in the Southern Dabie Terrain (SDT). According to morphology, Th and U contents of eight fractions of zircon and data distribution on the discordia, it is indicated that they should be treated as metamorphic overgrowth mixing zircons, in which the cores mainly are magmatic and the outers were metamorphic. The intercept ages show that the gneiss underwent UHPM. There is no direct correlation for zircon between morphological feature and genesis.     

Zircon SHRIMP dating of sodium alkaline rocks from Maomaogou area of Huili County in Panxi, SW China and its geological implications

Alkalinerocksareoftenassociatedwithextensionaltectonicsandregardedasthecharacteristicproductsoc-curringincontinentalmarginsorriftzones[1].Theywereusuallygeneratedindeep-large-faultzoneandcloselyconnectedwithbasic/ultrabasicrocksinspace.Therefore,alkalinerocksareofsignificanceintectonicpetrology.Atthebeginningofthe1980s,geologicalandgeophysicalstudieswereperformedinPanzhihua-Xichangpaleo-riftzone(Panxiriftzone).However,thesestudiesonlyin-volvedgeologyandpetrochemistryoftheMaomaogouringalkalic…     

Hf isotope composition of zircons and implication for the petrogenesis of Yajiangqiao granite,Hunan Province,China

In the peralumineous granite of Yajiangqiao zircon population can be divided into two groups (i.e. Zircon Ⅰ and Zircon Ⅱ), which were formed in magmatic chamber and in emplacement place, respectively. The Hf isotope compositions of two stages of zircon show that the host magma was essentially derived from crustal material by melting. However, some higher 176Hf/177Hf ratios indicate that the granitic zircons should contain fine crystal of zircon formed in mantle-derived magma. In fact, the backscattered electron imaging and the electron microprobe analysis reveal that there is another type of zircon included within Zircon Ⅰ, which is quite different from Zircon Ⅰ and Zircon Ⅱ in morphology and chemistry. They are considered to be the product of the mantle-derived magma intruded into the granitic magma chamber at the beginning of anatexis. Thus,it is suggested that the formation of Yajiangqiao granite is related to the underplating of mantle magma.     

与碱性玄武岩有关刚玉巨晶的多阶段成因—包裹体的证据

分析山东昌与碱性玄武岩有关的刚玉巨晶不同部位的常量元素、稀土元素及包裹体组成。刚玉巨晶的主体以大量流体－熔体包裹体、锆石、铌（钽）铁矿包裹体为主,而巨晶中的“晶核”部位则以大量的熔体包裹体为主,反映研究区的刚玉巨晶是在不同的阶段形成的,刚玉“晶核”以及“铜皮刚玉”形成于熔体相为主的体系中,而主体刚玉则形成于熔体－流体过渡的急剧变化的不均一的地球化学环境中。