SOME INVESTIGATIONS ON THE NATURE OF REACTION PROCEEDING OF RADIATIONINDUCED GRAFTING IN THE POLYETHYLENE AND ACRYLIC ACID SYSTEM |
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摘 要: | Direct radiation grafting of acrylic acid (AA) and methacrylic acid (MAA) onto polyethylene (PE) films was studied. The investigation of the nature and characters of grafting proceeding was performed. The penetration of grafting onto the thin PE film was studied and the mechanism discussed. This involves an initial stage whereby the grafted surface layer deforms the PE allowing further monomer to penetrate. It was shown that the surface grafting was dynamic controlled and the penetration of monomer depended on the polarity of monomer.
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SOME INVESTIGATIONS ON THE NATURE OF REACTION PROCEEDING OF RADIATIONINDUCED GRAFTING IN THE POLYETHYLENE AND ACRYLIC ACID SYSTEM |
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Authors: | Jiang Qikang |
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Institution: | Jiang Qikang
( Materlals Institute )
Sun Hongbin
(Shanghai Functional Polymeric Material Research Institate)
Zhang Zhiping (East China Unlverslty of Sclence and Technology) |
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Abstract: | Direct radiation grafting of acrylic acid (AA) and methacrylic acid (MAA) onto polyethylene (PE) films was studied. The investigation of the nature and characters of grafting proceeding was performed. The penetration of grafting onto the thin PE film was studied and the mechanism discussed. This involves an initial stage whereby the grafted surface layer deforms the PE allowing further monomer to penetrate. It was shown that the surface grafting was dynamic controlled and the penetration of monomer depended on the polarity of monomer. |
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Keywords: | irradiation-induced surface grafting penetration grafting diffusion |
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