| 聚Copp膜形成机理及在溶液中的电化学性质 |
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| 引用本文： | 肖少荣,王颖.聚Copp膜形成机理及在溶液中的电化学性质[J].广西大学学报(自然科学版),1995,20(4):407-410. |
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| 作者姓名： | 肖少荣 王颖 |
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| 作者单位： | 广西师范学院化学系 |
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| 摘 要： | 用循环伏安法研究钴原卟啉二甲酯（ＣｏＰＰ）在玻璃碳电极上的氧化聚合。电化学和紫外光谱结果表明ＣｏＰＰ单体的聚合是由于卟啉环上乙烯取低基的其中一个发生取代而导致的。随着水溶液的ＰＨ值升高，聚ＣｏＰＰ膜中Ｃｏ＾３＋／Ｃｏ＾２＋的还原峰电位负移。
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| 关 键 词： | 钴原卟啉二甲酯 电化学 聚合 循环伏安 聚CoPP膜 |
Formation Mechanism of Poly CoPP Film and Its Electrochemical Property in Solutions |
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| Xiao Shaorong, Wang Ying, Li Lilin.Formation Mechanism of Poly CoPP Film and Its Electrochemical Property in Solutions[J].Journal of Guangxi University(Natural Science Edition),1995,20(4):407-410. |
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| Authors: | Xiao Shaorong Wang Ying Li Lilin |
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| Abstract: | Cobaltprotoporphyrin iX dimethyl ester(CoPP)was oxidativelypolymerized at glass carbon electrode by cyclic voltammetry.The results ofelectrochemistry and UV spectrum indicated that the polymerization resulted from theoxidation of one vinyl group in CoPP.The potential of Co3+/Co2+in polymer moved toward.s to negative with the increase of PH values in solutions. |
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| Keywords: | cobaltprotoporohyrin IX dimethyl ester electrochemical polymerization cyclic voltammetry |
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