山东省微山稀土矿正长岩类锆石U-Pb年代学 及地球化学特征研究

为了加深对微山稀土矿碱性杂岩体岩浆活动期次及与成矿关系的理解,对微山稀土矿床碱性杂岩体进行岩相学、地球化学分析和锆石U-Pb年代学测定。结果表明,微山稀土矿碱性杂岩体正长岩类地球化学特征相似,具有同源性,为偏铝质碱性岩。稀土总量高,轻重稀土元素分馏明显,呈轻稀土高度富集模式。微量元素组成具有幔源岩浆岩的特征,富集Rb,Ba,Sr等大离子亲石元素,亏损Nb,Ta,Zr等高场强元素,Eu异常不显著。利用LA-ICP-MS U-Pb年代学方法,测得含矿石英正长岩、霓辉石英正长岩锆石U-Pb年龄分别为122.4±2.0 Ma(MSWD=5.2)和130.1±1.4 Ma(MSWD=9),存在2536±6.1 Ma(MSWD=1.6)的继承锆石,表明地壳物质参与成岩过程。结合鲁西燕山期构造演化过程,认为微山正长岩类形成于华北克拉通中生代构造体制转折后的伸展背景下,成矿作用与碱性杂岩体的演化有关。     

Petrogenesis and significance of the Hongshan syenitic pluton,South Taihang: zircon SHRIMP U-Pb age, chemical compositions and Sr-Nd isotopes

The Hongshan syenitic pluton (South Taihang) is mainly made up of hornblende syenite and minor granite. SHRIMP zircon dating yields a U-Pb age of 135±2.7 Ma for the emplacement of the pluton, while biotite Rb-Sr isotopic data give an isochron of 120. 3±2.4 Ma. Hongshan syenites show low silica, high alkalis and LILE such as Sr, and exhibit negligible Eu anomalies or slightly positive anomalies in the REE patterns. The syenites show quite enriched isotopic compositions with Isr from 0.7052 to 0. 7102 and εNd(t) from -7.5 to - 11.1. Petrogenesis of the pluton can be that partial melting of an enriched lithospheric mantle gave birth to an alkali basaltic magma, which subsequently underplated in the lower crust and experienced a coupled fractionation of ferromagnesian phases like pyroxene and hornblende and minor (<10 %) contamination of lower continental crust, producing the Hongshan syenites that partially e-volved into granite through combined fractionation of hornblende and feldspar. Our data are not in agreement with a previous model that the syenites originated from melting of lower crust in a thickened crust circumstance, and thus do not support the speculation of "East China Plateau" in the Mesozoic.     

雾灵山A型花岗岩系的矿物学特征及成因意义

雾灵山杂岩体由似斑状碱长正长岩及其中的岩石包体、碱性石英正长斑岩、碱性石英正长岩等岩石组成，是冀北地区白垩纪岩浆活动的代表。本文以岩相学工作为基础，讨论了这些岩石中主要造岩矿物的结晶顺序和共生关系，报道了它们的成分特点和演化趋势，推测了不同矿物结晶时的温度、压力、氧逸度、含水量等生成状态和条件，并探讨了由它们所反映出的岩浆演化历史、特点和岩石成因系列归属问题。     

新疆北山坡北基性超基性杂岩特征及成矿远景

新疆北山坡北基性-超基性杂岩体逆向同源成分演化特征明显、结构演化不清楚,包括角闪辉长岩、辉长苏长岩、橄榄辉长岩、橄榄辉石岩和辉石橄榄岩、斜长(拉长)岩5个岩相单元。钛铁矿化与角闪辉长岩相有关,铜镍矿化与橄榄辉长岩相和橄榄辉石岩及辉石橄榄岩相有关。综合研究认为,新疆北山构造带西段坡北杂岩具有较好的铜镍矿及钛铁矿成矿和找矿前景。     

The age of the Gaojiacun mafic-ultramafic intrusive complex in the Yanbian area,Sichuan Province： Geochronological constraints by U-Pb dating of single zircon grains and ^40Ar／^39Ar dating of hornblende

The Gaojiacun mafic-ultramafic intrusivecomplex in the Yanbian area, Sichuan Province, is a strati-form intrusive body that has undergone intensive magmaticdifferentiation. This intrusive body involves two magmaticaccumulating cycles. Systematic U-Pb dating of single zircongrains and ~(40)Ar/~(39)Ar dating of hornblende were conducted,and the results showed that the age of hornblende gabbro,which was formed at the main phase of intrusion of the Gao-jiacun intrusive complex, is 840±5 Ma, casting doubt on theconcept of "Yanbian Ophiolite". It is believed that the for-mation of the Gaojiacun intrusive complex seems to be re-lated to a super-mantl3 plume underneath the su-per-continent Rodinia. The above research results are helpfulfor us to get a better understanding of the characteristics ofNeoproterozoic tectonic evolution of the Yanbian area inSichuan Province.     

