| 5，10，15,20-四对羧基苯基卟啉及以其为核的星型聚合物的合成与表征 |
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| 引用本文： | 王迪,孙明昊,张洪文,王静媛. 5，10，15,20-四对羧基苯基卟啉及以其为核的星型聚合物的合成与表征[J]. 吉林大学学报(理学版), 2005, 43(4): 524-526 |
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| 作者姓名： | 王迪 孙明昊 张洪文 王静媛 |
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| 作者单位： | 吉林大学化学学院， 长春 130012 |
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| 摘 要： | 合成了5，10，15,20-四对羧基苯基卟啉(以其为核)与通过新的自由基聚合方法合成的聚丙烯酸丁酯(以其为臂)反应， 成功得到了一种新的星型聚合物. 紫外光谱 中卟啉特征吸收峰B带、 Q带的红移以及通过GPC对分子量及分散度的验证进一步推断了聚合物的结构.
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| 关 键 词： | 卟啉 ATRP 星型聚合物 |
| 文章编号： | 1671-5489(2005)04-0524-03 |
| 收稿时间： | 2004-12-07 |
| 修稿时间： | 2004-12-07 |
Synthesis and Characterization of 5,10,15,20-Tetra(4-Carboxylphenyl)porphyrin and Star-shaped Polymer |
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| WANG Di,SUN Ming-hao,ZHANG Hong-wen,WANG Jing-yuan. Synthesis and Characterization of 5,10,15,20-Tetra(4-Carboxylphenyl)porphyrin and Star-shaped Polymer[J]. Journal of Jilin University: Sci Ed, 2005, 43(4): 524-526 |
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| Authors: | WANG Di SUN Ming-hao ZHANG Hong-wen WANG Jing-yuan |
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| Affiliation: | College of Chemistry, Jilin University, Changchun 130012, China |
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| Abstract: | In this paper, 5,10,15,20-tetra(4-carboxylphenyl)porphyrin(TCPP) was synthesized first, then a kind of new star-shaped polymer was synthesized successfully with TCPP as the core and poly(butyl acrylate)(PBA) obtained by atom transfer radical polymerization(ATRP) as the arms. The characteristic ultraviolet absorption peak shows the difference between Soret band and Q bands of TCPP and the new star-shaped (polymer) and it can also be concluded that the molecular weight and polydispersity of the star-shaped polymer were controlled perfectly from the GPC spectrum. |
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| Keywords: | porphyrin atom transfer radical polymerization star-shaped polymer |
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