| 四硫富瓦烯衍生物制备及其机理研究 |
| |
| 引用本文： | 王建华 史真. 四硫富瓦烯衍生物制备及其机理研究[J]. 西北大学学报(自然科学版), 1997, 27(1): 44-48 |
| |
| 作者姓名： | 王建华 史真 |
| |
| 作者单位： | 西北大学化学系!西安，710069，西北大学化学系!西安，710069，西北大学化学系!西安，710069，西北大学化学系!西安，710069，西北大学化学系!西安，710069 |
| |
| 摘 要： | 以三价磷化合物为偶联剂，合成了6种有机电子给体，对偶联反应规律、应用范围及反应机理进行了讨论。提出该偶联反应的环加成与碳烯反应的竞争机制，认为反应中的重排是[2，3]负离子σ迁移反应。
|
| 关 键 词： | 四硫富瓦烯 三硒硫富瓦烯 偶联 |
Preparation of Tetrathiafulvalene Derivatives and Study of Their Mechanism |
| |
| Wang Jianhua, Shi Zhen, Zhang Wulong, Yang Gengxin, Wang Xiaogang. Preparation of Tetrathiafulvalene Derivatives and Study of Their Mechanism[J]. Journal of Northwest University(Natural Science Edition), 1997, 27(1): 44-48 |
| |
| Authors: | Wang Jianhua Shi Zhen Zhang Wulong Yang Gengxin Wang Xiaogang |
| |
| Abstract: | Tri-valence phosphorous compounds were used as coupling agent, 6 organic electron donorswere prepared. The results of coupling reaction, the scope of application and their mechanism arediscussed, competitive mechanism of cyclic addition and carbene reaction in the coupling reaction isproposed. The rearrangement in the reaction is considered as 2,3 anionic sigmatropic shift reaction. |
| |
| Keywords: | tetrathiafulvalene coupling reaction mechlanism |
| 本文献已被 CNKI 维普 等数据库收录！ |
