| 杂多酸/聚苯胺掺杂材料的制备、表征及性质 |
| |
| 引用本文： | 常希文,马荣华.杂多酸/聚苯胺掺杂材料的制备、表征及性质[J].齐齐哈尔大学学报(自然科学版),2006,22(6):24-26. |
| |
| 作者姓名： | 常希文 马荣华 |
| |
| 作者单位： | 齐齐哈尔大学,化学与化学工程学院,黑龙江,齐齐哈尔,161006 |
| |
| 摘 要： | 采用固相合成法,以苯胺为单体,过硫酸铵为氧化剂,制备了4种杂多酸/聚苯胺掺杂材料。测定了其在CHCl3和CCl4中的溶解度,并以红外光谱、紫外—可见光谱、X射线粉末衍射、电导率等测试手段对掺杂材料进行了表征。通过与本征态聚苯胺相比,证明出制备的材料是掺杂材料,同时表明聚苯胺经质子酸掺杂后,形成共轭结构,从而具有良好的导电性能。
|
| 关 键 词： | 杂多酸 聚苯胺 导电性 |
| 文章编号： | 1007-984X(2006)06-0024-03 |
| 收稿时间： | 2006-08-26 |
| 修稿时间： | 2006年8月26日 |
Synthesis, characterization and properties of polyaniline doped with heteropoly acid |
| |
| CHANG Xi-wen,MA Rong-hua.Synthesis, characterization and properties of polyaniline doped with heteropoly acid[J].Journal of Qiqihar University(Natural Science Edition),2006,22(6):24-26. |
| |
| Authors: | CHANG Xi-wen MA Rong-hua |
| |
| Institution: | College of Chemistry and Chemical Engineering,Qiqihar University,Heilongjiang Qiqihar161006,China |
| |
| Abstract: | Four polyaniline doped with heteropoly acid were prepared by solid-state synthesis method.The solubility in CHCl3 and CCl4 were detemined.These materials were characterized by IR spectra,X-Ray,conductivity.Com-pared with polyaniline base,it was proved that the materials were doped materials.At the same time,It indicatived that the conductivity of polyaniline doped by heteropoly acid is very good. |
| |
| Keywords: | heteropolyacid polyaniline conductivity |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