山西省临县紫金山地区U、Th、K三种放射性元素特征分析

为了研究山西临县紫金山地区放射性矿产铀、钍、钾元素异常分布规律、含量、赋存状态,通过运用地面伽马能谱和显微镜镜下分析二者相结合的方法研究了研究区内的岩石,得到紫金山地区岩石的铀、钍、钾放射性参数和铀、钍、钾异常对应岩石的镜下分析结果。结果表明:山西临县紫金山地区铀、钍元素异常主要分布在黑云辉石岩、霞石正长岩中,它是由于这二种岩石中分布的磷灰石和榍石所以引起的,榍石和磷灰石占黑云辉石岩总量的7%～11%,榍石在霞石正长岩中的含量占总量的1%～5%;钾异常主要分布在黑云母辉石正长岩中,钾元素异常是由黑云母辉石正长岩中的正长石引起的,黑云母辉石正长岩中的正长石占整体的85%～90%。可见通过地面伽马能谱和显微镜镜下分析二者相结合的方法可以解释山西省紫金山地区放射性矿产铀、钍、钾异常分布规律、含量、赋存状态。综上,黑云辉石岩、霞石正长岩、黑云母辉石正长岩为今后放射性矿产突破所在,建议在区部署地面伽玛能谱扫面工作,再对扫面工作的异常区进行槽探及钻探工程验证。     

Determination of U-Pb age and rare earth element concentrations of zircons from Cenozoic intrusions in northeastern China by laser ablation ICP-MS

Using the in situ zircon U-Pb dating method of LA-ICPMS, we analyzed the 31 Ma old SHRIMP U-Pb age of the Yongsheng nepheline syenite from southern Jilin Province under different spot sizes. The obtained ages are comparable with that of SHRIMP in both accuracy and precision. The age is also identical to that of the Yinmawanshan gabbro from the Liaodong Peninsula within error. Both the Yongsheng nepheline syenite and the Yinmawanshan gabbro represent the youngest known exposed intrusions in northeastern and even eastern China. The results indicate the Eocene mantle-derived magmatic underplating, and the rapid crustal uplifting of this region since 30 Ma. The analyses also document extremely high LREE concentrations and relatively fiat REE patterns for the zircons from the Yongsheng nepheline syenite, which represent a new type of zircon REE pattern.     

鲁西金岭岩浆侵入杂岩体中角闪石岩包体成因研究

为了确定鲁西金岭岩浆侵入杂岩体中的角闪石岩包体成因, 对该类包体进行岩相学、矿物化学和地球化学分析。结果表明, 角闪石岩包体具有明显的堆晶结构, 主要由角闪石和少量斜长石组成。其中, 角闪石可以分为两类: 一类为韭闪石, 具有较低的SiO₂含量和较高的Al₂O₃含量, 是原生角闪石; 另一类为阳起石、镁角闪石和浅闪石, 相对富集SiO₂, 贫Al₂O₃, 可能为原生角闪石晚期被改造的产物。利用角闪石全铝地质压力计对原生角闪石进行压力计算, 获得其平均结晶压力为0.48 GPa。这些角闪石岩包体的微量元素特征与寄主岩石黑云母闪长岩相似, 均富集轻稀土元素, 亏损重稀土元素。结合原生角闪石的形成条件, 可以认为这些角闪石岩包体可能与寄主岩石同源, 是中地壳岩浆房闪长质岩浆分离结晶的产物。     

Geochronologic and petrochemical evidence for the genetic link between the Maomaogou nepheline syenites and the Emeishan large igneous province

The Maomaogou nepheline syenite is located at the inner zone of the Emeishan large igneous province and exhibits intrusive contact with the Emeishan basalts. SHRIMP U-Pb dating on zircons from this syenite yields an age of 261.6±4.4 Ma, in agreement with the age of the Panzhihua layered intrusion and the eruption age of the Emeishan basalts as constrained by stratigraphic data. Geochemical data fur-ther suggest that the Maomaogou syenite has a source analogue to the Emeishan basalt, and may have been formed by partial melting of gabbroic cumulates underplated in the lower crust. As s result, tem-poral and spatial relationships and petrogenetic constraints provide evidence for the genetic link be-tween basalts, mafic/ultramafic and intermediate/acidic intrusives in the Panxi area.     

