| 二过碘酸合铜（Ⅲ）钾引发甲基丙烯酸甲酯在尼龙－1010上接枝共聚合反应的研究 |
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| 引用本文： | 王书香,刘盈海.二过碘酸合铜（Ⅲ）钾引发甲基丙烯酸甲酯在尼龙－1010上接枝共聚合反应的研究[J].河北大学学报(自然科学版),1996(3). |
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| 作者姓名： | 王书香 刘盈海 |
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| 作者单位： | Wang Shuxiang;Liu Yinghai(Department of Biology(* Chemistry)，Hebei University，Baoding 071002) |
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| 摘 要： | 本文以二过碘酸合铜（Ⅲ）钾（ＤＰＣ）为自由基引发剂，在尼龙－１０１０上引发甲基丙烯酸甲酯接枝共聚合反应，获得了具有一定接枝效率和接枝百分比的接枝共聚物。对接枝产物用红外光谱和Ｘ－射线衍射光谱进行了表征，测定了反应温度、ｐＨ值、单体用量和引发剂浓度对接枝参数的影响，探讨了该接枝共聚反应的引发机理。
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| 关 键 词： | 尼龙－1010，甲基丙烯酸甲酯，二过碘酸合铜（Ⅲ）钾，接枝共聚合反应 |
Graft Copolymerization of Methyl Methacrylate onto Nylon-1010 Initiated by Potassium Diperiodatocuprate(Ⅲ) |
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| Wang Shuxiang,Liu Yinghai.Graft Copolymerization of Methyl Methacrylate onto Nylon-1010 Initiated by Potassium Diperiodatocuprate(Ⅲ)[J].Journal of Hebei University (Natural Science Edition),1996(3). |
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| Authors: | Wang Shuxiang Liu Yinghai |
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| Abstract: | Potassium diperiodatocuprate(Ⅲ)(DPC)is an efficient initiator for graft copolymerization of methyl methacrylate onto nylon 1010.The structure of poly(MMA)-g-nylon was characterized by IR and X-ray diffraction spectra.It was found that the copolymerization reaction was influenced by the pH,temperature and concentrations of MMA and DPC.An initiation mechanism was proposed. |
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| Keywords: | Methyl methacrylate Nylon-1010 Graft copolymerization Potassium diperiodatocuprate(Ⅲ) |
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