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Synthesis of PPy-like Nanocrystallines by Oriented Plasma Polymerization at Atmospheric Pressure
作者姓名:方忻生  郭颖  徐金州  张菁
作者单位:College of Sciences, Dongh ua University, Shanghai 201620
摘    要:Polymeric polypyrrole-like (PPy-llke) nanocrystallines were fast synthesized through oriented plasma polymerization at atmospheric pressure and room temperature. The effects of discharge power on the nanocrystalline morphology were investigated. Larger power tends to produce longer nanocrystallines. 3 mm long nanowires were produced at the largest power in our experiment. TEM image and the sharp electronic diffraction spots in SAD suggest that the nanoparticles have a single crystal phase. The chemical structure of the nanocrystalline has been studied through FTIR, EDX etc. This novel polymerization method could have great applications in fabricating functional polymeric nanocrystallines.

关 键 词:聚吡咯  合成  纳米晶  大气压  等离子聚合
收稿时间:2005-12-02

Synthesis of PPy-like Nanocrystallines by Oriented Plasma Polymerization at Atmospheric Pressure
FANG Xin-sheng,GUO Ying,XU Jin-zhou,ZHANG Jing.Synthesis of PPy-like Nanocrystallines by Oriented Plasma Polymerization at Atmospheric Pressure[J].Journal of Donghua University,2006,23(3):64-66.
Authors:FANG Xin-sheng  GUO Ying  XU Jin-zhou  ZHANG Jing
Abstract:Polymeric polypyrrole-like (PPy-like) nanocrystallines were fast synthesized through oriented plasma polymerization at atmospheric pressure and room temperature. The effects of discharge power on the nanocrystalline morphology were investigated. Larger power tends to produce longer nanocrystallines. 3 mm long nanowires were produced at the largest power in our experiment. TEM image and the sharp electronic diffraction spots in SAD suggest that the nanoparticles have a single crystal phase. The chemical structure of the nanocrystalline has been studied through FTIR, EDX etc. This novel polymerization method could have great applications in fabricating functional polymeric nanocrystallines.
Keywords:atmospheric oriented plasma polymerization  polypyrrole (PPy)  nanocrysllines
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