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Research progress in synthesis and catalysis of polyoxometalates
作者姓名:GONG Yun  HU Changwen* and LIANG Hong
作者单位:1. Department of Chemistry,School of Science,the Institute for Chemical Physics,Beijing Institute of Technology,Beijing 100081,China; 2. Chemical Industry Press,Beijing 100029,China
摘    要:Polyoxometalates (POMs) form a large class ofmetal oxide cluster type compounds. Their wealthytopology, physical and chemical properties have at tracted increasing interests. In this paper, based onour group’s research, we review the latest progress inthe synthetic chemistry and catalysis of POMs and in troduce some POMs with novel structure and theirderivatives that emerged in 2002—2004. Most of thecited references come from those published in 2003.Due to POMs’superio…


Research progress in synthesis and catalysis of polyoxometalates
Gong Yun,HU Changwen,LIANG Hong.Research progress in synthesis and catalysis of polyoxometalates[J].Progress in Natural Science,2005,15(5).
Authors:Gong Yun  HU Changwen  LIANG Hong
Abstract:Recent progress in the synthetic chemistry and catalysis of polyoxometalates (POMs) is reviewed. The novel POMs and their derivatives emerging in nearly three years (2002-2004) are introduced, including POMs with novel structure, POMs-organic hybrid compounds and host-guest complexes. Our review is focused on the elaboration of POMs' supramolecular chemistry.
Keywords:polyoxometalates  hybrid  host-guest  structure  supramolecule  catalysis
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