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耐硫甲烷化催化剂粒内状态研究
引用本文:于广锁,于建国.耐硫甲烷化催化剂粒内状态研究[J].华东理工大学学报(自然科学版),1999,25(3):252-256.
作者姓名:于广锁  于建国
作者单位:华东理工大学洁净煤技术研究所
摘    要:采用正交配置法求解KD306型耐硫甲烷化催化剂一维(含死区)反应-扩散非等温模型,模型计算结果为实验测试值为吻合。模拟结果表明,催化剂粒内温差较小,浓差明显,“死区”的存在与否和温度有关。

关 键 词:催化剂  数学模型  耐硫甲烷化  粒内状态  KD306型

Research of Intragranular State for KD306type Sulfurtolerant Catalyst
Yu Guangsuo,Yu Jianguo,Zhang Xinmin,Wu Tao and Yu Zunhong.Research of Intragranular State for KD306type Sulfurtolerant Catalyst[J].Journal of East China University of Science and Technology,1999,25(3):252-256.
Authors:Yu Guangsuo  Yu Jianguo  Zhang Xinmin  Wu Tao and Yu Zunhong
Institution:Yu Guangsuo*,Yu Jianguo,Zhang Xinmin,Wu Tao and Yu Zunhong
Abstract:The onedimensional nonisothermal reactiondiffusion model (containing dead area) for KD306type sulfurtolerant catalyst has been solved by orthogonal collocation method. It is proved experimentally that the model can describe the state within the catalyst pellet. The results of the model simulation indicate that temperature difference within the pellet is small while concentration difference is great. In addition, whether there is a dead area depends on the temperature.
Keywords:catalyst  mathematical model  efficiency factor  sulfurtolerant methanation  intragranular state
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