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1.
1. IntroductionWith its more than 5000 years’long history, brilliant culture and wonderfully-preserved beautiful landscape, China attracts more  相似文献   

2.
Thermodynamics of the Single-Step Synthesis of Dimethyl Ether from Syngas   总被引:3,自引:0,他引:3  
A detailed thermodynamic analysis of single-step synthesis of dimethyl ether (DME) from syngas has been performed. From experiments and theoretical calculations, a suitable thermodynamic model based on Reid‘s thermodynamic data and the Soave-Redlich-Kwong equation of state was determined. Using thism model, a careful analysis of direct synthesis of dimethyl ether from syngas was carried out. Reaction synergy in the synthesis can greatly improve CO conversion and DME yield. Lower temperatures and higher pressures favor higher CO conversion and DME yield. Compared to methanol synthesis, however, the temperature has a smaller effect on the reaction. The direct synthesis of dimethyl ether can exploit CO-rich syngas efficiently due to the maximum DME yield obtained at H2/(CO CO2) mole ratio =1. A small amount of CO2 in the reactant mixture has little effect on the reaction. Under conditions of H2/(CO CO2) feedstock, water in the system can improve the reaction performance.  相似文献   

3.
GF14 widely occurs in plant species functioning as a regulatory protein in cell signal transdution,including monoamine synthesis,exocytosis and cell cycle regulation.A partial sequence,413bp in length,is cloned from the bulbs of F.crrihosa by means of RT-CPR technique.Sequence alignment with the BLAST program shows that it is highly similar to GF14 gene.A new full-length cDNA,1133bp,is obtained by RACE techniques,It contains a major open reading frame of 262 amino acids,5‘ and 3‘untranslated regions and a long Poly(A) tail,Sequence analysis of deduced GF14 protein from F.crrihosa indicates several conserved motifs of GF14 protiens are also found in sequence of GF14 protein of F.crrihosa.  相似文献   

4.
It is shown in this paper that quantum mechanics, which has so far been built on a foundation completely different from that of the theory of relativity, can actually be deduced mathematically from tbe later without any further physical postulate. Quantum mechanics is indeed, a relativistic statistical mechanics. This leads in particular to the somewhat unexpected but, I must say, much desirable conclusion that the quantization of the microscopic world is simply an effect of the relativistic space-time.  相似文献   

5.
6.
1 Results There is an increased interest in the hydrogen production from renewable sources. In this context, recently, numerous studies which use ethanol for hydrogen production have appeared. Ethanol is easily handled, non-toxic, and it can be obtained from biomass. The steam-reforming of bioethanol has been shown to beeffective for hydrogen production:C2H5OH 3 H2O  6 H2 2 CO2. Six moles of hydrogen can be yielded for each mole of ethanol reacted. However, depending on the catalyst used, other undesirable reactions could take place.Taking into account the complexity of the process, the development of materials which could be used as catalysts with high performance from the point of view of selectivity and activity is a research area of current interest. Several metallic phases have been shown to be active for the process, being cobalt-based catalysts promising catalysts which are active at temperatures relatively low and have been shown high selectivity values under total conversion of ethanol.  相似文献   

7.
Volcanic tuff deposits near Daohugou village, Ningcheng County of Inner Mongolia have yielded many wellpreserved fossils. Here we briefly introduce our recent findings of invertebrates from the Daohugou fauna: mainly insects, conchostracans, anostracans, and spiders. The age of the Daohugou fauna is considered to be Middle Jurassic on the basis of an analysis of various invertebrates especially insects and conchostracans, showing strong similarities to the Yanliao fauna of north China and the Karatau fauna of Kazakhstan.  相似文献   

