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1.
微波辐射降解水中高浓度有机物的H2O2综合反应体系研究   总被引:1,自引:0,他引:1  
以1.0g苯酚溶于1000mL无酚水中作为高浓度的有机物模拟水样组成反应模型,在微波辐射下研究了H2O2综合反应体系H2O2/TiO2;H2O2/Fe^2+;H2O2/活性炭;H2O2,Fe^2+/活性炭对水中高浓度苯酚的降解作用,实验测量了H2O2在不同体系中的分解速率,并测量苯酚在这些体系中的分解速率和有机物耗氧量(CODCr)去除率,实验表明H2O2所在体系的分解速率和苯酚的分解速率依次为H2O2,Fe^2+/活性炭〉H2O2/Fe^2+〉H2O2/活性炭〉H2O2/TiO2,而体系H2O2/活性炭由于活性炭在微波辐射下有较强的氧化协同作用,该体系对有机物COD呈现出很高的去除率。  相似文献   

2.
微波-H_2O_2-活性炭协同催化氧化处理苯酚废水   总被引:6,自引:0,他引:6  
采用微波、H2O2和活性炭协同催化氧化法处理苯酚废水,探讨各种因素协同作用以及对苯酚废水处理效果的影响.结果表明,微波-H2O2-活性炭氧化体系能高效快速降解废水中苯酚,100 mL初始pH为5、质量浓度为100 mg/L的苯酚废水中,在活性炭3 g、微波辐射18 min、微波辐射功率200 W、H2O2质量浓度1.5 g/L的最佳处理工艺条件下,苯酚去除率达98.5%.  相似文献   

3.
催化氧化法处理对氯硝基苯(PCNB)废水的研究   总被引:3,自引:0,他引:3  
以活性炭为催化剂,H2O2作氧化剂催化氧化降解对氯硝基苯(PCNB),结果表明,在H2O2/CODcr=1.2,活性炭/H2O2=0.4,pH=3.0的条件下,反应可在180min结束,PCNB的去除率高于99%,CODcr去除率可达80%,与Fenton试剂法相比较,CODcr去除率提高1.78倍,并对降解机理作了初步讨论。  相似文献   

4.
超声-Fenton试剂耦合降解水中苯酚的研究   总被引:8,自引:0,他引:8  
采用超声-Fenton试剂耦合法降解水中的苯酚.单因素考察了反应时间、超声功率、Fenton试剂中H2O2和Fe^2+的浓度配比、初始pH值以及反应温度对苯酚降解率的影响;采用正交实验法,得到各因素影响显著性的先后顺序为:Fenton试剂中H2O2与Fe^2+的浓度配比、超声功率、反应时间、初始pH值;优化了降解反应的工艺条件:常压、30℃时,在超声频率为40kHz、超声功率为400W、H2O2和Fe^2+的浓度分别为60mmol/L和1.2mmol/L、反应时间为10min、初始pH值为3的最佳条件下处理100mg/L的苯酚溶液,其降解率可达99.5%,在最佳工艺条件下对超声-Fenton降解苯酚的动力学研究发现:反应符合表观一级反应动力学,研究表明:超声-Fenton试剂耦合法明显优于二者的简单叠加,能够显著地缩短反应时间,提高苯酚的降解率。  相似文献   

5.
采用UV/Fenton试剂降解SDBS阴离子表面活性剂废水,在初始p H为3.0,Fe2+浓度为0.033 mol·L-1,H2O2分2次投加,总投加浓度为0.89 mol·L-1时,室温下紫外辐射反应30min,SDBS降解率可达89.01%.将UV、Fenton、UV/Fenton 3种体系处理SDBS废水的效果进行比较,发现UV对Fe2+催化H2O2氧化降解有机废水存在协同作用.  相似文献   

6.
以Fenton(Fe^3+/H2O2)光催化降解草甘膦废水,跟踪体系化学需氧量(Chemical Oxygen Demand,COD),研究了不同条件下(光源、试剂浓度和酸度等)废水光催化氧化特性及光催化反应条件.探讨了在太阳光及紫外光照射条件下Fenton试剂组分Fe^3+与H2O2不同投料比、投料量、介质酸度对光催化降解废水的影响.结果表明,利用太阳光、紫外光能显著提高废水降解速率;太阳光照射条件下,Fe^3+/H2O2为1:10投量比,pH=3时,对废水COD降解效果最佳,COD去除率达82%.  相似文献   

7.
分别用Fenton试剂法和EF-Feox法氧化处理苯酚模拟废水,研究结果显示:Fenton试剂法中,H2O2投加量为10mL/L,Fe^2+为4mmol/L,pH为4.1,经过30min后,COD去除率达75.7%,而在EF-Feox法中,在外加电压7V,H2O2投加量为5.6mL/L,Na2SO4投加量0.7g/L,pH为3.1,经过30min后,COD去除率达83.3%.两者比较,EF-Feox法比Fenton试剂法的去除率效果提高了近8%。  相似文献   

