| 有机化合物选择性氧化的研究——载体铬(Ⅵ)氧化醇类的研究 |
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| 引用本文： | 魏章申 蔡昆. 有机化合物选择性氧化的研究——载体铬(Ⅵ)氧化醇类的研究[J]. 河南师范大学学报(自然科学版), 1990, 0(2): 98-100 |
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| 作者姓名： | 魏章申 蔡昆 |
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| 作者单位： | 河南师范大学化学系，河南师范大学化学系 |
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| 摘 要： | 本文以普通型强碱性阴离子交换树脂作载体的铬(Ⅵ)试剂用于氧化苄醇、烯丙醇和仲醇类,取得了良好的效果,对饱和伯醇则不氧化。反应操作简单,树脂经再生后可循环使用。
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| 关 键 词： | 选择性氧化 载体铬(Ⅵ)试剂 717型树脂 |
STUDY ON SELECTIVE OXIDATION OF ORGANIC COMPOUNDS——The Selective Oxidation of Alcohols with the Polymer—supported Chromium(Ⅵ)Reagent |
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| Wei Zhangshen,Cai Kun. STUDY ON SELECTIVE OXIDATION OF ORGANIC COMPOUNDS——The Selective Oxidation of Alcohols with the Polymer—supported Chromium(Ⅵ)Reagent[J]. Journal of Henan Normal University(Natural Science), 1990, 0(2): 98-100 |
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| Authors: | Wei Zhangshen Cai Kun |
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| Affiliation: | Wei Zhangshen;Cai Kun Department of Chemistry |
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| Abstract: | This paper described the selective oxidations of benzylic,allylic and secondary alcohols to the correspondingcarbonyl compounds with 717 strong basic anion—exchange resin—supported chromium(Ⅵ)reagent in goodyield but unable to oxidize the saturated primary alcohols with it.Reaction procedure can be completed very readi-ly and the polymeric support can be regenerated without noticeable loss in reactivity. |
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| Keywords: | selective oxidation polymer—supported chromium(Ⅵ)reagent 717 strong basic anion—exchange resin |
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