| 四核前过渡金属原子簇的成键模式 |
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| 引用本文： | 钟世钧,王银桂. 四核前过渡金属原子簇的成键模式[J]. 厦门大学学报(自然科学版), 1991, 0(6) |
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| 作者姓名： | 钟世钧 王银桂 |
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| 作者单位： | 厦门大学化学系 物理化学研究所(钟世钧)，厦门大学化学系 物理化学研究所(王银桂) |
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| 摘 要： | 用半径验分子轨道理论方法研究了各种构型的四核前过渡金属原子簇,分析了它们的成键能力,讨论了簇合物构型与电子数和配体效应之间的关系,说明了给定化学计量的簇合物构型及实例,讨论了金属原子轨道对金用-金属键的贡献。
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| 关 键 词： | 分子轨道 成键能力 成键模式 |
Bonding Modes in Tetranuclear Early Transition-metal Clusters |
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| Zhong Shijun Wang Yinguj. Bonding Modes in Tetranuclear Early Transition-metal Clusters[J]. Journal of Xiamen University(Natural Science), 1991, 0(6) |
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| Authors: | Zhong Shijun Wang Yinguj |
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| Affiliation: | Dept of Chem. Inst. of Phys. Chem. |
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| Abstract: | The various types of tetranuclear early transition-metal clusters have been studied by using extended Huckel calculation. The analysis of their capabilites and the relations of electron-counting to configuration and ligand effect, lead to the suggested stoichiometries with individual symmetry which explain some actual clusters. The contribution of atomic orbitals of metals to the M-M bonds also be discussed. |
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| Keywords: | Molecular orhitals Bonding capability Bonding model |
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