Zircon U-Pb dating of basement gneisses in the super-large Bayan Obo REE-Fe-Nb deposit,Inner Mongolia

Zircon U-Pb ages have been determined for basement gneisses in the Bayan Obo REE-Fe-Nb deposit. On the U-Pb concordia diagram data of three samples yield upper intercept ages of 1948-1917 Ma. Thus, these basement gneisses are of Paleoproterozoic. Rock association of these basement gneisses includes tonalite, syenite and paragneiss, not belonging to a sedimentary package. It is more appropriate to consider this association as a basement complex rather than a stratigraphic "Group".     

新疆黄山镁铁-超镁铁杂岩体矿物化学成分特征及与含矿(Ni)性关系

本文对新疆黄山镁铁—超镁铁杂岩体中主要造岩矿物橄榄石,斜方辉石,单斜辉石及角闪石化学成分特征作了比较深入的研究.在此基础上,分析了岩体含矿(Ni)性与矿物化学成分间的关系,得出了岩体含矿的主要矿物化学标志.     

独山玉岩石学特征分析

独山玉矿区内岩石类型主要为次闪石化辉长岩、角闪岩及橄榄质科马提岩,岩石普遍呈碎裂、糜棱结构,总体属于铁质基性岩类.岩石蚀变普遍,特别是次闪石化遍及整个岩体.岩石是有明显的动力变质作用,显示出独山的个性格局.独山玉脉与次闪石化、钠黝帘石化和构造糜棱岩化关系密切.根据独山隐赋边界,推测整个基性岩区是玉石的成矿远景区.     

略阳县安林沟地区正长岩型铌钽矿特征及远景分析

陕西略阳县安林沟——仙台坝一带,分布着东西长20 km,南北宽2～3 km的加里东期到华力西期十余条正长岩体和正长斑岩,岩石呈细粒结构、斑状结构,块状构造.通过对其地质特征及铌钽等稀有金属含矿性调查和研究,认为正长岩和正长斑岩普遍存在有铌矿化,其中黑云母正长岩（ξ31-1,ξ31-2号）为成矿母岩,已达工业利用品位,全岩矿化明显,即岩体就是铌矿体.并伴有镧铈稀土金属矿化,还可综合回收利用.经初步预测,该区铌远景资源量（Nb2O5）可达超大型（50万t）.若能在选矿工艺上有所突破,经济价值十分可观.     

河南桐柏龟山组地质地球化学特征及成岩环境

河南桐柏龟山组由一套绿片岩相至角闪岩相的变质岩系组成,主要岩性为二云石英片岩、斜长角闪片岩、白云质大理岩及硅质岩。根据龟山组稀土元素和微量元素的研究,认为其原岩为基性火山岩、火山碎屑岩及砂泥质沉积岩;该组岩石形成于过渡壳性质的弧后盆地环境,为一套有利于成矿的火山沉积建造。     

甘肃北山桥湾北花岗岩体的年代学、地球化学及其地质意义

为加深对北山晚古生代构造演化的认识, 选取位于甘肃北山南带、敦煌地块北缘的桥湾北花岗岩体进行年代学、地球化学研究。桥湾北角闪石花岗岩体锆石LA-ICP MS年龄为303.7±2.4 Ma, ε_Hf(t)为-1.2~5.8, ε_Nd(t)相对较高(-0.40~-0.06), (⁸⁷Sr/⁸⁶Sr)_i =(0.704524~0.705062)。 桥湾北花岗岩体K₂O含量为4.09%~5.58%, 属高钾钙碱性岩石, A/CNK值在0.92~1.04之间, 为I型花岗岩; 微量元素较富集LILE, 相对亏损HFSE, 有明显的Nb, Ta负异常。岩体具相对富集的微弱分馏的轻稀土元素, 重稀土元素分馏不明显, 基本没有Eu异常。由Hf, Nd同位素及地球化学特征判断, 桥湾北花岗岩体为壳幔混合成因, 其形式可以是底侵的幔源岩浆再分异, 上升过程中遭受地壳物质混染。根据区域构造背景及岩石学、地球化学特征, 可以认为桥湾北岩体是北山南带后碰撞过程岩浆活动的产物, 反映出在晚石炭世北山地区的碰撞拼贴已经完成。     

