| 亚硝基聚吡咯修饰离子选择性电极的制备及电化学性能 |
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| 引用本文： | 程发良,莫金垣,戴晓云. 亚硝基聚吡咯修饰离子选择性电极的制备及电化学性能[J]. 东莞理工学院学报, 1997, 0(2) |
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| 作者姓名： | 程发良 莫金垣 戴晓云 |
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| 作者单位： | 东莞理工学院应用化学系!东莞市步步高，511700，中山大学，中山大学化学系，香港科技大学生化系 |
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| 摘 要： | 用循环伏安法（CV）制备了聚吡咯亚硝酸根离子选择性电极。表征了电极的电化学性能。在1．0x10－1～5．0x10－5mol／L浓度范围内，电极电位与亚硝酸根离子浓度成良好的线性关系，Nernst响应科率为51mv／PNO2－。观察了NO2-在PPy膜中掺杂＝去掺杂过程，从而验证了电极响应是基于掺杂机理。
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| 关 键 词： | 聚吡咯 离子选择性电极 掺杂 亚硝酸根 |
ELECTROCHEMICAL PROPERTIES OF NO_2~-POLYPYRROLE MODIFIED ION-SELECTIVE ELECTRODE |
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| Cheng Faliang. ELECTROCHEMICAL PROPERTIES OF NO_2~-POLYPYRROLE MODIFIED ION-SELECTIVE ELECTRODE[J]. Journal of Dongguan Institute of Technology, 1997, 0(2) |
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| Authors: | Cheng Faliang |
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| Abstract: | In this paper, NO2- PPy ion selective electrode is prepared by cyclic voltammograms,and the properties of this polypyrrole modified electrode are characterized. There's a good linear relationship between electrode potential and the concentration of NO2- within 10-1 mol/L and 5 x 10-5 mol/L. The mingling process of NO2 - on PPy film is observed on line, and the mingling machanism of the modified electrode studied. |
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| Keywords: | Polypyrrole Chemically modified electrode NO_2~- |
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