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热处理下光电致变色器件的结构和变色性能
引用本文:陈明洁,沈辉.热处理下光电致变色器件的结构和变色性能[J].华南理工大学学报(自然科学版),2004,32(6):31-35.
作者姓名:陈明洁  沈辉
作者单位:华南理工大学,材料科学与工程学院,广东,广州,510640;中国科学院,广州能源研究所,广东,广州,510070
基金项目:广州市科技计划项目(2003J1-C0261)
摘    要:采用溶胶-凝胶法分别制备稳定的WO3和TiO2溶胶,溶胶颗粒分散不团聚,颗粒尺寸集中,并采用提拉法和旋涂法成膜,组装成光电致变色器件,研究了不同热处理温度下光电致变色器件的透过率变化.结果表明,l000W碘钨灯光照10min后,器件的透过率由变色前的70%下降到变色后的20%左右,达到了对可见光的调节作用.

关 键 词:二氧化钛  三氧化钨  光电致变色  溶胶-凝胶法  热处理
文章编号:1000-565X(2004)06-0031-05
修稿时间:2003年10月15

Structure and Chromic Properties of the Photoelectrochromic Devices with Heat Treatment
Chen Ming-jie Shen Hui.Structure and Chromic Properties of the Photoelectrochromic Devices with Heat Treatment[J].Journal of South China University of Technology(Natural Science Edition),2004,32(6):31-35.
Authors:Chen Ming-jie Shen Hui
Abstract:In this paper, stable WO3 sol and TiO2 sol with well-dispersed granules and narrow dimension distribution were prepared by the sol-gel method. Thin films were obtained by dip-coating and spin-coating methods and they were then assembled into a photoelectrochromic device. The variation of the transmittance with heating temperature of the photoelectrochromic device was investigated. The results show that the transmittance of the device decreases from 70% (bleached state) to 20% (colored state) under the illumination by 1000W tungsten-iodine lamp for 10min, thus achieving the purpose of adjusting the visible lights.
Keywords:TiO2  WO3  photoelectrochromic  sol-gel method  heat treatment
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