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中药香附的化学成分研究
引用本文:王蔷,段文兰,段云凤,易春蝶,曾广智,尹俊林.中药香附的化学成分研究[J].云南民族大学学报(自然科学版),2021(1):6-11.
作者姓名:王蔷  段文兰  段云凤  易春蝶  曾广智  尹俊林
作者单位:1.云南民族大学民族医药学院民族药资源化学国家民委-教育部重点实验室
摘    要:利用硅胶柱层析、Sephadex LH-20凝胶柱层析及高效液相等多种方法对中药香附(Cyperus-rotundus L.)95%甲醇提取物的石油醚萃取物中的化学成分进行了研究,从中分离得到15个化合物.根据其理化性质和波谱数据鉴定所得化合物为倍半萜类化合物10个,分别为isonardoeudesmol C(1)、(...

关 键 词:香附  化学成分  倍半萜  甾醇

Chemical constituents isolated from Cyperus rotundus L.
Institution:,Key Laboratory of Chemistry in Ethnic Medicinal Resources, State Ethnic Affairs Commission & Ministry of Education of China,School of Ethnic Medicine, Yunnan Minzu University
Abstract:The chemical constituents of the petroleum ether extract of the methanol extract of Cyperus rotundus L. were studied by the chromatographic techniques such as silica gel column chromatography, Sephadex LH-20, and HPLC, which led to the isolation of 15 compounds including 10 sesquiterpenes(1~10) and 5 sterols(11~15). On the basis of the NMR spectral data, the compounds were identified as isonardoeudesmol C(1),(+)-nootkatone(2), teutenone A(3), ishwarol B(4),β-dictyopterol(5),1R,3R,6S,7R,10S-7-Isopropyl-4,10-dimethylbicyclo 4.4.0] dec-4-en-3,10-diol(6), isonardoeudesmol B(7), l β-hydroxy-α-cyperone(8),1β,4β-dihydroxyeudesman-11-ene(9), chrysanthemumin C(10),5α-stigmast-9(11)-en-3β-ol(11), β-Sitosterol(12),β-Sitosterol-D-glycoside(13),desmosterol(14), and Stigmasterol(15). Compound 4 and 6 were isolated from the genus Cyperus for the first time.
Keywords:Cyperus rotundus L    chemical constituents  sesquiterpene  sterols
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