C/[Co5nm/Cxnm]4/C纳米颗粒膜的微结构和磁特性研究

在室温下,应用对靶磁控溅射法制备了多层C/[Co5nm/Cxnm]4/C颗粒膜.C靶和Co靶分别采用了射频溅射和直流对靶溅射模式,随后进行了原位退火.用振动样品磁强计(VSM)和扫描探针显微镜(SPM)系统研究了插层C层的厚度对多层颗粒膜的微结构和磁特性的影响.X射线衍射(XRD)图样显示出样品具有六角密堆积结构.振动样品磁强计测量表明磁矩很好地排列在膜面内,在插层C层的厚度为12nm时矫顽力达到最大值,剩磁比接近于1.     

C覆盖层对FePt纳米薄膜微结构的影响

使用对靶直流磁控溅射和原位退火方法在普通玻璃基底上制备了C/FePt/Fe纳米颗粒薄膜.通过表征分析表明,加入C覆盖层对FePt薄膜的微结构有较大的影响.经过退火处理后C颗粒渗透到磁性层中,起到了隔离磁性颗粒和减弱颗粒间结合能的效果,并且减弱了磁性颗粒间强的交换耦合作用,最终使颗粒和磁畴减小,增加了L10结构的有序程度;样品获得了1 089kA/m的矫顽力.     

Co/AlO/FeNi三层膜的磁结构特性

利用多靶离子束溅射配合振动样品磁性分析技术对Co/AlO/FeNi纳米三层膜进行了分步制备与磁特性研究.分析结果表明,Co膜与FeNi膜的层间耦合强度及类型取决于中间隔离层(铝膜或氧化铝膜)的性能和厚度;垂直样品膜平面的电流输运机制源于电子隧穿和自旋电子流对铁磁层局域磁矩的作用.     

多靶射频磁控共溅射SmCo/Cr薄膜的制备和磁性能

采用多靶射频磁控共溅射方法制备了SmCo/Cr薄膜,用XRD和VSM测量了各样品的微结构和矫顽力.结果表明,SmCo膜具有较强的垂直各向异性,当Cr底层溅射时间为5min、SmCo磁性层溅射时间为14min、Co靶溅射功率为220W时,所得到的薄膜垂直矫顽力最大.     

后退火对C/CoCrPt/Ti颗粒膜的微结构和磁特性的影响

在室温下,采用射频溅射模式和直流对靶溅射模式制备了C(60 nm)/CoCrPt(30 nm)/Ti(60 nm)系列薄膜.样品在高真空条件下进行30 min后退火,退火温度分别为RT(室温),300,500,600 ℃.研究表明,后退火处理对样品的微结构和磁特性有很大的影响.VSM测量结果显示,当ta=300 ℃时,垂直膜面矫顽力达到最大(131 kA/m);扫描探针显微镜(SPM)观察结果显示,样品的平均粒径最小为9.6 nm.     

Ti(t)/Co(54nm)/Ti(t)纳米薄膜的制备和磁特性

应用对靶磁控溅射法在玻璃基底上制备了Ti(t)/Co(54nm)/Ti(t)(t=5,10,15,20,25nm)纳米薄膜,研究了非磁性Ti层厚度对样品磁特性的影响.实验结果显示,Ti(5nm)/Co(54nm)/Ti(5nm)样品的垂直膜面矫顽力高达159kA·m-1.研究表明,如此高的矫顽力主要源于样品晶粒的磁晶各向异性.另外,非磁性Ti原子的扩散在一定程度上减小了磁性颗粒间的交换相互作用,导致出现大的矫顽力.     

烧结温度对Co掺杂ZnO稀磁半导体性能的影响

通过溶胶—凝胶法制备了Co掺杂ZnO稀磁半导体纳米颗粒,利用X射线衍射仪、透射电子显微镜和振动样品磁强计等测试手段对Co掺杂ZnO稀磁半导体样品进行了结构和磁性表征.结果表明,随着烧结温度的升高,样品的固溶度逐渐增加.当样品的烧结温度为800℃时,样品为单相的ZnO结构.磁性测试结果表明,Co掺杂ZnO稀磁半导体在室温下具有铁磁性.     

