| 苯乙烯／丙烯酸丁酯／（二甲基丁基）甲基丙烯酰氧乙基溴化铵无皂阳离子乳液研究 |
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| 引用本文： | 陈正国,徐祖顺,张金枝,程时远.苯乙烯／丙烯酸丁酯／（二甲基丁基）甲基丙烯酰氧乙基溴化铵无皂阳离子乳液研究[J].湖北大学学报(自然科学版),1996(3). |
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| 作者姓名： | 陈正国 徐祖顺 张金枝 程时远 |
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| 作者单位： | 湖北大学化学系 |
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| 摘 要： | 在无皂条件下，利用偶氮二异丁基脒盐酸盐（ＡＩＢＡ）作引发剂，探讨苯乙烯／丙烯酸丁酯／（二甲基丁基）甲基丙烯酰氧乙基溴化铵（Ｓｔ／ＢＡ／ＤＭＢＭＥＡＢ）三元阳离子共聚物乳液制备的合理条件，通过电镜观察到粒子形态规则、大小均一．功能性单体ＤＭＢＭＥＡＢ是以甲基丙烯酸二甲胺基乙酯和正溴丁烷为原料，选择乙腈作溶剂合成的，制取的最终产品纯度高、收率高
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| 关 键 词： | 功能性单体 无皂阳离子乳液 聚合 |
STUDIES ON STYRENE/BUTYLACRYLATE/N,N DIMETHYL N BUTYL N METHACRYL OXYETHYL AMMONIUM BROMIDE SOAP FREE CATIONIC EMULSION |
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| Chen Zhengguo,Xu Zushun,Zhang Jinzhi,Cheng Shiyuan.STUDIES ON STYRENE/BUTYLACRYLATE/N,N DIMETHYL N BUTYL N METHACRYL OXYETHYL AMMONIUM BROMIDE SOAP FREE CATIONIC EMULSION[J].Journal of Hubei University(Natural Science Edition),1996(3). |
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| Authors: | Chen Zhengguo Xu Zushun Zhang Jinzhi Cheng Shiyuan |
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| Abstract: | Soap free cationic emulsion was prepared by adjusting monomer concentration, pH value, initiator concentration, temperature. The morpholgy of latex particles was determined by TEM. In the presence of acetonitrile as reaction solvent, the unsaturated acrylate quaternary ammonium salt was synthesized in high quality crystalline form in high yield and was separated from reaction system. |
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| Keywords: | Functional monomer Soap free cationic emulision Polymerization |
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