含砷难浸金矿次氯酸钠一步法浸金理论与技术

简单地评述了含砷难浸金矿处理技术的方法和特点,对次氯酸钠浸金的一步法问题进行了初步的讨论,并对次氯酸钠浸金的基础理论作了综述。     

枞阳井边金矿金的赋存状态研究

井边金矿位于下扬子台坳、长江褶皱断裂隆起带中段。金矿体赋存于三叠系中统铜头尖组中 ,矿体形态呈不规则脉状。矿石类型主要有以含金褐铁矿为主的氧化矿石和以含金黄铁矿为主的原生矿石两大类。通过矿相鉴定 ,单矿物含金分析、物相分析、多点分析及电子探针分析等 ,查明了载金矿物系列特征的金的赋存状态。金矿物以自然金为主 ,其次为银金矿。金的粒度较细 ,主要为中细粒显微金。金的嵌布类型有包体金、晶隙金及裂隙金 ,金的成色较高 ,平均为 91 0 .4。金主要呈矿物态存在。     

河东金矿床矿体赋存规律研究

河东金矿位于焦家矿田内 ,属蚀变岩型金矿 ,矿床受望儿山断裂控制 ,矿体沿断裂带平行产出 ,上下盘围岩分别为玲珑型花岗岩和郭家岭似斑状花岗闪长岩。蚀变带由上至下出现绢英岩化花岗质碎裂岩、绢英岩、绢英岩化花岗闪长岩 ,金矿体赋存在强蚀变岩中。一般认为河东金矿的各矿体产于断裂带下盘部位 ,但本文研究认为 ,河东金矿的矿体确切地说应该位于两条主断裂之间的部位 ,尤其是组成菱形结环的分叉或汇合部位 ,河东金矿的1～ 10号矿体全部落于两断裂之间     

微细粒型金矿床金的赋存状态研究——以皖西南枞阳井边金矿为例

通过矿相鉴定、单矿物含金分析、物相分析对皖西南枞阳井边金矿金的赋存状态进行了系统研究 ,并用微束分析技术———质子探针分析方法对超显微形式存在金的赋存状态进行研究 .结果表明 :矿石矿物黄铁矿、黄铜矿中金的赋存状态以微细粒自然金为主 ,其次为银金矿 .金有 2种形式存在 ,一种是显微可见金 ,另一种是超显微形式存在的金 ,其中 ,显微可见金又进一步分为包裹金和裂隙金 ;超显微形式的金也是一种游离金 ,而不是晶格金 ,这与我国卡林型金矿床中金的赋存状态一致     

New insights into the extraction of invisible gold in a low-grade high-sulfur Carlin-type gold concentrate by bio-pretreatment

To extract gold from a low-grade (13.43 g/t) and high-sulfur (39.94wt% sulfide sulfur) Carlin-type gold concentrate from the Nibao deposit, Guizhou, a bio-pretreatment followed by carbon-in-pulp (CIP) cyanide leaching process was used. Various methods were used to detect the low-grade gold in the concentrate; however, only time-of-flight secondary-ion mass spectrometry (TOF-SIMS) was successful. With bio-pretreatment, the gold recovery rate increased by approximately 70.16% compared with that obtained by direct cyanide leaching of the concentrate. Various attempts were made to increase the final gold recovery rate. However, approximately 20wt% of the gold was non-extractable. To determine the nature of this non-extractable gold, mineralogy liberation analysis (MLA), formation of secondary product during the bio-pretreatment, and the preg-robbing capacity of the carbonaceous matter in the ore were investigated. The results indicated that at least four factors affected the gold recovery rate:gold occurrence, tight junctions of gold-bearing pyrite with gangue minerals, jarosite coating of the ore, and the carbonaceous matter content.     

秦岭二台子金矿床地质地球化学再研究

为了指导找矿，通过近年来找矿预测获得的新突破和积累的较新测试资料，对二台子金矿床作出进一步的认识和总结，在探讨矿床成矿大地构造背景的基础上，提出矿床所在盆地的容矿岩系发育模式，在矿床成矿作用演化研究中，进一步阐述了矿床形成经历的同生与后生两次成矿作用，分别与秦岭造山带南北陆块俯冲碰撞造山导致被动大陆一侧局部出现伸展断陷式盆地和转入陆内逆冲推覆造山的构造－岩浆活动密切耦合。     

深源CO2及其对金的富集成矿作用

目的深源CO2与金成矿作用关系的研究是当前地学界倍受关注的前沿课题,介绍了深源CO2的特点。方法以国内外一些典型金矿研究资料为基础,结合我们近年从事矿床地球化学研究的成果,为深源CO2与金矿化间的联系提供了直接的地质证据。结果地球深部CO2储量巨大,且处于超临界状态,对金矿化有重要作用。结论深源CO2对金矿化的作用主要表现为运输成矿物质和提供巨大的能量两个方面。     

难处理金矿的加工方法

为确定难处理金矿的加工方法,在对矿样的的化学成分、粒度分布、赋存状态分析的基础上,进行了相关的浮选条件实验,确定了矿样的最佳浮选工艺流程和参数,并进行了浮选开路实验。结果表明：浮选精矿中的金的回收率为50.97%,金品位为8.75 g/t,精矿中金的回收率和品位都较低,说明该矿样不宜用浮选方法获取精矿,可以考虑用其他方法提金。     

