| 聚苯胺电致变色薄膜的制备及性能 |
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| 引用本文： | 董丹霞,刘芬,孙冬兰. 聚苯胺电致变色薄膜的制备及性能[J]. 天津科技大学学报, 2011, 0(4): 48-52 |
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| 作者姓名： | 董丹霞 刘芬 孙冬兰 |
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| 作者单位： | 天津科技大学理学院; |
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| 基金项目： | 天津市科委应用基础研究项目(06YFJMJC14900); 天津科技大学引进人才基金资助项目(20060410) |
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| 摘 要： | 以苯胺单体为原料,采用电化学沉积法在玻璃衬底FTO导电薄膜上合成聚苯胺电致变色薄膜.采用恒电流法,研究苯胺单体浓度、酸的种类、电沉积时间、电流密度等对薄膜制备及电致变色性能的影响,确定合成聚苯胺薄膜的最佳条件.结果表明,聚苯胺电致变化薄膜的最佳制备条件是0.15,mol/L苯胺单体的1,mol/L硫酸溶液,以10,μA/cm2的电流密度电沉积40,min.该条件下制备的薄膜的着色效率较无机电致变色薄膜高,但仅能循环105次.
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| 关 键 词： | 聚苯胺 电致变色 循环伏安 恒电流法 |
Preparation and Characterization of Polyanilline Electrochromic Film |
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| DONG Dan-xia,LIU Fen,SUN Dong-lan. Preparation and Characterization of Polyanilline Electrochromic Film[J]. Journal of Tianjin University of Science & Technology, 2011, 0(4): 48-52 |
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| Authors: | DONG Dan-xia LIU Fen SUN Dong-lan |
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| Affiliation: | DONG Dan-xia,LIU Fen,SUN Dong-lan(College of Science,Tianjin University of Science & Technology,Tianjin 300457,China) |
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| Abstract: | Polyaniline(PANI)electrochromic films was made onto commercially available FTO conductive glass substrate by galvanostat method with aniline monomer as raw materials.The effects of aniline concentration,acid species,electrodeposition time and density of the current on the electrochromic properties of the PANI film were studied.The best condition of PANI synthesis was 0.15 mol/L aniline in 1 mol/L H2SO4,current density 10 μA/cm2 for 40 min.The results revealed that the film’s coloring efficiency is higher but the layer could cycle only 105 times. |
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| Keywords: | polyaniline electrochromic cyclic Voltemmetry galvanostat method |
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