| 氰根桥联双金属配位聚合物K2[Ni(en)2][Fe(CN)6]的合成与表征 |
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| 引用本文： | 刘传芳,黄子群,高小余,张胜义.氰根桥联双金属配位聚合物K2[Ni(en)2][Fe(CN)6]的合成与表征[J].安庆师范学院学报(自然科学版),2007,13(3):36-38. |
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| 作者姓名： | 刘传芳 黄子群 高小余 张胜义 |
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| 作者单位： | 皖西学院,化学与生命科学系,安徽,六安,237012;安徽,大学化学化工学院,安徽,合肥,230039 |
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| 基金项目： | 安徽省教育厅自然科学基金（2004KJ354）资助. |
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| 摘 要： | 室温下将Ni(en)_2(NO_2)_2的DMF溶液与K_4Fe(CN)_6]水溶液反应合成了标题化合物——一种新型氰基桥联配位聚合物K_2Ni(en)_2]Fe(CN)_6]。对标题化合物进行元素分析、原子吸收光谱、紫外光谱、红外光谱研究,对标题化合物的结构进行了推测,变温磁化率测定表明,在分子内部存在弱的反铁磁相互作用。
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| 关 键 词： | 镍(Ⅱ)配合物 铁(Ⅱ)配合物 氰基桥联 磁性质 |
| 文章编号： | 1007-4260（2007）03-0036-03 |
| 修稿时间： | 2006-12-26 |
Synthesis and Characterization of a Cyrano-bridged bi-metallia Coordination Polymer K2[Ni(en)2][Fe(CN)6] |
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| LIU Chuan-fang,HUANG Zi-qun,GAO Xiao-yu,ZHANG Sheng-yi.Synthesis and Characterization of a Cyrano-bridged bi-metallia Coordination Polymer K2[Ni(en)2][Fe(CN)6][J].Journal of Anqing Teachers College(Natural Science Edition),2007,13(3):36-38. |
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| Authors: | LIU Chuan-fang HUANG Zi-qun GAO Xiao-yu ZHANG Sheng-yi |
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| Institution: | 1. Department of Chemistry and Biology, Wanxi College, Lu-an 237012; 2, Department of chemistry Anhui University ,Hefei 230039,China |
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| Abstract: | A cyrano-bridged coordination polymer K_2Ni(en)_2]Fe(CN)_6]is synthesized by an aqueous solution of K_4Fe(CN)_6] and a solution of Ni(en)_2(NO)_2)_2,in DMF,which are installed at room temperature.The title compound is characterized by elemental analyses,atomic absorption spectra UV,IR.Magnetic susceptibility measurements indicate the presence of a weak intra-molecular anti-ferromagnetic interaction.The structure of the tide compound is also presumed. |
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| Keywords: | Ni(Ⅱ)complex Fe(Ⅱ)complex Cyanide-bridged magnetic property |
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