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Removal of TOC and Color in Bleaching Effluents from Straw Pulp and Paper Mill by Fe^0- H2O2 Process
引用本文:于水利 刘汝鹏 刘亚男. Removal of TOC and Color in Bleaching Effluents from Straw Pulp and Paper Mill by Fe^0- H2O2 Process[J]. 东华大学学报(英文版), 2006, 23(3): 114-119
作者姓名:于水利 刘汝鹏 刘亚男
作者单位:[1]School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090 [2]College of Envirorrmental Science and Engineering, Donghua University, Shanghai 201620
摘    要:TOC and color in the bleaching effluent from straw pulp paper process could not reach draining standard after its treatment by a biochemical process. In this study, advanced treatment by integrated micro-electrolysis (Fe^0) method and Fenton-like process was investigated under various conditions, i.e. pH, Fe/C ratio, initial I-I2O2 concentration and carrier gas. Results showed that Fe/C ratio(V/V = 1.5), larger H2O2 dosage around 50 rag/L, lower pH(pH= 3) turned out to be particularly efficient. Temperature was a key parameter, remarkably increasing reaction rates. Carrier air not only improved reaction efficiency, but also saved H2O2 dosage. Chlorinated organic compounds could be reductive dechlorinated by Fe^0 reaction and oxidated by OH produced from Fenton process. The combination of Fe^0 and H2O2 reactions had been proved to be highly effective for the advanced treatment of such a type of wastewaters, and important advantages concerning the application in the study.

关 键 词:深度处理 绿色化学 有机化合物 维电解 造纸厂
收稿时间:2005-10-08

Removal of TOC and Color in Bleaching Effluents from Straw Pulp and Paper Mill by Fe0- H2O2 Process
YU Shui-li,LIU Ru-peng,LIU Ya-nan. Removal of TOC and Color in Bleaching Effluents from Straw Pulp and Paper Mill by Fe0- H2O2 Process[J]. Journal of Donghua University, 2006, 23(3): 114-119
Authors:YU Shui-li  LIU Ru-peng  LIU Ya-nan
Abstract:TOC and color in the bleaching effluent from straw pulp paper process could not reach draining standard after its treatment by a biochemical process. In this study, advanced treatment by integrated micro-electrolysis (Fe0) method and Fenton-like process was investigated under various conditions, i.e. pH, Fe/C ratio, initial H2O2 concentration and carrier gas. Results showed that Fe/C ratio(V/V =1.5), larger H2O2 dosage around 50 mg/L, lower pH(pH=3) turned out to be particularly efficient. Temperature was a key parameter, remarkably increasing reaction rates.Carrier air not only improved reaction efficiency, but also saved H2O2 dosage. Chlorinated organic compounds could be reductive dechlorinated by Fe0 reaction and oxidated by · OH produced from Fenton process. The combination of Fe0 and H2O2 reactions had been proved to be highly effective for the advanced treatment of such a type of wastewaters, and important advantages concerning the application in the study.
Keywords:straw pulp and paper mill  bleaching effluents  advanced treatment  chlorinated organic compounds  micro-electrolysis  Fenton-like process
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