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La~(3+)掺杂Bi_(0.5)(Na_(1-x-y)K_xLi_y)_(0.5)TiO_3陶瓷的微结构与电学性能
引用本文:廖运文.La~(3+)掺杂Bi_(0.5)(Na_(1-x-y)K_xLi_y)_(0.5)TiO_3陶瓷的微结构与电学性能[J].西华师范大学学报(哲学社会科学版),2008,29(3).
作者姓名:廖运文
作者单位:化学应用与污染控制技术四川省教育厅重点实验室,西华师范大学化学化工学院,四川南充637002
基金项目:四川省教育厅重点项目(2006A075)
摘    要:利用传统的电子陶瓷工艺制备了La^3+掺杂Bi0.5(Na1-x-yKxLiy)0.5TiO3无铅压电陶瓷,研究了La^3+掺杂对该体系陶瓷的介电压电性能与微观结构的影响.结果表明,少量的La^3+掺杂可以改善该陶瓷的微结构;当掺杂量为0.1%时,该陶瓷体系的压电性能有较大的改善,室温下该体系配方的压电常数d33可达215pC/N,径向机电耦合系数kp达到37.4%,但同时介电损耗增大,机械品质因子降低.当掺杂量达到1.5%以后,陶瓷的压电性能严重下降.

关 键 词:无铅压电陶瓷  Bi0.5(Na1-x-yKxLiy)0.5TiO3  La^3+掺杂  压电常数  机电耦合系数

Electrical Properties and Microstructure of La~(3+)-Doped Bi_(0.5)(Na_(1-x-y)K_xLi_y)_(0.5)TiO_3 Lead-Free Piezoelectric Ceramics
LIAO Yun-wen.Electrical Properties and Microstructure of La~(3+)-Doped Bi_(0.5)(Na_(1-x-y)K_xLi_y)_(0.5)TiO_3 Lead-Free Piezoelectric Ceramics[J].Journal of China West Normal University:Natural Science Edition,2008,29(3).
Authors:LIAO Yun-wen
Institution:LIAO Yun-wen(College of Chemistry , Chemical Engineering,China West Normal University,Nanchong 637002,China)
Abstract:La3+-doped Bi0.5(Na0.725K0.175Li0.10)0.5TiO3 lead-free piezoelectric ceramics were prepared by traditional electronic ceramics processes.The effect of La3+-doping on the dielectric and piezoelectric properties and microstructure of the ceramics has been investigated.SEM observation indicates that doping with a small amount of La3+ can improve the microstructure of the ceramics.The results indicate that La3+-doping can greatly improve the piezoelectric properties of Bi0.5(Na0.725K0.175Li0.10)0.5TiO3 ceramics...
Keywords:lead-free piezoelectric ceramics  La3+-doping  piezoelectric constant  electromechanical coupling factor  
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