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Ionic Liquids Derived New Media for from the Chiral Pool: Fine Chemistry
作者姓名:A.C. Gaumont D. Bregeon J. Levillain C. Baudequin F. Guillen J.C. Plaquevent
作者单位:[1]Laboratoire de Chimie Moléculaire et Thioorganique, UNIR CNRS 6507, ENSICAEN,6 bd du Mar&hal Juin, 14050 Caen, France [2]IRCOF , UMR CNRS 6014, Université de Rouen, rue Tesnibes , 76821 Mont Saint-Aignan , France
摘    要:Ionic liquids (Ils) are low melting point salts, which are characterized by properties such as high ability to dissolve organic, organometallic and even inorganic compounds, absence of flammability, lack of measurable vapour pressure and high thermal stability. Due to these peculiar properties, they have recently attracted considerable attention as greener alternatives to volatile organic solvents. A few chiral ionic liquids, which could provide a renewal in the field of chiral solvents, have also been reported recently. Herein, we will present the synthesis of a new family of ionic liquids based on a thiazolinium skeleton. Preliminary results on the use of these chiral ionic liquids in the field of chiral recognition and organic synthesis will also be reported.

关 键 词:离子液体 分子识别 金属盐 热稳定性 chiral pool
文章编号:0427-7104(2005)05-0674-02
收稿时间:2005-08-10
修稿时间:2005-08-10
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