淋湘金矿地球化学特征

陕西旬阳淋湘金矿床产于南秦岭古生界泥盆系地层中,容矿围岩主要为碳酸盐岩和细碎屑岩,金矿体主要受近东西向断裂控制．第Ⅱ、第Ⅲ矿化阶段为金的主要矿化阶段,第Ⅱ～Ⅲ阶段石英包体中N2含量大于21μg/g,而第Ⅳ阶段矿物中的N2含量均小于1μg/g,说明成矿流体中的N2含量减少对金矿化不利;成矿流体的氢氧同位素组成与变质水相当;矿石的硫同位素早期为18.21‰,中晚期为17.83‰～14.01‰;铅具有正常铅同位素特征;不同矿化程度的矿石的稀土元素组成的球粒陨石标准化分配曲线,呈富轻稀土的右倾型,曲线形态基本一致,随着矿化增强其稀土元素含量明显增高．这些矿床地球化学特征表明,成矿金属元素和硫主要来源于造山带围岩地层,属容矿岩石为沉积岩中的浅层渗滤同生热盐水型金矿床,成矿时代为燕山期．     

Progress in gold solvent extraction

Gold solvent extraction has been used to recover gold by analytical chemists for about one century. Due to the potential advantages of solvent extraction technology over present zinc-dust cementation and carbon-adsorption procedures in gold recovery, metallurgists have paid much attention to the study of gold solvent extraction in recent years . Some promising extraction systems were proposed and studied. Recently some new progress in gold solvent extraction have been achieved in our research group. In the mechanism study on quaternary amine extraction system, a supramolecular structure model based on hydrogen bonding between modifier and Au(CN)2~ was proposed. For the stripping of quaternary amine extraction system, a procedure based on NaCI04 solution and saturated KCl solution was reported.     

Two-dimensional self-organization of 1-nonanethiol-capped gold nanoparticles

A two-dimensional (2D) ordered hexagonal close-packed structure, formed by 1-nonanethiol-capped gold nanoparticles, is reported. The structure was constructed only by dipping the gold nanoparticle colloidal solution on flat substrate. The gold nanoparticles were synthesized as follows: First, AuCl₄^-1 was transferred from aqueous solution to toluene by the phase-transfer reagent of tetraoctylammonium bromide. Then it was reduced with aqueous sodium borohydride in the presence of a given amount of 1-nonanethiol molecules which was used to control the nucleation and growth of the gold nanoparticles for the desired size. The experimental techniques, such as UV-Vis, FT-IR, and X-ray photoelectron spectroscopy (XPS), were employed to characterize the obtained product. Transmission electron microscopy (TEM) measurement demonstrated the size of the gold nanoparticle and the formation of two-dimensional ordered hexagonal close-packed gold nanoparticle structure.     

黄金矿山尾矿的再资源化

随着黄金开发规模的扩大和开采历史的延长，黄金矿山尾矿逐年增加。堆存的尾矿不仅占用大量土地，浪费大量资金，还严重污染环境。本文综述了黄金矿山尾矿的再资源化利用方法：一是回收，即从金矿尾矿中提取金，银以及铅、锌、铜、硫等伴生成分进行尾矿再选；二是利用，以尾矿为基本原料开发新产品；以此来实现金矿尾矿再资源化。     

丁二酮肟-氧化剂型无毒浸金剂的浸出性能研究

用分子设计理论提出了一类新型浸金剂 ,它由丁二酮肟和某种氧化剂构成 ,具有无毒害和化学稳定性好的特点 ,实验结果表明 :1)丁二酮肟能与许多氧化剂尤其是高锰酸钾组合成高效浸金剂 ;2 )在丁二酮肟 -高锰酸钾浸出体系中 ,适宜的Ox/Lig(氧化剂与金络剂分子比 )比值范围为 0 .2 5～ 0 .50 ,最佳范围为 0 .30～0 .4 0 ;3)丁二酮肟 -高锰酸钾浸出体系的操作pH范围为 8～ 10 ;4 )与氰化物相比 ,丁二酮肟的浸出率与它相当但浸出速度明显快很多 ;5)从含丁二酮肟的浸出贵液中回收金既可采用炭吸附法也可采用锌置换法 图1,表 5,参 9     

安徽省全椒县范水洼金矿床地质特征研究

文章对安徽省全椒县范水洼金矿床的地质特征进行了研究,确定了矿床的赋矿围岩为上寒武统琅琊山组的泥质条带灰岩,矿区内主要构造有断裂和皱褶,主要蚀变矿化类型有硅化、黄铁矿化、碳酸盐化、萤石化以及金矿化。对矿床的控矿条件进行分析,认为地层层位和岩性、地质构造条件以及围岩蚀变是矿床主要的控矿因素,初步研究认为该矿床可能为卡林型金矿。     

N235协同萃取碱性氰化浸金溶液中的金(Ⅰ)

由N235与路易斯碱三辛基氧膦(TOPO)组成协同萃取体系,对碱性氰化浸金贵液中金(Ⅰ)协同萃取和反萃进行了研究.研究了有机相中N235含量、水相平衡pH、相比等因素对金(Ⅰ)萃取率的影响,考察了反萃液中氢氧化钠液浓度对负载金有机相的反萃效果.结果表明,采用有机相为10% 10%协萃剂TOPO 80%煤油的协萃体系,对pH=9～10和初始金(Ⅰ)质量浓度ρo=10.87 mg/L碱性氰化浸金贵液进行萃取时,经一级萃取后,萃取率可高达98%左右;同时,采用0.05～0.1 mol/L的氢氧化钠溶液可对负载有机相进行反萃,反萃率达到91%以上.