8.
Origin and tectonic evolution of the Qilian Precambrian basement on NW China were investigated using zircon U-Pb ages with collaborating stratigraphic and paleontological evidence. Zircon grains were separated from two schists, two granitic gneisses and one mylonized gneiss and dated with SHRIMP. Seventy percent of sixty-one detrital zircon ages from two schists ranges from 0.88 Ga to 3.09 Ga, mostly within 1.0 Ga to 1.8 Ga with a peak at 1.6 Ga to 1.8 Ga, and twenty percent varies from 2.0 Ga to 2.5 Ga. A few falls in the Archean and Neoproterozoic periods. The two granitic gneisses were dated 930±8 Ma and 918±14 Ma, whereas the mylonized granitic gneiss was dated 790±12 Ma. These ages represent two periods of magmatisms, which can be correlated with the early and late stages of magmatisms associated with the Jinningian movement on the Yangtze Blocks. The results from this and previous studies indicate that the ages of the Precambrian detrital zircons from the Qilian Block are widely distributed in the Proterozoic era, distinct from the North China Block which was stable in the Neo-Mesoproterozoic era. By contrast, the age histograms of the detrital zircons from the Qilian Block is similar to those from Precambrian basement of the Yangtze Craton. Therefore, it is suggested that the Qilian Block had a strong affinity toward the Yangtze Craton and might belong to the supercontinent Gondwana in the Neoproterozoic time. This inference is supported by Nd model age (TDM), stratigraphic, and paleontological evidence. It is further considered that the Qilian Block was rifted from the supercontinent Gondwana during late Sinian to form an isolated continent in the Proto-Tethyan Ocean, moving towards the Alaxa Block in the North China Craton. The part of Proto-Tethyan Ocean between the Qilian and Alaxa Blocks should correspond to the so-called Paleo-Qilian Ocean. Following the closure of the Paleo-Qilian Ocean in the early Paleozoic, the Qilian Block collided with the Alaxa Block to form the North Qilian Orogenic Belt. Based on this tectonic explanation, the North Qilian ophiolites should represent parts of lithosphere from the Proto-Tethyan Ocean. Lithological and geochronological evidence also indicates that the Qilian Block underwent continental reactivation possibly induced by the deep northward subduction of the North Qaidam Block in early Paleozoic time.  相似文献   

9.
The copper recovery from low-grade copper sulfide ore was investigated using microbial leaching. Several parameters substantially affect the bioleaching of copper; among them, pulp density and nutrient media were selected for investigation. The optimum conditions for copper recovery were a pulp density of 5 g/mL, a mixed-mineral salt medium of Acidithiobacillus thiooxidans (70vol%) and Acidithiobacillus ferrooxidans (30vol%), and 10vol% of inoculum. Under these conditions, the maximum bioleaching capacity of the medium for copper recovery was determined to be approximately 99%. The effect of pulp density on the kinetics of the bioleaching process was surveyed using both da Silva's method and constrained multilinear regression analysis. The kinetics of copper dissolution followed the shrinking core model, and the process was diffusion controlled at a pulp density of 5 g/mL. Nevertheless, at higher pulp densities, the process was controlled by chemical reaction.  相似文献   

10.
Gas chromatography/mass spectrometry (GC-MS) of the essential oil from the aerial parts of Rabdosia lophanthoides resulted in the identification of 108 compounds repreaentin4g 78. 12096 of the oil. Hydro-distillation of Rabdosia lophanthoides yielded a pale yellow oil. The compounds identified and their relative proportions are listed in Table 1 according to their order of elution on an HP-5MS capillary column.  相似文献   

11.
Discussions on the age of the Daohugou fauna—evidence from invertebrates   总被引:6,自引:0,他引:6  
Volcanic tuff deposits near Daohugou village, Ningcheng County of Inner Mongolia have yielded many wellpreserved fossils. Here we briefly introduce our recent findings of invertebrates from the Daohugou fauna: mainly insects, conchostracans, anostracans, and spiders. The age of the Daohugou fauna is considered to be Middle Jurassic on the basis of an analysis of various invertebrates especially insects and conchostracans, showing strong similarities to the Yanliao fauna of north China and the Karatau fauna of Kazakhstan.  相似文献   

12.
Brogi M  Snellen IA  de Kok RJ  Albrecht S  Birkby J  de Mooij EJ 《Nature》2012,486(7404):502-504
The giant planet orbiting τ Bo?tis (named τ Bo?tis b) was amongst the first extrasolar planets to be discovered. It is one of the brightest exoplanets and one of the nearest to us, with an orbital period of just a few days. Over the course of more than a decade, measurements of its orbital inclination have been announced and refuted, and have hitherto remained elusive. Here we report the detection of carbon monoxide absorption in the thermal dayside spectrum of τ Bo?tis b. At a spectral resolution of ~100,000, we trace the change in the radial velocity of the planet over a large range in phase, determining an orbital inclination of 44.5°?±?1.5° and a mass 5.95?±?0.28 times that of Jupiter, demonstrating that atmospheric characterization is possible for non-transiting planets. The strong absorption signal points to an atmosphere with a temperature that is decreasing towards higher altitudes, in contrast to the temperature inversion inferred for other highly irradiated planets. This supports the hypothesis that the absorbing compounds believed to cause such atmospheric inversions are destroyed in τ Bo?tis b by the ultraviolet emission from the active host star.  相似文献   