辽东矿洞沟地区四张磙子古元古代花岗岩识别及意义

为深入研究辽宁盖州四张磙子花岗岩的形成时代、地质特征及意义,通过锆石LA-ICP-MS U-Pb定年系统和X射线荧光光谱仪,对四张磙子花岗岩进行年龄测试和主微量元素分析.锆石定年结果表明,四张磙子花岗岩侵位年龄为(1 871.2±9.3)Ma,属于古元古代产物.主微量元素结果表明,四张磙子花岗岩与矿洞沟正长岩及闪长岩的Si O2与K2O及Na2O基本呈现正相关,与Ti O2,Al2O3,TFe2O3,Ca O,Mg O,M n O呈负相关,表明3种岩体可能具有亲缘关系.结合前人研究,认为四张磙子花岗岩与矿洞沟正长岩、闪长岩可能具有同一岩浆来源,四张磙子花岗岩为古元古代侵位的花岗岩体.     

钱塘江河口区重矿物特征及其与动力环境的关系

本文研究钱塘江河口区的重矿物组成、组合类型、重矿物的分区及其与水动力的关系,同时探讨其物质的来源。钱塘江河口区已鉴定的重矿物有25种,分为四种组合类型,同时存在与其相适应的四个重矿物区,近口段重矿物区、河口段重矿物区,杭州湾重矿物区与金山深槽重矿物区。钱塘江河口区在不同的区段其沉积物来源不一样。近口段主要来自钱塘江流域,口外海滨主要来自长江口,河口段则两者兼有,而金山深槽主要来自槽下被冲刷出来的全新世的沉积物。     

钱塘江河口区重矿物特征及其与动力环境的关系

本文研究钱塘江河口区的重矿物组成、组合类型、重矿物的分区及其与水动力的关系,同时探讨其物质的来源。钱塘江河口区已鉴定的重矿物有25种,分为四种组合类型,同时存在与其相适应的四个重矿物区,近口段重矿物区、河口段重矿物区,杭州湾重矿物区与金山深槽重矿物区。钱塘江河口区在不同的区段其沉积物来源不一样。近口段主要来自钱塘江流域,口外海滨主要来自长江口,河口段则两者兼有,而金山深槽主要来自槽下被冲刷出来的全新世的沉积物。     

西藏八宿侏罗纪花岗岩的岩石学特征及找矿意义

探讨西藏八宿地区侏罗纪花岗岩的岩石学特征,为找矿提供理论依据.通过对花岗岩类岩体的地质、地球化学、成分演化程度、分异程度和氧化状态的分析,结果表明区内侏罗纪花岗岩大量分布,反映了一次大规模岩浆事件.花岗岩由北西—南东向的断裂控制.岩石组合为黑云角闪石英二长闪长岩-黑云母花岗闪长岩-花岗闪长斑岩-黑云母二长花岗岩,为过铝...     

钼精矿焙烧处理过程中典型杂质元素的热力学行为及分析

通过模拟实验结合X射线荧光光谱仪(X-ray fluorescence spectrometer,XRF)、电感耦合等离子光谱发生仪(inductively coupled plasma spectrometer,ICP)及矿物解离分析仪(mineral liberation analyser,MLA)等研究了钼精矿焙烧处理流程中多种杂质元素间的相互作用,在MLA对物相定量分析的基础上,采用Factsage7.0软件分析了钼精矿焙烧过程中不同杂质元素反应进行的热力学条件。结果表明：杂质元素在钼精矿及后续处理流程中的分布存在明显的粒度偏析,主要表现为K、Si等杂质更多以大分子量的矿物形式赋存在较粗粒度的钼精矿中,而Fe、Ca、Cu等杂质则更多以FeS₂、CaSO₄、CuFeS₂等小分子量的化合物形式赋存在较细粒度的钼精矿中。FeS₂、CaSO₄和SiO₂等杂质会在高温焙烧过程中与MoO₃形成致密度较高的混合物,降低Mo的浸出率。云母在钼...