Co-Al-O磁性纳米颗粒膜微波磁性研究

通过实验研究和理论计算模拟研究Co-Al-O磁性纳米颗粒膜的微波磁性.首先采用双靶反应磁控溅射工艺制备Co-Al-O磁性纳米颗粒膜,探讨工艺条件对薄膜微波磁谱的影响;然后,利用Landau-Lifshitz-Gilbert方程和Bruggeman有效媒质理论,计算模拟主要磁参量变化对磁性纳米颗粒膜磁谱的影响.研究结果表明:增大Co靶溅射功率,可使磁性颗粒间因分布电容效应引起的涡流损耗增加,从而使磁谱的共振线宽增大;阻尼系数增大导致磁导率频谱的共振线宽增人趋势与实验结果基本一致.     

CoFe_2O_4/Co_3Fe_7-Co纳米核壳结构的高频磁特性

通过H2热还原法制备了一种以磁性介电材料Co Fe2O4为核,以磁性金属材料Co3Fe7-Co为壳的纳米核壳结构。表征了样品的形貌、结构、静态和动态磁性并利用Landau-Lifshitz-Gibert方程对核壳结构的磁谱进行了拟合。结果表明Co Fe2O4/Co3Fe7-Co纳米核壳结构能够有效的提高磁导率,其共振机制以自然共振和交换共振为主。该结构有利于增强磁损耗,在微波领域具有广泛应用价值。     

纳米磁性多层膜电磁介观特性

利用多靶离子束真空溅射技术制备平面结构为“铁磁金属／非磁性绝缘体／铁磁金属”的纳米多层膜样品．在室温下研究了样品的电磁输运特性．测量了样品的磁致电阻、垂直和平行样品膜面方向的电磁输运特性．研究结果显示了纳米金属磁性多层膜材料的微结构空间位置相关性和电磁输运过程奇异的非定域特性．     

Co/Ru多层膜的磁性

使用电子束蒸发的方法制备多层膜样品,采用振动样品磁强计测量磁学性能.通过分析发现,随着Co层厚度的逐渐减小,垂直易磁化的趋势逐渐增强.当Co层厚度减至0.5nm时,实现了垂直易磁化.同时,Co原子磁矩随Co层厚度增加而减小.     

用纵向磁光克尔效应观察Co/Cu/Co三层膜正交方向磁矩随磁场的翻转过程

运用光弹调制器和锁向放大器作为主要的光电子仪器,搭建磁光克尔效应实验系统,将平行和垂直磁场应用于纵向磁光克尔(Kerr)效应,用来分析薄膜正交方向磁矩随磁场翻转的情况.应用此方法,研究了在不同衬底上用磁控溅射方法制备的Co(2.7 nm)/Cu(2 nm)/Co(2.7 nm)三层膜的磁性及磁矩翻转,探索其耦合机理.衬底与间隔层Cu层表面结构的差异,诱导了底层Co与表面层Co结构的差异,导致底层和表面层Co膜的矫顽力不同,从而实现了两铁磁层的磁矩翻转不一致.     

球形多孔氧化钴/碳复合材料的制备及电容性能研究

采用水热合成和煅烧制备氧化钴/碳(Co3O4/C)复合材料,通过SEM、XRD、N2吸附实验等对该材料进行表征.制备的Co3O4/C复合材料为5μm大小,孔径约为30nm的多孔球形结构.在6mol/L的氢氧化钾溶液中进行电化学测试.结果表明,Co3O4/C复合材料具有良好的电容性能.在电流密度为1A/g时,比电容为143F/g.此外,Co3O4/C复合材料还表现出良好的循环稳定性,在1A/g的电流密度下,充放电循环1000次后,比电容保持率为77.8%.     

Co/Co3O4双层膜中的交换偏置

在磁控溅射系统中利用Co靶和Co3O4靶制备了Co/Co3O4双层膜.振动样品磁强计(VSM)结果显示在测量温度高于Co3O4的奈耳温度时,交换偏置场HE仍然存在,多功能光电子能谱(XPS)分析表明在靠近Co层一侧Co3O4层被还原成一薄层的CoO.当Co3O4层的厚度低于3.5 nm时,Co3O4完全被还原成CoO.     