13.
Study Objective: To compare and analyze the changes of the pulmonary-artery pressure of the migrants coming from different elevation in the hypoxic environment of 4636 - 4907 m extreme altitude. To explore the susceptibility to hypoxic pulmonary-artery hypertension (PH) in the subjects from different altitude and profession. Methods: By using Color Doppler Ultmsonography (CDU), measuring the pulmonary-artery pressure of 207 healthy men, who had continuously being lived and worked at the extreme altitude for more than six months, and then were divided into three groups according to their profession and the altitude of original living place. Results: There was a significant difference in the outcomes of pulmonary-artery pressure from the 3 groups. Conclusions: Altitude of original living place, labor intensity are some of factors that impact the pulmonary-artery pressure of the people who exposure to a hypoxic environment. The pulmonary- artery pressure of person without strenuously physical work experience was more sensitive to hypoxic surroundings than that of labor workers. It was not always the fact at an extreme altitude that the moderate altitude mountaineers were superior to other migrants from a lower altitude or plain. The higher PH was found in the groups of the moderate altitude mountaineers and labor workers. It is unlikely certain that one with PH would surfer from HAPE.  相似文献   

14.
The upstream regulatory region of a seed-specific gene was isolated from the genomic DNA of Brassica napus by PCR amplification. The cloned fragment contained 1755 nucleotides, and shared a sequence homology of 99.6% with the reported data. The coding region of oleic acid desaturase gene was then cloned from Arabidopsis thaliana. The sequencing analysis indicated that the sequence of the PCR product was just the same as reported before. In addition, the plant expression vector harboring the seed-specific promoter and trans-Fad2 gene was constructed.  相似文献   

15.
Introduction Alkaline phosphatase (ALP, EC 3.1.3.1) is a non-specific phosphomonoesterase that functions through a phosphoseryl intermediate to produce free inorganic phosphate or to transfer the phosphoryl group to other alcohols[1,2]. In the past decade…  相似文献   

16.
Fibre bundle tensile curves can be used to characterise fibre processing properties and end-use performance directly and to predict single-fibre properties in theory. In this paper, the tensile behaviour of polyester fibre-bundles has been analysed in characteristic values and diagramming. The characteristic distributions which include the symmetry distribution on right part, SRBS‘(e), on left part, SLBS‘(e) and the curve on base-line modification, MBS‘(e),based on the modulus distribution, BS‘(e), as well as thefrequency density function of broken fibres, B‘(e), havebeen derived from the tail of bundle tensile curves. Thetheoretical and measured results show that the mostimportant curves are MRS‘(e) and B‘(e) and can be usedto estimate the breaking-extension distribution of singlefibres. Especially for MRS‘(e), the modulus distributioncan accurately characterize single-fibre tensile propertiesand is no limitation as the calculation of B‘(e) because thebundle specific stress Y(e) of no fibre breaking at extensione should be found at first.  相似文献   

17.
There are a series of constrasted ideas which appear again and again throughout the novel.The constrast between the world of women and the world of men,the constrast between individual and society,the contradictory individual.Through these constrasted ideas,we can find at the end of 19th century,westernpeople are undergoing a process of spiritual lost after achieving material succees,therefore,Dreiser just express the universal concern for the common problem before the whole human being.  相似文献   

18.
Located in the east portion of the North Orogenic Belt, the Songliao Basin is bounded by the Da Hinggan Mountains in the west, the Xiao Hinggan Mountains in the north, the Zhangguangcai Range in the east, and the North China Craton (NCC) in the south (Fig…  相似文献   

19.
Spurný P  Oberst J  Heinlein D 《Nature》2003,423(6936):151-153
Photographic observations of meteoroids passing through the atmosphere provide information about the population of interplanetary bodies in the Earth's vicinity in the size range from 0.1 m to several metres. It is extremely rare that any of these meteoroids survives atmospheric entry to be recovered as a meteorite on the ground. Príbram was the first meteorite (an ordinary chondrite) with a photographically determined orbit; it fell on 7 April 1959 (ref. 1). Here we report the fourth meteorite fall to be captured by camera networks. We determined the atmospheric trajectory and pre-atmospheric orbit of the object from the photographic records. One 1.75-kg meteorite--named Neuschwanstein and classified as an enstatite chondrite--was recovered within the predicted impact area. The bolide's heliocentric orbit is exceptional as it is almost identical to the orbit of Príbram, suggesting that we have discovered a 'stream' of meteoritic objects in an Earth-crossing orbit. The chemical classifications and cosmic-ray exposure ages of the two meteorites are quite different, however, which implies a heterogeneous stream.  相似文献   

20.
The biological species concept defines species in terms of interbreeding. Interbreeding between spe-cies is prevented by reproductive isolation mechanisms. Based on our results of interspecific hybridi-zation between Helicoverpa armigera and Helicoverpa assulta, reproductive isolation mechanisms of the two species are analyzed. A combination of prezygotic factors (absent sex attraction and physical incompatibility of the genitalia) and postzygotic factors (female absence and partial sterility in F1 hy-brids) causes reproductive isolation of the two species. In addition, the role of interspecific hybridiza-tion in speciation is discussed.  相似文献   

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