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辉光放电等离子体降解染料直接蓝86
引用本文:张红梅,金星龙. 辉光放电等离子体降解染料直接蓝86[J]. 天津理工大学学报, 2012, 28(4): 66-69
作者姓名:张红梅  金星龙
作者单位:天津理工大学环境科学与安全工程学院,天津,300384
基金项目:天津市应用基础与前沿技术研究计划(重点)项目
摘    要:利用接触辉光放电反应器产生等离子体降解直接蓝86(DB)水溶液,考察了DB初始浓度、初始pH和Fe^2+对DB降解率的影响.结果表明,当DB初始浓度为30.0mg/L,溶液pH为3.0时,放电90min DB降解率可达72.36%;加入10.0mg/LFe^2+时,放电10min DB降解率可达69.20%.DB降解过程中,随反应时间的延长,溶液pH值逐渐降低,溶液电导率逐渐上升.降解90min后COD去除率为41.76%,加入10.0mg/LFe^2+后10minCOD去除率达38.50%,表明Fe^2+对DB降解有明显的催化作用.

关 键 词:接触辉光放电电解  降解  直接蓝86

Degradation of direct blue 86 in aqueous solution with contact glow discharge electrolysis
ZHANG Hong-mei , JIN Xing-long. Degradation of direct blue 86 in aqueous solution with contact glow discharge electrolysis[J]. Journal of Tianjin University of Technology, 2012, 28(4): 66-69
Authors:ZHANG Hong-mei    JIN Xing-long
Affiliation:(School of Environmental Science and Safety Engineering, Tianjin University of Technology, Tianjin 300384, China)
Abstract:In this paper, degradation of direct blue 86 (DB) was carried out by contact glow discharge electrolysis ( % CG- DE) and the effect of initial concentration, initial pH and Fe^2+ concentration were investigated. The results showed that the degradation rate of DB was 72.36% after 90 min CGDE treatment, when initial concentration of DB was 30.0 mg/L and the value of pH was 3. O. With 10.0 mg/L Fe^2+ in presence of solution, the degradation rate was 69.20% after 10 min treatment. During CGDE treatment, the value of pH decreased and the conductivity of solution increased with increasing treatment time. COD removal rate was 41.76% after 90 min treatment without catalyst. With 10.0 mg/L Fe^2+in presence of electrolyte solution, COD removal rate reached 38.50% after 10 min treatment. The results indicated that Fe^2+ had catalytic effect on the degradation of DB in CGDE.
Keywords:contact glow discharge electrolysis  degradation  direct blue 86
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