Magnetoresistive sensors with hybrid Co/insulator/ZnO:Co junctions

Magnetic tunnel junctions (MTJs), as the seminal spintronic devices, are expected for applications in magnetoresistive sensors due to their large magnetoresistance (MR) and high field sensitivity. Two hybrid Co/insulator/ZnO:Co junctions were fabricated with two different barriers to investigate the magneto-transport properties. Experimental results indicate that, both Co/MgO/ZnO:Co and Co/ZnO/ZnO:Co junctions show the positive and nearly linear MR, and their tunnel magnetoresistances (TMR) are 21.8% and 13.6%, respectively, when the current is applied perpendicular to the film plane under the magnetic field of 2 T at 4 K. The nonlinearity of MR is less than 1% within the magnetic field (H) of 1 kOe < H < 12 kOe at low temperature, making them attractive as magnetoresistive sensors. The higher MR of Co/MgO/ZnO:Co junctions is due to the superior spin filtering effect and larger effective barrier height of the MgO barrier. This linear MR characteristic of Co/insulator/ZnO:Co structures shows a promising future on the applications of diluted magnetic semiconductors in magnetoresistive sensors.     

Aging effect of Co/C soft X-ray multilayer mirrors

Conclusion We have investigated the aging effect of Co/C soft X-ray multilayers prepared by dualfacing-target sputtering. It was found that phase-separation phenomena exist in the Co/C multilayers, which causes the reflectivity at grazing incidence to increase with time, and can be interpreted as positive enthalpy of Co-C mixing. It is evident that oxidation of the outermost layer of Co/C multilayers with Co deposited last is a potential problem in applications where the highest possible reflectivity is required.     

Cu层厚度对NiFe/Cu/Co 的巨磁电阻效应影响

用磁控射频溅射法制备了NiFe/Cu/Co多层膜;研究了薄膜的磁特性和磁电阻特性与中间层Cu厚度的关系.在适当的Cu层厚度下 (大约为2 nm),制备出了具有很好自旋阀巨磁阻效应的多层膜.研究表明,在弱磁场下,薄膜的磁电阻回线的斜率与原来的磁化过程有关,因此该薄膜材料可以用于巨磁电阻存储器中.     

Friction and Wear Behaviors of C/C-Si C Composites under Water Lubricated Conditions

C/C-SiC composites have the potentiality to be applied in shield pumps of nuclear reactors as the bearing material because of their low density, good mechanical properties and excellent tribological properties. The C/C-SiC composites are fabricated via reactive melt infiltration(RMI) using silicon liquid infiltrated in C/C matrix composites. Friction and wear behaviors of C/C-SiC composites under water lubricated conditions are investigated using the block-on-ring test at room temperature, and compared with those of the resin graphite which is used as the bearing material in shield pumps at present. In addition, friction and wear mechanisms of C/C-SiC composites under water lubricated conditions have been discussed. Results show that tensile strengths of C/C-SiC composites are 150-210 MPa, and compressive strengths are 403-536 MPa. Friction and wear behaviors of C/C-SiC composites are closely related to the load and the speed. The time to reach a stable friction status decreases with the increase of the speed. Though the friction coefficient of C/C-SiC composites under water lubricated conditions is slightly higher than that of graphite, the wear rate of C/C-SiC composites is much lower, which suggests that the C/C-SiC composites can sustain a longer life during operation.     

Co改性Pd/C催化的葡萄糖催化氧化反应

以活性炭为栽体,制备了Pd／C,Pd-Co／C催化剂．活性评价结果表明,Pd-Co／C催化剂显示出良好的催化性能,反应4h后,葡萄糖的转化率达98．8％,较Pd／C催化剂的活性有显著的提高．BET,XRD表征结果也表明．Co的添加及焙烧过程,使载体由无定形结构转变为晶型结构,且比表面积和微孔容积均有所增加,既提高了Pd的表面分散度,又增大了Pd在催化剂表面的裸露程度,从而使Pd-Co／C催化剂表现出良好的催化性能．