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强电解质浓溶液活度系数的半经验公式
引用本文:梁英教. 强电解质浓溶液活度系数的半经验公式[J]. 东北大学学报(自然科学版), 1986, 0(1)
作者姓名:梁英教
作者单位:东北工学院化学系
摘    要:本文根据Pitzer电解质溶液理论,提出计算强电解质浓溶液活度系数的半经验计算公式(25℃,水溶液): 由文献的实验数据求出了一系列电解质的A_1、B_1、A_2、B_2,C_2等参数值。算得的活度系数值与实验值符合得较好。

关 键 词:离子活度系数  强电解质溶液

Semiempirtcal Formulae for Activity Coefficients of Strong Electrolytes in Concentrated Solutions
Liang Yingjiao. Semiempirtcal Formulae for Activity Coefficients of Strong Electrolytes in Concentrated Solutions[J]. Journal of Northeastern University(Natural Science), 1986, 0(1)
Authors:Liang Yingjiao
Affiliation:Liang Yingjiao
Abstract:Two semiempirical formulae for calculating activity coefficients of strong electrolytes in concentrated solution at 25 C have been proposed according to Pitzer's theory. These formulae are expressed as:These formulae are less complicated than those of Pitzer's.The parameters in these formulae have been compuled and listed in appendix table 1. The calculated results show satisfactory agreement with the experimental data of activity coefficients,
Keywords:ionic activity coefficient   strong electrolytic solution
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