8.
活性炭—H2O2催化氧化处理垃圾渗滤液的试验研究   总被引:7,自引:0,他引:7  
处理垃圾渗滤液试验以活性炭作催化剂、H2O2作氧化剂。结果表明,在H2O2/COD0=1.5,活性炭/H2O2=0.6,pH值为2的条件下反应可以在180min内结束,其中COD及色度的去除率分别为82.8%和85.5%,臭味消失,比Fenton试剂法处理渗滤液效果要好,并对氧化机理进行了初步探讨。  相似文献   

9.
Fenton试剂氧化降解亚甲基蓝的动力学研究   总被引:2,自引:0,他引:2  
采用Fenton试剂氧化降解亚甲基蓝,通过对亚甲基蓝染料处理过程中的紫外、红外光谱分析可知,Fenton对亚甲基蓝的结构造成了严重破坏,探讨了Fenton试剂氧化降解亚甲基蓝的反应动力学.结果表明,Fenton氧化过程中,H2O2初始浓度、FeSO4初始浓度及温度对反应都有影响,且确定反应为一级反应,其动力学方程式为:-dC/dt=0.1842exp(-3.53/RT)·[H2O2]始^0.88561·[Fe^2+]始^0.88519.  相似文献   

10.
UV/Fenton/杂多酸体系光催化氧化结晶紫   总被引:2,自引:1,他引:1  
由于光助Fenton反应产生大量·OH而使有机物得以氧化降解,杂多酸具有强的紫外光吸收特性,可以作为Fenton反应的活化剂.研究以结晶紫为底物,考察了UV/Fenton/杂多酸体系对染料的降解作用,考察了pH值、H2O2的用量、Fe2+的用量、杂多酸的引入等因素的影响,确定了优化的实验条件:在结晶紫的浓度是20 mg·L-1时,加入2.4 g·L-1 30%的H2O2,0.02 g·L-1 的Fe2+,0.024 g·L-1的磷钨酸,pH2.7时反应60min后测得脱色率高达95%.研究结果表明:紫外光能有效地促进结晶紫的氧化脱色,引入杂多酸催化剂后,可增强Fenton试剂的反应活性,大大缩短反应时间.  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

13.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

14.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

15.
Location based services is promising due to its novel working style and contents.A software platform is proposed to provide application programs of typical location based services and support new applications developing efficiently. The analysis shows that this scheme is easy implemented, low cost and adapt to all kinds of mobile nework system.  相似文献   

16.
以AC-13级配为基础,将橡胶颗粒代替部分集料掺入混合料中,以低温弯曲试验为评价方法对不同橡胶颗粒掺量下沥青混合料的低温抗裂性进行研究,并引入应变能密度值对混合料的低温抗裂性进行综合评价.试验结果表明:橡胶颗粒沥青混合料试件的破坏微应变均超过2 300,满足冬寒区的技术指标;无论是否掺加橡胶颗粒,随着温度的下降,沥青混合料破坏时的最大弯拉强度增大,弯拉应变降低,劲度模量增大;弯曲应变能密度在胶粒掺量为1%左右时具有较大的弯曲应变能密度值,此时橡胶颗粒沥青混合料具有较好的低温抗裂性.  相似文献   

17.
AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…  相似文献   

18.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

19.
Quality traits in wheat (Triticum aestirum L.) were studied by quantitative trait locus (QTL) analysis in a recombinant inbred line (RIL) population, a set of 131 lines derived from Chuan 35050 × Shannong 483 cross (ChSh). Grains from RILs were assayed for 21 quality traits related to protein and starch. A total of 35 putative QTLs for 19 traits with a single QTL explaining 7.99-40.52% of phenotypic variations were detected on 10 chromosomes, 1D, 2A, 2D, 3B, 3D, 5A, 6A, 6B, 6D, and 7B. The additive effects of 30 QTLs were positive, contributed by Chuan 35050, the remaining 5 QTLs were negative with the additive effect contributed by Shannong 483. For protein traits, 15 QTLs were obtained and most of them were located on chromosomes 1 D, 3B and 6D, while 20 QTLs for starch traits were detected and most of them were located on chromosomes 3D, 6B and 7B. Only 7 QTLs for protein and starch traits were co-located in three regions on chromosomes 1D, 2A and 2D. These protein and starch trait QTLs showed a distinct distribution pattern in certain regions and chromosomes. Twenty-two QTLs were clustered in 6 regions of 5 chromosomes. Two QTL clusters for protein traits were located on chromosomes 1D and 3B, respectively, three clusters for starch traits on chromosomes 3D, 6B and 7B, and one cluster including protein and starch traits on chromosome 1D.  相似文献   

20.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

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